Copper Silver Gold Zinc Cadmium Mercury Oxides Hydroxides

Interest in the title compounds has fallen into three phases: initial study of their solution chemistry, study of their role in the electrode reactions of alkaline batteries during and since World War II, and present concern over the mechanisms by which these elements can enter the environment through dissolution processes, sometimes with toxic results. This volume provides a complete compilation of solubility data published up to 1984, including all pertinent articles, together with critical evaluations of the data. Almost all the measurements relate to aqueous systems.

This volume contains evaluated data on the solubility of beryllium hydroxide, magnesium hydroxide, calcium hydroxide, strontium hydroxide and barium hydroxide in water and in a number of electrolyte and nonelectrolyte solutions in water. The alkaline earth hydroxides can be divided into two groups depending on the hydration of the solid. First, the sparingly soluble anhydrous beryllium, magnesium and calcium hydroxides, whose freshly precipitated solids are poorly crystalline and show decreasing solubility with aging, and whose solubility in water decreases with increasing temperature. Second, the soluble strontium and barium hydroxide octahydrates that form crystalline precipitates which do not show changes in solubility on aging, and whose solubility in water increases with increasing temperature.

Metal ions play an important role in analytical chemistry, organometallic chemistry, bioinorganic chemistry, and materials chemistry. This book, Descriptive Inorganic Chemistry Researches of Metal Compounds, collects research articles, review articles, and tutorial description about metal compounds. To perspective contemporary researches of inorganic chemistry widely, the kinds of metal elements (typical and transition metals including rare earth; p, d, f-blocks) and compounds (molecular coordination compounds, ionic solid materials, or natural metalloenzyme) or simple substance (bulk, clusters, or alloys) to be focused are not limited. In this way, review chapters of current researches are collected in this book.

Copper and Silver Halates is the third in a series of four volumes on inorganic metal halates. This volume presents critical evaluations and compilations for halate solubilities of the Group II metals. The solubility data included in this volume are those for the five compounds, copper chlorate and iodate, and silver chlorate, bromate and iodate.

An element of obvious importance, mercury is also hazardous in the environment and corrosive to many materials. A knowledge of its solubility is inestimable in addressing problems concerning the element's concentration in our surroundings. This volume presents all relevant data published on the solubility of mercury up to June 1986. By combining these data with the mercury equilibrium vapour pressure, Henry's constant and Ostwald coefficients can be calculated.

The volume covers binary amalgams of all the metals, together with those of carbon, silicon and boron, a total of 76 systems. Complete literature coverage extends through 1983. The emphasis is on accurate, evaluated solubility data, but phase diagrams have been included where they have been defined, and will aid the reader in assigning the solid-liquid equilibrium. Tha data have been critically evaluated, and are classified as 'recommended' when independent determinations agree within experimental error. The data may also be used to compute thermodynamic properties of the binary components.

Intermetallic Compounds in Mercury is Volume 51 of the Solubility Data Series. It follows Volume 25, Metals in Mercury, of the same series. Evaluations of more than fifty systems are presented together with all of the data and citations from the original literature. In addition, over 200 references are given to related literature that describes metal interactions in amalgams but from which quantitative information can only be inferred. For each compound reported, a critical evaluation presents recommended or tentative values of solubilities or solubility products based on statistical treatment of the data reported. Mercury provides a unique solvent for metal-metal reactions, and thus the data reported here are a valuable addition to the experimental basis for better fundamental understanding of interactions of metals in the elemental state. In addition, this material is important technologically in the areas of metal processing, materials, and electrochemistry.