Rapid Methods Of Trace Analysis For Geochemical Applications

Handbook of Exploration Geochemistry, Volume I: Analytical Methods in Geochemical Prospecting focuses on the principles, methodologies, approaches, and techniques employed in geochemical prospecting. The book first underscores quality control in the laboratory, sample preparation, sample decomposition-solution techniques, and colorimetry and related techniques. Discussions focus on colorimetry, turbidimetric methods, strong decompositions, partial extractions, preparation of rock samples, random and systematic errors, and quality control program. The publication then takes a look at atomic absorption spectrophotometry, emission spectroscopy, and X-ray fluorescence. Concerns cover instrumentation, operation of the X-ray fluorescence spectrometer, flame emission spectroscopy, semi-quantitative DC-arc spectroscopy, and plasma sources. The text examines electrochemical methods, including determination of pH and specific ion electrodes. The publication is a dependable reference for researchers interested in the analytical methods in geochemical prospecting.

Geochemists, geologists, chemists, mathematicians, technicians and amateur prospectors alike will find this a practically oriented and comprehensive handbook for use in the field or office. It describes methodologies for assessing overburden in Arctic and temperate regions. Scientists can study the composition of bedrock by analyzing the overburden and ores found by the separation of the anomalies from the chemical background variation. This task is a very demanding one for previously glaciated terrain, where overburden consists totally of transported and mixed materials. It is possible to trace back the anomalies found in glacial till and sometimes those found in glacifluvial sediments. Special care in sampling and preparation of samples for analysis as well as very sensitive methods of analysis are necessary in obtaining results suitable for successful interpretation. The present handbook is dedicated to these vital problems. The genesis of overburden formations and the character of geochemical anomalies are discussed at length, after which examples are provided from a variety of situations. Articles concerning practical aspects of sampling, analysis and mathematical treatment, written specifically to help investigations are also included. The text is illustrated by 196 drawings, 32 tables and the selected bibliography contains 533 references. A key word list makes the handbook easy to use.

This Proceedings volume contains papers from three symposia which were held during the 29th International Geological Congress, Kyoto, Japan, 24 August--3 September 1992. From the first symposium --- ''Metamorphic Reactions: kinetics and mass transfer'' --- 5 papers were selected for publication. One of the objectives of the symposium was to clarify the nature of reactions and mass transfer from the viewpoint of kinetics. From the ''Sandstone Petrology in Relation to Tectonics''-symposium, 10 papers were selected and revised for inclusion in this book. The articles reflect the different approaches on the relationship between sandstone composition and tectonic setting. The third symposium in this volume --- ''Evaporite and Desert Environment'' consists of 8 selected papers. The papers summarize the relationship between various desertification factors and the dynamics of different regions, and the classification of these regions according to their geological and mineralogical factors.

Developments in Economic Geology, 15: Geochemical Exploration 1980 focuses on practices, processes, methodologies, and principles involved in geochemical exploration. The selection first takes a look at the simultaneous determination of sulfide, polysulfides, and thiosulfate as an aid to ore exploration; hydrogeochemical exploration for uranium ore deposits; and mercury and mercury compounds in surface air, soil gas, soils, and rocks. Discussions focus on the methods of mercury analysis, calibration, sensitivity and computations, exploration, titration of hydrogen sulfide, polysulfides, thiosulfate and sulfite, and leaching of a sulfide deposit by percolating water. The book then examines meteorological noise in crustal gas emission and relevance to geochemical exploration; a mercury vapor survey in an area of thick transported overburden in Shanghai, China; and mechanisms of ore formation and primary dispersion at the Dexing porphyry copper deposit in Jiangxi and their implications to geochemical exploration. The publication explores the organic matter of a gulf coast well studied by a thermal analysis; selective extraction procedures applied to geochemical prospecting in an area contaminated by old mine workings; and application of radionuclide energy-dispersive X-ray fluorescence analysis in geochemical prospecting. The selection is a vital source of data for researchers interested in geochemical exploration.

For some years I have felt there was a need for a single, comprehen sive, reference book on exploration geology. Numerous textbooks are available on subjects such as geophysical prospecting, exploration geochemistry, mining geology, photogeology and general economic geology, but, for the geologist working in mineral exploration, who does not require a specialist's knowledge, a general book on explora tion techniques is needed. Many undergraduate university courses tend to neglect economic geology and few deal with the more prac tical aspects in any detail. Graduate geologists embarking on a career in economic geology or mineral exploration are therefore often poorly equipped and have to learn a considerable amount 'on the job'. By providing a book that includes material which can be found in some of the standard texts together with a number of practical aspects not to be found elsewhere, I hope that both recent graduates and more experienced exploration geologists will find it a useful reference work and manual. In addition, students of economic geology and personnel working in related fields in the mining and mineral extraction in dustries will find it informative. J. H. REEDMAN v Acknowledgements The author would like to thank Dr K. Fletcher, geochemist with the Department of Geology, University of British Columbia, and Kari Savario, geophysicist with Finnish Technical Aid to Zambia, for reading the original drafts and offering constructive criticism and advice on the chapters on geochemical and geophysical prospecting respectively.