Environmental Soil Chemistry

As the author states in his Preface, this book is written at a time when scientific and lay communities recognize that knowledge of environmental chemistry is fundamental in understanding and predicting the fate of pollutants in soils and waters, and in making sound decisions about remediation of contaminated soils. Environmental Soil Chemistry presents the fundamental concepts of soil science and applies them to environmentally significant reactions in soil. Clearly and concisely written for undergraduate and beginning graduate students of soil science, the book is likewise accessible to all students and professionals of environmental engineering and science. Chapters cover background information useful to students new to the discipline, including the chemistry of inorganic and organic soil components, soilacidity and salinity, and ion exchange and redox phenomena. However, discussion also extends to sorption/desorption, oxidation-reduction of metals and organic chemicals, rates of pollutant reactions as well as technologies for remediating contaminated soils. Supplementary reading lists, sample problems, and extensive tables and figures make this textbook accessible to readers. Key Features * Provides students with both sound contemporary training in the basics of soil chemistry and applications to real-world environmental concerns * Timely and comprehensive discussion of important concepts including: * Sorption/desorption * Oxidation-reduction of metals and organics * Effects of acidic deposition and salinity on contaminant reactions * Boxed sections focus on sample problems and explanations of key terms and parameters * Extensive tables on elemental composition of soils, rocks and sediments, pesticide classes, inorganic minerals, and methods of decontaminating soils * Clearly written for all students and professionals in environmental science and environmental engineering as well as soil science

Soil and Environmental Chemistry, Second Edition, presents key aspects of soil chemistry in environmental science, including dose responses, risk characterization, and practical applications of calculations using spreadsheets. The book offers a holistic, practical approach to the application of environmental chemistry to soil science and is designed to equip the reader with the chemistry knowledge and problem-solving skills necessary to validate and interpret data. This updated edition features significantly revised chapters, averaging almost a 50% revision overall, including some reordering of chapters. All new problem sets and solutions are found at the end of each chapter, and linked to a companion site that reflects advances in the field, including expanded coverage of such topics as sample collection, soil moisture, soil carbon cycle models, water chemistry simulation, alkalinity, and redox reactions. There is also additional pedagogy, including key term and real-world scenarios. This book is a must-have reference for researchers and practitioners in environmental and soil sciences, as well as intermediate and advanced students in soil science and/or environmental chemistry. Includes additional pedagogy, such as key terms and real-world scenarios Supplemented by over 100 spreadsheets to migrate readers from calculator-based to spreadsheet-based problem-solving that are directly linked from the text Includes example problems and solutions to enhance understanding Significantly revised chapters link to a companion site that reflects advances in the field, including expanded coverage of such topics as sample collection, soil moisture, soil carbon cycle models, water chemistry simulation, alkalinity, and redox reactions

This introduction to modern soil chemistry describes chemical processes in soils in terms of established principles of inorganic, organic, and physical chemistry. It aims for a modern conceptual approach rather than empirical description, including the most recently developed explanations for the more controversial topics. The text provides an understanding of the structure of the solid mineral and organic materials from which soils are formed. With the help of diagrams and graphs, it explains such important processes as cation exchange, chemisorption and physical adsorption of organic and inorganic ions and molecules, soil acidification and weathering, oxidation-reduction reactions, and development of soil alkalinity and clay swelling properties. Environmental as well as agricultural topics are covered, illustrated with case studies and individual chapters on agricultural chemicals and pollutants such as heavy metals and toxic organic chemicals. This book defines and addresses the challenge of the future -- to protect the soil ecosystem from the pollutants of an industrial society.

Environmental Chemistry of Soils provides an understanding of soil chemical properties and processes at a fundamental scientific level.

The central role of soil chemistry in the ecosystem and other disciplines is becoming increasingly important. For example the effects of the increased levels of atmospheric carbon dioxide, and accelerated use of pesticides, on soil fertility has been a focus of much high-level debate. This text begins by defining the relationship between soil chemistry and other fields such as plant science and pollution science. A detailed description of the components of soils follows, including inorganic, mineral and organic matter. The book addresses cogent issues such as soil fertility and soil pollution. In a concluding chapter, a review of future analytic advances in the study of soil chemistry is given, emphasising the importance of the soil chemist in equitable and sustainable land use and agricultural policy. The book is an ideal starting point for the student undertaking undergraduate study in the environmental and soil sciences.

An excellent knowledge base in soil and water chemistry --the ideal basic text for students of the environmental sciences In Environmental Soil and Water Chemistry, leading soil and water authority V. P. Evangelou presents a complete overview of the principles and applications of soil science, addressing the subject by viewing the interactions between soil and water as a basis for understanding the nature, extent, and treatment of polluted soil and water. The text opens with a discussion of principles--the fundamental tenets of chemistry needed to understand soil and water quality and treatment of polluted resources--and continues with a look at applications for the control and treatment of soil and water. Suitable for advanced undergraduates and beginning graduate students, this extensive, timely volume covers: * Water chemistry and mineral solubility; soil minerals and surface chemical properties and their behavior; and electrochemistry and kinetics * The control of agricultural chemical pollution and land disturbance pollution; colloids and transport processes in soils; and technologies for measuring quality and executing treatment * Specific chemical contaminants and the procedures for their neutralization In a world where chemical pollutants pose a grave threat to the earth's natural resources, Environmental Soil and Water Chemistry offers students both an excellent textbook and a handy reference on the wide spectrum of environmental problems they will confront outside the classroom.

Learn the secrets of soil chemistry and its role in agriculture and the environment. Examine the fundamental laws of soil chemistry, how they affect dissolution, cation and anion exchange, and other reactions. Explore how water can form water-bridges and hydrogen bonding, the most common forces in adsorption, chelation, and more. Discover how electrical charges develop in soils creating electrochemical potentials forcing ions to move into the plant body through barriers such as root membranes, nourishing crops and plants. You can do all this and more with Principles of Soil Chemistry, Fourth Edition. Since the first edition published in 1982, this resource has made a name for itself as a textbook for upper level undergraduates and as a handy reference for professionals and scientists. This fourth edition reexamines the entire reach of soil chemistry while maintaining the clear, concise style that made previous editions so user-friendly. By completely revising, updating, and incorporating a decade’s worth of new information, author Kim Tan has made this edition an entirely new and better book. See what's new in the Fourth Edition Reexamines atoms as the smallest particle that will enter into chemical reactions by probing new advances testifying the presence of subatomic particles and concepts such as string theory Underscores oxygen as the key element in soil air and atmosphere for life on earth Reevaluates the idea of transformation of orthoclase into albite by simple cation exchange reactions as misleading and bending scientific concepts of ion exchange over the limit of truth Examines the role of fertilizers, sulfur, pyrite, acid rain, and nitrogen fixation in soil acidity, underscoring the controversial effect of nitrification on increasing soil acidity over time Addresses the old and new approaches to humic acids by comparing the traditional operational concept against the currently proposed supramolecular and pseudomicellar concept Proposes soil organics, such as nucleic acids of DNA and others, to also adsorb cation ions held as diffusive ion clouds around the polymers Tan explains, in easy and simple language, the chemical make-up of the four soil constituents, their chemical reactions and interactions in soils as governed by basic chemical laws, and their importance in agriculture, industry, and the environment. He differentiates soil chemistry from geochemistry and physical chemistry. Containing more than 200 equations, 123 figures, and 38 tables, this popular text and resource supplies a comprehensive treatment of soil chemistry that builds a foundation for work in environmental pollution, organic and inorganic soil contamination, and potential ecological health and environmental health risks.

Kinetics of soil chemical reactions. Methods of obtaining and analyzin kinetic data. Relaxation methods for studying kinetics of soil chemical phenomena. Kinetics of ion sorptionon humic substances. Kinetics of sorption/desorption processes in soils. Modelling nonequilibrium reactions of inorganic solutes in soil columns. Sorption kinetics of organic chemicals: methods, models, and mechanisms.