Apatites And Their Synthetic Analogues Synthesis Structure Properties And Applications

Apatite-type minerals and their synthetic analogues are of interest of many industrial branches and scientific disciplines including material sciences, chemical industry, agriculture, geology, medicine and dentistry. This book provides a basic overview of general knowledges of this topic in order to provide the comprehensive survey from a scientific and technological perspective. The book is divided into 10 chapters, which are devoted to the structure and properties of minerals from the supergroup of apatite, experimental techniques of preparation and characterization of synthetic analogues of apatite minerals, substitution in the structure of apatite as well as utilization of these materials in wide range of common and special advanced applications in industry, material sciences and research. Additionally, the phosphate rocks, their classification, geological role, mining and beneficiation of phosphate ore, production of elemental phosphorus, phosphoric acid and fertilizers are also described. Although this book is meant for chemist, material scientist and research engineers, the individual chapters contain theoretical background, historical aspects as well as examples of synthetic and analytical methods which may be also interesting for students and non-expert readers as well.

Essential reference for researchers and experts in industry highlighting the rapidly growing field of hydroxyapatite-based catalysts and their application in various chemical processes. Hydroxyapatite (Ca10(PO4)6(OH)2) is the main mineral component of human and animal bones. It is largely applied in the field of biomaterials due to its biocompatibility. Recently, hydroxyapatite-based materials have especially gained a lot of attention by researchers in catalysis, as they are versatile and have shown precious properties of a good catalyst and catalyst support such as excellent ion-exchange capacity, high porosity, very low water solubility, controlled basicity/acidity, and good thermal stability at high temperatures. Design and Applications of Hydroxyapatite-Based Catalysts gives a detailed overview of the synthesis, characterization, and use of hydroxyapatite-based materials in catalysis. It covers synthetic hydroxyapatites (from pure chemicals or waste), natural apatites and materials from eggshells and animal bones. The application of hydroxyapatite-based catalysts in selective oxidation, deoxygenation, selective hydrogenation, dehydrogenation reactions, organic synthesis, as well as reforming processes and production of energy carriers is reviewed. Moreover, electrocatalysis and photocatalysis using hydroxyapatite-based materials are discussed. Kinetic and mechanism studies of various chemical pro-cesses over hydroxyapatite-based catalysts are also presented. This is the first book solely dedicated to hydroxyapatite-based materials and their use in catalysis. Covers synthesis and characterization, surface and structure studies, kinetic and mechanism aspects, and various applications in heterogeneous catalysis, electrocatalysis, and photocatalysis. Aimed at further stimulating research in the field Design and Applications of Hydroxyapatite-Based Catalysts is an indispensable source-of-information for researchers in academia and industry working in catalysis.

The book represents a collection of papers presented at VII International Symposium "Biogenic-abiogenic interactions in natural and anthropogenic systems" that was held on 26-29 September 2022 in Saint Petersburg (Russia). Papers in this book cover a wide range of topics connecting with interactions between biogenic and abiogenic components in lithosphere, biosphere and technosphere. The main regarding topics are following: biomineralization in living organisms and nature-like materials; biomineralization in geosystems; geochemistry of biogenic-abiogenic systems; biomineral interactions in soil; interaction of microorganisms with natural and artificial materials; medical geology; philosophical aspects of interdisciplinary researchs

Recovery of Values from Low-Grade and Complex Minerals The book elaborates on various physicochemical properties of minerals and technological developments to improve the recovery of metals while ensuring cost-effectiveness and minimal environmental impact. The mineral industry is undergoing significant cultural, organizational, and technological transformations to address some of the major limitations and challenges related to the environmental and productivity domains. As far as productivity is concerned, the decrease of high-grade ores has been one of the stumbling blocks toward the achievement of maximum recovery of metals while, on the other hand, the complexity of minerals therein makes it difficult to profitably extract metals using only conventional methods. This book presents eight specialized chapters that focus on the exploration of the complexity of minerals that are likely to negatively influence the recovery of values, as well as the development of adequate technologies capable of improving the process of mineral concentration and/or metal recovery from complex minerals in a sustainable manner. It reviews the various physicochemical properties of minerals that are likely to pose a challenge during the attempt to recover values using conventional methods. It also elaborates on the recent technological development that has been considered by researchers to improve the recovery of metals from gangue-dominated minerals while ensuring cost-effectiveness and minimal adverse environmental impact. Audience This book will be of interest to academic researchers from the fields of mineral processing, hydrometallurgy, geochemistry, environment, chemistry, engineering, and professionals including mining plant operators, environmental managers in the industries, government regulatory bodies officers, and environmentalists.

This book highlights the synthesis, luminescence, and applications of rare earth-doped phosphors materials for solid-state lighting. Solid-state lighting is turning into a leading technology in the lighting industry, permitting improvement in the fields from architectural to domestic applications. Driven with the aid of using ongoing multi-field research, solid-state lighting needs an improvement of various technologies: efficient and reliable light-emitting devices, devices for new functionalities, and optical solutions for beam shaping. Noteworthy research endeavors were aimed to find out eco-friendly, better performance, cost, and energy-efficient phosphor materials for the application in solid-state lighting devices. Power phosphor materials with advanced optical and photoluminescence properties in a wide range of areas have shared the research efforts in this sector aimed in the direction of achieving better material features. Rare earth ion-doped phosphor materials have been the subject of scientific interest because of their significant applications in a variety of fields such as display devices, temperature sensors, solar cells, bio-imaging, and optoelectronics devices. This book covers the broad aspects of organic and inorganic materials based on phosphor materials and is beneficial to researchers involved in these areas. This book is specially designed to provide an introductory concept of luminescent materials, particularly man-made (artificial) phosphors in a language comprehensible to beginners and students. The book also includes some new materials with promising technologies and upgraded properties that expose new potential possibilities are also highlighted.

Due to a great chemical similarity with the biological calcified tissues, many calcium orthophosphates possess remarkable biocompatibility and bioactivity. Materials scientists use this property extensively to construct artificial bone grafts that are either entirely made of or only surface-coated with the biologically relevant calcium orthophospha

The apatites and related calcium phosphates have been of considerable interest to biologists, mineralogists, and inorganic and industrial chemists for many years. This book contains a detailed description of the structures and structural interrelationships of the calcium orthophosphates, including the apatites. Their preparation, crystal growth and dissolution, chemical reactions including thermal decomposition, IR, Raman and NMR spectra and various physical properties are discussed. Apatites other than those containing calcium and phosphorus are included. Synthetic, mineral and biological carbonate apatites are also considered. A wide, but critical coverage of the literature is given, which includes a substantial amount not written in English. Research from many disciplines is included which results in a comprehensive compilation of recent work.