Electrochemistry In Light Water Reactors

There has long been a need for effective methods of measuring corrosion within light water nuclear reactors. This important volume discusses key issues surrounding the development of high temperature reference electrodes and other electrochemical techniques. The book is divided into three parts with part one reviewing the latest developments in the use of reference electrode technology in both pressurised water and boiling water reactors. Parts two and three cover different types of corrosion and tribocorrosion and ways they can be measured using such techniques as electrochemical impedance spectroscopy. Topics covered across the book include in-pile testing, modelling techniques and the tribocorrosion behaviour of stainless steel under reactor conditions. Electrochemistry in light water reactors is a valuable reference for all those concerned with corrosion problems in this key technology for the power industry. Discusses key issues surrounding the development of high temperature reference eletrodes A valuable reference for all concerned with corrosion problems in this key technology

This book presents a complete overview of the powerful but often misused technique of Electrochemical Impedance Spectroscopy (EIS). The book presents a systematic and complete overview of EIS. The book carefully describes EIS and its application in studies of electrocatalytic reactions and other electrochemical processes of practical interest. This book is directed towards graduate students and researchers in Electrochemistry. Concepts are illustrated through detailed graphics and numerous examples. The book also includes practice problems. Additional materials and solutions are available online.

Stress Corrosion Cracking of Nickel Based Alloys in Water-Cooled Nuclear Reactors: The Coriou Effect presents the latest information on brittle failure of metals in corrosive chemical environments under the influence of tensile stresses. Nickel alloys are more resistant to SCC as well as high temperatures and have been widely used in more challenging environments such as nuclear power plants. However, these alloys can suffer SCC under certain conditions, resulting in component failure. A key figure in understanding the mechanisms of SCC in nickel alloys in water-cooled nuclear reactors is Henri Coriou of the CEA, France’s leading center for nuclear research. This book assesses his work in the context of the latest research on SCC in nickel alloys in nuclear power plants. Up-to-date reviews of recent research findings from leading experts in the field Authoritative and comprehensively reviewed by the Working Party 4 on Nuclear Corrosion Showcases the excellent quality and technical accomplishments of Henri Coriou and CEA

This special issue of Corrosion Engineering Science and Technology is dedicated to the study of corrosion of objects from historical sites. The issue contains contributions from the 2009 EUROCORR session on Corrosion of Archaeological and Heritage Artefacts organised by the European Federation of Corrosion's working party and commissioned articles on other key issues. The objective is to give the reader a broad understanding of corrosion of ancient materials, for the most part metal but also glass. Articles shed light on a range of analytical approaches related to the study of the complex systems that make up historical artifacts. In order to arrive at an understanding of the nanometric organisation of rust layers and interphases, such studies must be approached on a macroscopic scale. Techniques used include; macrophotography, synchrotron radiation and transmission electron microscopy (TEM) that ensure results that are both exhaustive and representative of particular observations. This issue demonstrates the wealth of approaches possible in the study of the corrosion of ancient materials.

Corrosion remains one of the key issues affecting the performance and availability of nuclear power plants. Therefore, reliable in-plant corrosion monitoring methods are essential both for the future operation of existing plants and to ensure the safety of future nuclear waste disposal systems. In two parts, this book was stimulated by a workshop organised by EFC Working Party 4 on Nuclear Corrosion and the European Cooperative Group on Corrosion Monitoring of Nuclear Materials (EGC-COMON). The first part deals mainly with research into the detection of stress corrosion crack initiation in nuclear power plant environments (essentially high temperature water at around 300 °C) by various methods, particularly the electrochemical noise technique but also including the electrochemical impedance, acoustic emission and direct current potential drop methods. The second part addresses the goal to develop in-situ techniques and includes examples of the application of electrochemical corrosion potential monitoring. This book will be of particular interest to scientists and engineers concerned with the mitigation of corrosion in nuclear systems.

Corrosion of nuclear materials, i.e. the interaction between these materials and their environments, is a major issue for plant safety as well as for operation and economic competitiveness. Understanding these corrosion mechanisms, the systems and materials they affect, and the methods to accurately measure their incidence is of critical importance to the nuclear industry. Combining assessment techniques and analytical models into this understanding allows operators to predict the service life of corrosion-affected nuclear plant materials, and to apply the most appropriate maintenance and mitigation options to ensure safe long term operation. This book critically reviews the fundamental corrosion mechanisms that affect nuclear power plants and facilities. Initial sections introduce the complex field of nuclear corrosion science, with detailed chapters on the different types of both aqueous and non aqueous corrosion mechanisms and the nuclear materials susceptible to attack from them. This is complemented by reviews of monitoring and control methodologies, as well as modelling and lifetime prediction approaches. Given that corrosion is an applied science, the final sections review corrosion issues across the range of current and next-generation nuclear reactors, and across such nuclear applications as fuel reprocessing facilities, radioactive waste storage and geological disposal systems. With its distinguished editor and international team of expert contributors, Nuclear corrosion science and engineering is an invaluable reference for nuclear metallurgists, materials scientists and engineers, as well as nuclear facility operators, regulators and consultants, and researchers and academics in this field. Comprehensively reviews the fundamental corrosion mechanisms that affect nuclear power plants and facilities Chapters assess different types of both aqueous and non aqueous corrosion mechanisms and the nuclear materials susceptible to attack from them Considers monitoring and control methodologies, as well as modelling and lifetime prediction approaches

The papers included in this issue of ECS Transactions were originally presented in the symposium ¿Interfacial Electrochemistry and Chemistry in High Temperature Media¿, held during the 212th meeting of The Electrochemical Society, in Washington, DC, from October 7 to 12, 2007.

Nuclear Corrosion: Research, Progress and Challenges, part of the “Green Book series of the EFC, builds upon the foundations of the very first book published in this series in 1989 (“Number 1 - Corrosion in the Nuclear Industry ). This newest volume provides an overview on state-of-the-art research in some of the most important areas of nuclear corrosion. Chapters covered include aging phenomena in light water reactors, reprocessing plants, nuclear waste disposal, and supercritical water and liquid metal systems. This book will be a vital resource for both researchers and engineers working within the nuclear field in both academic and industrial environments. Discusses industry related aspects of materials in nuclear power generation and how these materials react with the environment Provides comprehensive coverage of the topic as written by noted experts in the field Includes coverage of nuclear waste corrosion