Nanofillers For Binary Polymer Blends

Nanofillers for Binary Polymer Blends covers major advances in the field of polymer-blend nanocomposites. The book encompasses the fundamentals of polymer blends, various nanofillers, experimental techniques used in their fabrication, the characterization of various polymer blend nanocomposites, and theoretical evaluations of various properties. The properties and potential applications that have been achieved in various polymer blends by the addition of nanofillers are also highlighted. Applications for commercial products, including automotive parts, packaging, construction materials, biotechnology, medical devices, building materials, computer housings, car interiors, etc., are also covered in detail. This is an important reference source for materials scientists and engineers looking to increase their understanding of how nanofillers are being used in polymer blends.

Nanofillers can play two important roles in polymer blends. The first is the improvement of various properties such as mechanical, barrier, thermal, flame retardancy, and electrical properties. The second is the modification of miscibility/compatibility and morphology of polymer blends. The mechanism of action of nanoparticles to modify the morphology, interfacial properties, and performance of immiscible polymer blends relies on their localization, their interactions with polymer components, and the way these additives disperse within the polymer blend. The objective of this chapter is to review the research on nanofilled thermoplastic/thermoplastic polymer blends, paying particular attention both to the distribution of nanoparticles inside a binary polymer blend and to the effect of nanofillers on the morphology and on the properties of the thermoplastic polymer blends. In a large majority of cases, thermoplastic polymer blends filled with nanoparticles show better compatibility in terms of morphology size than pure blends. Moreover, the formation of a cocontinuous structure is promoted by the presence of the nanofiller.

The design of polymer blends constitutes an interesting alternative to obtaining micro- and nanostructured surfaces. The cost is reasonable and it is free from time-consuming procedures. Blending of polymers can yield materials with unprecedented properties that cannot be provided otherwise by using a single polymer. The free surface topography of polymer blend films, often related to phase domain structure, is critical to the applications. Two main aspects need to be considered in the preparation of multistructured blends: the interfaces involved and the morphology to be obtained. The control of these two aspects depends further on materials-related parameters involving the composition of the blend, the interfacial tension or viscosity ratio, and the processing conditions related to the temperature, time, or intensity of mixing, among others. Both domain structure and topography of the blend films have garnered increasing interest over the past decade. This chapter describes the nanomicrostructures formed at the polymer surface from polymer blends. Despite the crucial role that surfaces play in the final application of the material, up to now most of the studies concerning polymer blends have been related to the control of the mechanical properties (toughness, stiffness, thermal expansion, etc.), their barrier properties, or the electrical conductivity. This chapter focuses on the analysis of the structured polymer surfaces and thin films, giving an overview of the role of these structures on the final application. The principles of phase separation and the resulting structures formed are briefly discussed, followed by a wide overview of the possibilities of producing stimuli-responsive interfaces by introducing, among other things, pH- or temperature-responsive polymers within the blend. Finally, we look at how using particular preparation conditions and/or self-assembly of block copolymers, the formation of films and surfaces with hierarchical order length-scales can be induced. We also examine the main areas in which multiscale-ordered interfaces obtained from polymer blends have been applied.

Over 30% of commercial polymers are blends or alloys or one kind or another. Nanostructured blends offer the scientist or plastics engineer a new range of possibilities with characteristics including thermodynamic stablility; the potential to improve material transparency, creep and solvent resistance; the potential to simultaneously increase tensile strength and ductility; superior rheological properties; and relatively low cost. Nanostructured Polymer Blends opens up immense structural possibilities via chemical and mechanical modifications that generate novel properties and functions and high-performance characteristics at a low cost. The emerging applications of these new materials cover a wide range of industry sectors, encompassing the coatings and adhesives industry, electronics, energy (photovoltaics), aerospace and medical devices (where polymer blends provide innovations in biocompatible materials). This book explains the science of nanostructure formation and the nature of interphase formations, demystifies the design of nanostructured blends to achieve specific properties, and introduces the applications for this important new class of nanomaterial. All the key topics related to recent advances in blends are covered: IPNs, phase morphologies, composites and nanocomposites, nanostructure formation, the chemistry and structure of additives, etc. Introduces the science and technology of nanostructured polymer blends – and the procedures involved in melt blending and chemical blending to produce new materials with specific performance characteristics Unlocks the potential of nanostructured polymer blends for applications across sectors, including electronics, energy/photovoltaics, aerospace/automotive, and medical devices (biocompatible polymers) Explains the performance benefits in areas including rheological properties, thermodynamic stablility, material transparency, solvent resistance, etc.

Nanostructured Immiscible Polymer Blends: Migration and Interface covers a wide range of nanoparticle types, emphasizing the mechanisms and parameters involved in the migration of nanofillers inside immiscible polymer blends. This book explores the influence of nanoparticle migration on the localization, and hence, morphology development, electrical conductivity, and met-rheological properties of blended composite materials. As the influence of solid particles, ranging in size from several hundred nanometers to a few microns in immiscible polymer blends has been extensively studied for use as compatibilizers, morphology stabilizers, and reinforcement agents, this book is a timely resource. Outlines techniques used to prepare nanoparticles-modified immiscible polymer blend composites Explains the structural and morphological development, and melt-state rheological behaviors of nanoparticles-modified immiscible polymer blend composites Discusses major industrial applications

Compatibilization of Polymer Blends: Micro and Nano Scale Phase Morphologies, Interphase Characterization and Properties offers a comprehensive approach to the use of compatibilizers in polymer blends, examining both fundamental and advanced knowledge in the field. The book begins by introducing polymer blends, describing thermodynamics, miscibility, and phase separation, and explaining the main concepts of compatibilization. Other sections cover theoretical approaches for nearly compatible blends, incompatible blends, nanofillers, physical compatibilization, reactive compatibilization, morphological and structural characterization, and physico-mechanical characterization. Finally, key application areas are covered, including biomedical applications, packaging and automobile engineering. While this book will be a highly valuable reference source for academics, researchers and postgraduate students interested in polymer blends, it will also be ideal for anyone involved in the fields of polymer science, polymer chemistry, polymer physics, materials science, scientists, R&D professionals, and engineers in involved in the development or engineering of polymer products. Offers detailed and systematic coverage of essential and advanced topics relating to the compatibilization of polymer blends Presents a critical analysis of the effect of compatibilization on morphology and thermal, mechanical, electrical and viscoelastic properties of polymer blends Draws on novel studies and state-of-the-art research, discussing the latest issues and developments

This handbook brings together technical expertise, conceptual background, applications, and societal aspects of Industry 4.0: the evolution of automation and data exchange in fabrication technologies, materials processing, and device manufacturing at both experimental and theoretical model scales. The book assembles all the aspects of Industry 4.0, starting from the emergence of the concept to the consequences of its progression. Drawing on expert contributors from around the world, the volume details the technologies that sparked the fourth revolution and illustrates their characteristics, potential, and methods of use in the industrial and societal domains. In addition, important topics such as ethics, privacy and security are considered in a reality where all data is shared and saved remotely. The collection of contribution serve a very broad audience working in the fields of science and engineering, chemical engineering, materials science, nanotechnology, energy, environment, green chemistry, sustainability, electrical and electronic engineering, solid-state physics, surface science, aerosol technology, chemistry, colloid science, device engineering, and computer technology. This handbook ideal reference libraries in universities and industrial institutions, government and independent institutes, individual research groups and scientists.

Hybrid Nanofillers for Polymer Reinforcement: Synthesis, Assembly, Characterization, and Applications provides a targeted approach to hybrid nanostructures, enabling the development of these advanced nanomaterials for specific applications.The book begins by reviewing the status of hybrid nanostructures, their current applications, and future opportunities. This is followed by chapters examining synthesis and characterization techniques, as well as interactions within nanohybrid systems. The second part of the book provides detailed chapters each highlighting a particular application area, and discussing the preparation of various hybrid nano systems that can potentially be utilized in that area. The last chapters turn towards notable state-of-the-art hybrid nanomaterials, and their properties and applications.This book is a valuable resource for researchers and advanced students across polymer science, nanotechnology, rubber technology, chemistry, sustainable materials, and materials engineering, as well as scientists, engineers, and R&D professionals with an interest in hybrid nanostructures or advanced nanomaterials for a industrial application. Provides synthesis methods, characterization techniques, and structure-property analysis for hybrid nanostructures Offers in-depth coverage focusing on specific applications across energy storage, environment, automotive, aerospace, construction, and biomedicine Includes the latest novel areas, such as elastomeric hybrid nano systems, hybrid ceramic polymer nanocomposites, and self-assembled structures