Advanced Ferroelectricity

Recent exciting advances in the field of ferroelectricity have implications both for basic physics and for technological applications such as memory devices, spintronic applications and electro-optic devices, as well as in acoustics, robotics, telecommunications and medicine. This book provides a full account of recent developments in the field.

Discover the latest advances in ferroelectric and piezoelectric material sciences with this comprehensive monograph, divided into six chapters, each offering unique insights into the field.Chapter 1 delves into the manufacture and study of new ceramic materials, focusing on complex oxides of various metals (Aurivillius phases). The authors explore layered bismuth titanates and niobates, known for their high Curie temperature, and discuss how varying their chemical composition can lead to significant changes in their electrophysical properties. Chapter 2 explores the fascinating world of ferroelectrics — dielectrics with spontaneous polarization. Mathematical models and approaches of fractional calculus are used to understand the process of polarization switching in these materials, shedding light on the fractality of electrical responses. In Chapter 3, readers gain valuable insights into the inhomogeneous polarization process of polycrystalline ferroelectrics, a crucial stage in creating piezoceramic samples for energy converters. The authors present a comprehensive mathematical model that allows the determination of various characteristics, including dielectric and piezoelectric hysteresis loops and the effect of attenuation processes.Chapter 4 focuses on state-of-the-art piezoelectric energy harvesting, discussing theoretical, experimental, and computer modelling approaches. The authors discuss piezoelectric generators (PEGs) of different types (cantilever, stack and axis) and nonlinear effects arising at their operation. Chapter 5 presents expanded test and finite element models for cantilever-type and axial-type PEGs with active elements. The studies cover various structural and electric schemes of the PEGs with proof mass, bimorph and cylindrical piezoelectric elements, and excitation loads. Finally, Chapter 6 reviews some results in the last five years, obtained in modelling the vibration of devices from piezoactive materials, including five important effects: piezoelectric, flexoelectric, pyroelectric, piezomagnetic and flexomagnetic.As a diverse addition to the literature, this book is a relevant resource for researchers, engineers, and students seeking to expand their knowledge of cutting-edge developments in this exciting field.

This comprehensive book covers recent developments in advanced dielectric, piezoelectric and ferroelectric materials. Dielectric materials such as ceramics are used to manufacture microelectronic devices. Piezoelectric components have been used for many years in radioelectrics, time-keeping and, more recently, in microprocessor-based devices. Ferroelectric materials are widely used in various devices such as piezoelectric/electrostrictive transducers and actuators, pyroelectric infrared detectors, optical integrated circuits, optical data storage and display devices.The book is divided into eight parts under the general headings: High strain high performance piezo- and ferroelectric single crystals; Electric field-induced effects and domain engineering; Morphotropic phase boundary related phenomena; High power piezoelectric and microwave dielectric materials; Nanoscale piezo- and ferroelectrics; Piezo- and ferroelectric films; Novel processing and new materials; Novel properties of ferroelectrics and related materials. Each chapter looks at key recent research on these materials, their properties and potential applications.Advanced dielectric, piezoelectric and ferroelectric materials is an important reference tool for all those working in the area of electrical and electronic materials in general and dielectrics, piezoelectrics and ferroelectrics in particular. Covers the latest developments in advanced dielectric, piezoelectric and ferroelectric materials Includes topics such as high strain high performance piezo and ferroelectric single crystals Discusses novel processing and new materials, and novel properties of ferroelectrics and related materials

This book shows how a small toolbox of experimental techniques, physical chemistry concepts as well as quantum/classical mechanics and statistical methods can be used to understand, explain and even predict extraordinary applications of these advanced engineering materials and biomolecules. It highlights how improving the material foresight by design, including the fundamental understanding of their physical and chemical properties, can provide new technological levels in the future.

This book deals with functional materials that are in the frontiers of current materials science and technology research, development and manufacture. The first of its kind, it deals with three classes of materials, (1) magnetic semiconductors, (2) multiferroics, and (3) graphene. Because of the wide popularity of these materials there is a strong need for a book about these materials for graduate students, new researchers in science and technology, as well as experienced scientists and technologists, technology based companies and government institutes for science and technology. The book will provide this broad audience with both theoretical and experimental understanding to help in technological advances in the development of devices and related new technologies based on these very interesting and novel materials. Covers both the theoretical and experimental aspects of advanced functional materials, which are important for use in a number of rapidly developing novel technological devices Includes excellent coverage of three of the leading advanced functional materials Edited by a leading expert at the forefront of advanced functional materials research

This two volume set reviews the key issues in processing and characterization of nanoscale ferroelectrics and multiferroics, and provides a comprehensive description of their properties, with an emphasis in differentiating size effects of extrinsic ones like boundary or interface effects. Recently described nanoscale novel phenomena are also addressed. Organized into three parts it addresses key issues in processing (nanostructuring), characterization (of the nanostructured materials) and nanoscale effects. Taking full advantage of the synergies between nanoscale ferroelectrics and multiferroics, the text covers materials nanostructured at all levels, from ceramic technologies like ferroelectric nanopowders, bulk nanostructured ceramics and thick films, and magnetoelectric nanocomposites, to thin films, either polycrystalline layer heterostructures or epitaxial systems, and to nanoscale free standing objects with specific geometries, such as nanowires and tubes at different levels of development. This set is developed from the high level European scientific knowledge platform built within the COST (European Cooperation in Science and Technology) Action on Single and multiphase ferroics and multiferroics with restricted geometries (SIMUFER, ref. MP0904). Chapter contributors have been carefully selected, and have all made major contributions to knowledge of the respective topics, and overall, they are among most respected scientists in the field.

Advanced Structural Chemistry Discover the relationships between inorganic chemical synthesis, structure, and property with these comprehensive and insightful volumes Advanced Structural Chemistry: Tailoring Properties of Inorganic Materials and their Applications (3 Volume Set) offers readers the opportunity to discover the relationship between the structure and function of matter, develop efficient and precise synthesis methodology, and to understand the theoretical tools for new functional substances. Advanced Structural Chemistry clarifies the relationships between synthesis and structure, as well as structure and property, both of which are central to the creation of new materials with unique functions. In addition to subjects like the syntheses of metal-oxide clusters, metal-organic cages, and metal-organic frameworks with tailored optical, electric, ferroelectric, magnetic, adsorption, separation, and catalytic properties, the accomplished editor Rong Cao provides readers with information on a wide variety of topics, such as: Coordination-assembled metal-organic macrocycles and cages, including metallacycles and metallacages The structural chemistry of metal-oxo clusters, including the oxo clusters of transition metal, main group metal, and lanthanides Synthetic approaches, structural diversities, and biological aspects of molybdenum-based heterometallic sulfide clusters and coordination polymers Group 11-15 metal chalcogenides, including discrete chalcogenide clusters synthesized in ionic liquids The structures of metal-organic frameworks, including one-, two-, and three-dimensional MOFs Perfect for inorganic chemists, structural chemists, solid state chemists, material scientists, and solid state physicists, Advanced Structural Chemistry also belongs on the bookshelves of catalytic and industrial chemists who seek to improve their understanding of the structure and functions of inorganic materials.

This is the first comprehensive book on ferroelectric memories which contains chapters on device design, processing, testing, and device physics, as well as on breakdown, leakage currents, switching mechanisms, and fatigue. State-of-the-art device designs are included and illustrated among the books many figures. More than 500 up-to-date references and 76 problems make it useful as a research reference for physicists, engineers and students.