Atomic Spectroscopy

This book describes the basic physical principles of atomic spectroscopy and the absorption and emission of radiation in astrophysical and laboratory plasmas. It summarizes the basics of electromagnetism and thermodynamics and then describes in detail the theory of atomic spectra for complex atoms, with emphasis on astrophysical applications. Both equilibrium and non-equilibrium phenomena in plasmas are considered. The interaction between radiation and matter is described, together with various types of radiation (e.g., cyclotron, synchrotron, bremsstrahlung, Compton). The basic theory of polarization is explained, as is the theory of radiative transfer for astrophysical applications. Atomic Spectroscopy and Radiative Processes bridges the gap between basic books on atomic spectroscopy and the very specialized publications for the advanced researcher: it will provide under- and postgraduates with a clear in-depth description of theoretical aspects, supported by practical examples of applications.

The standard comprehensive work on the theory of atomic spectra. "...a work of the first rank...." Nature

"Provides a thorough, up-to-date survey of techniques for elemental analysis--including atomic absorption spectroscopy, atomic fluorescence, flame photometry, emission spectroscopy, and plasma emission. Second Edition includes expanded material on interfaced plasma-mass spectrometry (ICP-MS), diode arrays, and other emerging spectroscopic fields."

W. HANLE and H. KLEINPOPPEN In 1919, in the first edition of Atombau and Spektrallinien, Sommerfeld referred to the immense amount of information which had been accumu lated during the first period of 60 years of spectroscopic practice. Sommer feld emphasized that the names of Planck and Bohr would be connected forever with the efforts that had been made to understand the physics and the theory of spectral lines. Another period of almost 60 years has elapsed since the first edition of Sommerfeld's famous monograph. As the editors of this monograph, Progress in Atomic Spectroscopy, we feel that the present period is best characterized by the large variety of new spec troscopic methods that have been invented in the last decades. Spectroscopy has always been involved in the field of research on atomic structure and the interaction of light and atoms. The development of new spectroscopic methods (i.e., new as compared to the traditional optical methods) has led to many outstanding achievements, which, together with the increase of activity over the last decades, appear as a kind of renaissance of atomic spectroscopy.

The book includes various spectroscopic techniques including atomic spectroscopy, pure rotational spectroscopy, vibrational spectroscopy of diatomic and polyatomic molecules, Raman spectroscopy and electronic spectroscopy. Solved and unsolved exercises are provided throughout the book for easy understanding and better assessment.

In the 1920s, when quantum mechanics was in its infancy, chemists and solid state physicists had little choice but to manipulate unwieldy equations to determine the properties of even the simplest molecules. When mathematicians turned their attention to the equations of quantum mechanics, they discovered that these could be expressed in terms of group theory, and from group theory it was a short step to operator methods. This important development lay largely dormant until this book was originally published in 1963. In this pathbreaking publication, Brian Judd made the operator techniques of mathematicians comprehensible to physicists and chemists. He extended the existing methods so that they could handle heavier, more complex molecules and calculate their energy levels, and from there, it was another short step to the mathematical analysis of spectra. This book provides a first-class introduction to continuous groups for physicists and chemists. Although first written from the perspective of atomic spectroscopy, its major topics and methods will appeal to anyone who has an interest in understanding particle theories of nuclear physics. Originally published in 1998. The Princeton Legacy Library uses the latest print-on-demand technology to again make available previously out-of-print books from the distinguished backlist of Princeton University Press. These editions preserve the original texts of these important books while presenting them in durable paperback and hardcover editions. The goal of the Princeton Legacy Library is to vastly increase access to the rich scholarly heritage found in the thousands of books published by Princeton University Press since its founding in 1905.

My previous book on the theory of atomic spectra was published in Russian about fifteen years ago. Besides the traditional problems usually included in a book on atomic spectroscopy, some other problems arising in various applications of spectroscopic methods were also discussed in the book. These include, for example, continuous spectrum radiation, excitation of atoms, and spectral line broadening. Extensive revisions were made in the English version of the book published by the Pergamon Press in 1972, especially in the chapter devoted to the problem of excitation of atoms. This book is intended as the first part of a two-volume presentation of the theory of atomic spectra, atomic radiative transitions, excitation of atoms, and spectral line broadening. The aim in preparing these new books has been to stress the problems connected with the most interesting applications of atomic spectroscopy to plasma diagnostics, astrophysics, laser physics, and other fields, which have been developed very intensively in recent years. The content of this first volume, devoted to the systematics of atomic spectra and radiative transitions, is similar to that of Chapters 1-6, 8 and 9 of the old book, but considerable revision has been made. Some sections, such as those on the Hartree-Fock method, the Dirac equation, and relativistic corrections, have been deleted. At the same time, more attention is paid to radiative transitions. More extensive tables of oscillator strengths, prob abilities, and effective cross sections of radiative transitions in discrete and continuous spectra are given.

Analysis of water. Analysis of geological materials. Analysis of organic samples. Analysis of metals and alloys. Analysis of air samples. Analysis of petroleum and petroleum products. Analysis of industrial samples. Determination of metal compounds. Expected new developments in atomic spectroscopy.