Beyond The Second Law

The Second Law, a cornerstone of thermodynamics, governs the average direction of dissipative, non-equilibrium processes. But it says nothing about their actual rates or the probability of fluctuations about the average. This interdisciplinary book, written and peer-reviewed by international experts, presents recent advances in the search for new non-equilibrium principles beyond the Second Law, and their applications to a wide range of systems across physics, chemistry and biology. Beyond The Second Law brings together traditionally isolated areas of non-equilibrium research and highlights potentially fruitful connections between them, with entropy production playing the unifying role. Key theoretical concepts include the Maximum Entropy Production principle, the Fluctuation Theorem, and the Maximum Entropy method of statistical inference. Applications of these principles are illustrated in such diverse fields as climatology, cosmology, crystal growth morphology, Earth system science, environmental physics, evolutionary biology and technology, fluid turbulence, microbial biogeochemistry, plasma physics, and radiative transport, using a wide variety of analytical and experimental techniques. Beyond The Second Law will appeal to students and researchers wishing to gain an understanding of entropy production and its central place in the science of non-equilibrium systems – both in detail and in terms of the bigger picture.

This book presents a coherent formulation of all aspects of thermodynamics and statistical mechanics with entropy as the unifying theme. By consolidating these approaches into a coherent and self-contained framework, it is intended to improve the understanding of this fundamental and fascinating area of physics.

Entropy is fundamental to the physical universe, and its applications beyond the Second Law of Thermodynamics to classical time-dependent systems and to quantum condensed matter lie at the frontiers of science.

The advance of scienti?c thought in ways resembles biological and geologic transformation: long periods of gradual change punctuated by episodes of radical upheaval. Twentieth century physics witnessed at least three major shifts — relativity, quantum mechanics and chaos theory — as well many lesser ones. Now, st early in the 21 , another shift appears imminent, this one involving the second law of thermodynamics. Over the last 20 years the absolute status of the second law has come under increased scrutiny, more than during any other period its 180-year history. Since the early 1980’s, roughly 50 papers representing over 20 challenges have appeared in the refereed scienti?c literature. In July 2002, the ?rst conference on its status was convened at the University of San Diego, attended by 120 researchers from 25 countries (QLSL2002) [1]. In 2003, the second edition of Le?’s and Rex’s classic anthology on Maxwell demons appeared [2], further raising interest in this emerging ?eld. In 2004, the mainstream scienti?c journal Entropy published a special edition devoted to second law challenges [3]. And, in July 2004, an echo of QLSL2002 was held in Prague, Czech Republic [4]. Modern second law challenges began in the early 1980’s with the theoretical proposals of Gordon and Denur. Starting in the mid-1990’s, several proposals for experimentally testable challenges were advanced by Sheehan, et al. By the late 1990’s and early 2000’s, a rapid succession of theoretical quantum mechanical ? challenges were being advanced by C ́ apek, et al.

Long ago his mother had routinely cleaned the windows of the family home to invisibility. But the glass had shut him away nevertheless, a fading print of a boy, a creature as flat and boneless as the paper animals taped on the plaster. The symptoms of chronic disease had excluded him from the world outside-and the world inside, created from books piled high in the sickroom provided small compensation for his expected death. Only the vast histories of human conflict were a consolation. His reading and rereading of them intensified the enmity that nourished his remaining strength. Or that's what he chose to remember as he looked down on the quiet street below. In The Second Law of Dying, the ghostly presence of Nobel laureate Dr. Albert Schweitzer lays out the map of moral choices for Dr. Hugo Haultain as he grinds his way through the abyss of degradation that poisons his life. Across several continents and ending in Schweitzer's remote African hospital, varying and inevitable circumstances give the notorious and depleted Dr. Haultain the daily option of turning violently on the world-or not.

A novel approach to the unresolved issues of theoretical physics and the philosophy/foundations of physics.

This book is a brief and accessible popular science text intended for a broad audience and of particular interest also to science students and specialists. Using a minimum of mathematics, a number of qualitative and quantitative examples, and clear illustrations, the author explains the science of thermodynamics in its full historical context, focusing on the concepts of energy and its availability and transformation in thermodynamic processes. His ultimate aim is to gain a deep understanding of the second law—the increase of entropy—and its rather disheartening message of a universe descending inexorably into chaos and disorder. It also examines the connection between the second law and why things go wrong in our daily lives. Readers will enhance their science literacy and feel more at home on the science side of author C. P. Snow's celebrated two-culture, science-humanities divide, and hopefully will feel more at home in the universe knowing that the disorder we deal with in our daily lives is not anyone's fault but Nature's.

Beyond Einstein’s Gravity is a graduate level introduction to extended theories of gravity and cosmology, including variational principles, the weak-field limit, gravitational waves, mathematical tools, exact solutions, as well as cosmological and astrophysical applications. The book provides a critical overview of the research in this area and unifies the existing literature using a consistent notation. Although the results apply in principle to all alternative gravities, a special emphasis is on scalar-tensor and f(R) theories. They were studied by theoretical physicists from early on, and in the 1980s they appeared in attempts to renormalize General Relativity and in models of the early universe. Recently, these theories have seen a new lease of life, in both their metric and metric-affine versions, as models of the present acceleration of the universe without introducing the mysterious and exotic dark energy. The dark matter problem can also be addressed in extended gravity. These applications are contributing to a deeper understanding of the gravitational interaction from both the theoretical and the experimental point of view. An extensive bibliography guides the reader into more detailed literature on particular topics.