2d Materials

A comprehensive and accessible introduction to 2D materials, covering basic physics, electronic and optical properties, and potential applications.

The advent of graphene and, more recently, two-dimensional materials has opened new perspectives in electronics, optoelectronics, energy harvesting, and sensing applications. This book, based on a Special Issue published in Nanomaterials – MDPI covers experimental, simulation, and theoretical research on 2D materials and their van der Waals heterojunctions. The emphasis is the physical properties and the applications of 2D materials in state-of-the-art sensors and electronic or optoelectronic devices.

Synthesis, Modelling and Characterization of 2D Materials and Their Heterostructures provides a detailed discussion on the multiscale computational approach surrounding atomic, molecular and atomic-informed continuum models. In addition to a detailed theoretical description, this book provides example problems, sample code/script, and a discussion on how theoretical analysis provides insight into optimal experimental design. Furthermore, the book addresses the growth mechanism of these 2D materials, the formation of defects, and different lattice mismatch and interlayer interactions. Sections cover direct band gap, Raman scattering, extraordinary strong light matter interaction, layer dependent photoluminescence, and other physical properties. Explains multiscale computational techniques, from atomic to continuum scale, covering different time and length scales Provides fundamental theoretical insights, example problems, sample code and exercise problems Outlines major characterization and synthesis methods for different types of 2D materials

Fundamentals and Sensing Applications of 2D Materials provides a comprehensive understanding of a wide range of 2D materials. Examples of fundamental topics include: defect and vacancy engineering, doping and advantages of 2D materials for sensing, 2D materials and composites for sensing, and 2D materials in biosystems. A wide range of applications are addressed, such as gas sensors based on 2D materials, electrochemical glucose sensors, biosensors (enzymatic and non-enzymatic), and printed, stretchable, wearable and flexible biosensors. Due to their sub-nanometer thickness, 2D materials have a high packing density, thus making them suitable for the fabrication of thin film based sensor devices. Benefiting from their unique physical and chemical properties (e.g. strong mechanical strength, high surface area, unparalleled thermal conductivity, remarkable biocompatibility and ease of functionalization), 2D layered nanomaterials have shown great potential in designing high performance sensor devices. Provides a comprehensive overview of 2D materials systems that are relevant to sensing, including transition metal dichalcogenides, metal oxides, graphene and other 2D materials system Includes information on potential applications, such as flexible sensors, biosensors, optical sensors, electrochemical sensors, and more Discusses graphene in terms of the lessons learned from this material for sensing applications and how these lessons can be applied to other 2D materials

2D Materials for Photonic and Optoelectronic Applications introduces readers to two-dimensional materials and their properties (optical, electronic, spin and plasmonic), various methods of synthesis, and possible applications, with a strong focus on novel findings and technological challenges. The two-dimensional materials reviewed include hexagonal boron nitride, silicene, germanene, topological insulators, transition metal dichalcogenides, black phosphorous and other novel materials. This book will be ideal for students and researchers in materials science, photonics, electronics, nanotechnology and condensed matter physics and chemistry, providing background for both junior investigators and timely reviews for seasoned researchers. Provides an in-depth look at boron nitride, silicene, germanene, topological insulators, transition metal dichalcogenides, and more Reviews key applications for photonics and optoelectronics, including photodetectors, optical signal processing, light-emitting diodes and photovoltaics Addresses key technological challenges for the realization of optoelectronic applications and comments on future solutions

Driven by the advent of two-dimensional materials, valleytronics is emerging as the next hot field of research in materials science. While the use of charge or spin degrees of freedom in electronic materials as information carriers is familiar and well-appreciated, employment of the valley degree of freedom as an information carrier has remained elusive for many decades. Shortly following the discovery of isolated graphene, 2D semiconductors such as transition metal dichalcogenides were also isolated and investigated. We now understand that these materials can have separately addressable valleys because each valley can be uniquely coupled to a spin state. This imparts the ability to address different valleys (like pseudospins) with electric field, magnetic field, or light, and there is now a real possibility to engineer practical devices based on using valley as the information carrier.Valleytronics in 2D Materials is the first book in the world on the topic of valleytronics. The reader is introduced to the concept via a brief history emphasizing the challenges that impeded its development for so long. We then dive into the valley physics of 2D semiconductors to explain the recent excitement in 2D valleytronics, the scientific investigations to confirm the addressable valleys, and the attempts to engineer valley devices for practical purposes. The text takes on a decidedly practical approach towards the subject, seeking to bring the reader quickly into the field by presenting the minimum theoretical basis for understanding the use of the valley degree of freedom in devices. A selection of key works establishing the scientific underpinnings of valley addressability and control are described to help the reader grasp the current stage of understanding, the technical foundations established, and the open questions. The renewal in valleytronics is yet unfinished, but with more than a decade of research and engineering efforts devoted in recent times, this book seeks to provide a timely reference for students, scientists and engineers to join this exciting journey and perhaps help to create the next disruption in information technology.

This book brings together innovative methodologies and strategies adopted in the research and developments of Advanced 2D Materials. Well-known worldwide researchers deliberate subjects on (1) Synthesis, characterizations, modeling and properties, (2) State-of-the-art design and (3) innovative uses of 2D materials including: Two-dimensional layered gallium selenide Synthesis of 2D boron nitride nanosheets The effects of substrates on 2-D crystals Electrical conductivity and reflectivity of models of some 2D materials Graphene derivatives in semicrystalline polymer composites Graphene oxide based multifunctional composites Covalent and non-covalent polymer grafting of graphene oxide Graphene-semiconductor hybrid photocatalysts for solar fuels Graphene based sensors Graphene composites from bench to clinic Photocatalytic ZnO-graphene hybrids Hydroxyapatite-graphene bioceramics in orthopaedic applications

2D Materials for Nanophotonics presents a detailed overview of the applications of 2D materials for nanophotonics, covering the photonic properties of a range of 2D materials including graphene, 2D phosphorene and MXenes, and discussing applications in lighting and energy storage. This comprehensive reference is ideal for readers seeking a detailed and critical analysis of how 2D materials are being used for a range of photonic and optical applications. Outlines the major photonic properties in a variety of 2D materials Demonstrates major applications in lighting and energy storage Explores the challenges of using 2D materials in photonics