Crystal Structures

Crystals and Crystal Structures is an introductorytext for students and others who need to understand the subjectwithout necessarily becoming crystallographers. Using the book willenable students to read scientific papers and articles describing acrystal structure or use crystallographic databases with confidenceand understanding. Reflecting the interdisciplinary nature of the subject the bookincludes a variety of applications as diverse as the relationshipbetween physical properties and symmetry, and molecular and proteincrystallography. As well as covering the basics the book containsan introduction to areas of crystallography, such as modulatedstructures and quasicrystals, and protein crystallography, whichare the subject of important and activeresearch. A non-mathematical introduction to the key elements of thesubject Contains numerous applications across a variety ofdisciplines Includes a range of problems and exercises Clear, direct writing style "…the book contains a wealth of information and itfulfils its purpose of providing an interesting and broadintroduction to the terpenes." CHEMISTRY WORLD, February2007

This classic text is devoted to describing crystal structures, especially periodic structures, and their symmetries. Updated material prepared by author enhances presentation, which can serve as text or reference. 1996 edition.

This survey of the important types of inorganic and organic crystal structures treats its subject thoroughly and in sufficient depth for undergraduate modules in chemistry courses. Features of this book are the instructions for 3D stereoviewing which is central to a full appreciation of the presentation. Clear directions for making your own stereo have been provided in the book, which enables readers to examine the plentiful stereo of lattices and crystal structures which are illustrated. The introductory chapter explains point-group and space-group symmetry insofar as required to understand lattices and crystal structures. Crystal structures are sub-divided according to the atomic force mainly responsible for cohesion in the solid state, The descriptions of the structures are gi in crystallographic terms, including data on the space group, molecular symmetry and molecular geometry. Discussions of bonding theory for each sub-division of the structures enhance and strengthen the author’s presentation. The book stems from the author’s successful lecture courses, tested and refined in class teaching. It draws as necessary on equilibrium thermodynamics and other chemical topics, with avoidance of advanced mathematics, A level being the prerequisite. Examines the important types of inorganic and organic crystal structures Includes instructions for making simple stereoviewers and computer programs Draws, as necessary, on equilibrium thermodynamics and other chemical topics, with avoidance of advanced mathematics

A volume which includes entries on quasicrystals, icosahedral packing, other packing considerations, extended structures, data treatment and data mining is presented by luminaries from the crystallography community. Several of the contributions are from the schools of such trend-setting crystallographers as J. Desmond Bernal and Aleksandr I. Kitaigorodskii. Internationally renowned scientists contributed such as Tom L. Blundell, Johann Jacob Burckhardt, John L. Finney, Jenny P. Glusker, Nobel laureate Herbert A. Hauptman, the 2014 Ewald-Prize winner A. Janner, Aminoff-Prize winner Isabella Karle, Nobel laureate Jerome Karle, Buckley-Prize winner Alan L. Mackay, Ewald-Prize winner David Sayre, Vladimir Shevchenko, and J. Fraser Stoddart. A few frontier topics dominate the selected material. Pioneers of the direct methods describe the phase problem and how it was solved, including the mathematical approach and the utilization of experience with gas-phase electron diffraction. The reviews by Herbert Hauptman, Jerome and Isabella Karle, and David Sayre reach to the present day in assessing the possibilities of X-ray crystallography. Another focus topic is the investigation of systems that are outside the so-called classical system of crystals. They include quasicrystals, imperfect and very small crystals, supramolecular species, crystal structures without lattice, clusters, nanomaterials among others. Application of synchrotron and cryoprotection techniques, the free-electron laser flash technique and others are mentioned in addition to X-ray crystallography. The relationship between structural and materials properties are examined and uncovered. The broader topics of the so-called generalized crystallography include polymers, clusters, polydisperse chain assemblies, and giant icosahedral fullerenes. There are some key contributions related to the structural investigation of biological macromolecules.

This volume is devoted to the electron and phonon energy states of inorganic layered crystals. The distinctive feature of these low-dimensional materials is their easy mechanical cleavage along planes parallel to the layers. This feature implies that the chemical binding within each layer is much stronger than the binding between layers and that some, but not necessarily all, physical properties of layered crystals have two-dimensional character. In Wyckoff's Crystal Structures, SiC and related com pounds are regarded as layered structures, because their atomic layers are alternately stacked according to the requirements of cubic and hexagonal close-packing. How ever, the uniform (tetrahedral) coordination of the atoms in these compounds excludes the kind of structural anisotropy that is fundamental to the materials dis cussed in this volume. An individual layer of a layered crystal may be composed of either a single sheet of atoms, as in graphite, or a set of up to five atomic sheets, as in Bi2 Te3' A layer may also have more complicated arrangements of the atoms, as we find for example in Sb S . But the unique feature common to all these materials is 2 3 the structural anisotropy, which directly affects their electronic and vibrational properties. The nature of the weak interlayer coupling is not very well understood, despite the frequent attribution of the coupling in the literature to van der Waals forces. Two main facts, however, have emerged from all studies.

The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students.

This book presents and discusses those common crystal structures that would be encountered by students taking chemistry, or any subject within which chemistry forms a significant component. With many worked examples and a wide selection of problems with solutions. Includes instructions for making simple stereoviewers and computer programs, in a thorough treatment of binary alloys and three-dimensional packing in molecular solids.

An authoritative, updated text that offers an introduction to crystals and crystal structure with coverage of crystallography, and microscopy of materials Written in a friendly, non-mathematical style, the updated second edition of Crystals and Crystal Structures offers a comprehensive exploration of the key elements of crystals and crystal structures. Starting with the basics, it includes information on multiple areas of crystallography, including modulated structures, quasicrystals and protein crystallography, and interdisciplinary applications as diverse as the relationship between physical properties and symmetry. To enhance comprehension of the material presented, the book contains a variety of problems and exercises. The revised second edition offers new material and updates in the field including: An introduction to the use of high intensity X-ray analysis of protein structures Advances in imaging, scanning electron microscopy, and cryo-electron microscopy The relationship between symmetry and physical properties highlighting new findings and an introduction to tensor notation in describing these relationships in a concise fashion Nanoparticles as well as crystallographic aspects, defects, surface defects and the impact of these crystallographic features on properties Perovskite structures and their variations and the inclusion of their wide-ranging properties Written for students ofcrystallography, chemistry, physics, materials science, biosciences and geology, Crystals and Crystal Structures, Second Edition provides an understanding of the subject and enables students to read scientific papers and articles describing a crystal structure or use crystallographic databases.