Dynamic Processes In Solids

The results obtained from kinetic studies on reactions in solids often depend on numerous factors. Therefore, it is important for researchers to understand how both chemical factors related to composition and procedural choices may influence outcomes. Dynamic Processes in Solids provides an authoritative overview of reactions in solids and helps readers interpret the results obtained from kinetic studies. In chapters written by active researchers, the reader will learn about choosing appropriate experimental techniques and their limitations for studying various types of reactions. Beginning with an introduction to numerous aspects of rate processes in solids and experimental techniques, information is provided on rate laws, factors affecting rates, diffusion, and sintering. Subsequent chapters deal with electrical conductivity in dispersed phase polymers, thermochemical reactions for producing solid materials, reactions in coordination compounds, dynamic observations on plastic deformation, light driven phenomena in quantum materials, decomposition of perovskite photovoltaic compounds, and reaction of oxygen radicals with surfaces. This book is a practical introduction to the field for chemists and researchers whose work is directly related to dynamic changes in solids, and additionally for those in related fields whose work would be enhanced by an understanding of these types of rate processes. Presents useful discussions of the applications of several experimental techniques Describes approaches for synthesis of solid materials by thermochemical reactions Presents theoretical interpretation structural dynamics and processes at the molecular level in solids Provides information on the relationships between performance and rate processes in several types of materials related to electronic behavior

When we see a jumbo jet at the airport, we sometimes wonder how such a huge, heavy plane can fly high in the sky. To the extent that we think in a static way, it is certainly not understandable. In such a manner, dynamics yields behavior quite different from statics. When we want to prepare an iron nitride, for example, one of the most orthodox ways is to put iron in a nitrogen atmosphere under pressures higher than the dissociation pressure of the iron nitride at temperatures sufficiently high to let the nitrogen penetrate into the bulk iron. This is the way thermodynamics tells us to proceed, which requires an elaborate, expensive high-pressure apparatus, sophisticated techniques, and great efforts. However, if we flow ammonia over the iron, even under low pressures, we can easily prepare the nitride-provided the hydrogen pressure is sufficiently low. Since the nitrogen desorption rate is the determining step of the ammonia decomposition on the iron surface, the virtual pressure of nitrogen at the surface can reach an extremely high level (as is generally accepted) because, in such a dynamic system, the driving force of the ammonia decomposition reaction pushes the nitrogen into the bulk iron to form the nitride. Thus, dynamics is an approach considerably different from statics.

This book presents the latest advances in flowsheet simulation of solids processes, focusing on the dynamic behaviour of systems with interconnected solids processing units, but also covering stationary simulation. The book includes the modelling of solids processing units, for example for comminution, sifting and particle formulation and also for reaction systems. Furthermore, it examines new approaches for the description of solids and their property distributions and for the mathematical treatment of flowsheets with multivariate population balances.

This book commemorates the 60th birthday of Dr. Wim van Horssen, a specialist in nonlinear dynamic and wave processes in solids, fluids and structures. In honor of Dr. Horssen’s contributions to the field, it presents papers discussing topics such as the current problems of the theory of nonlinear dynamic processes in continua and structures; applications, including discrete and continuous dynamic models of structures and media; and problems of asymptotic approaches.

This book presents theoretical and experimental investigations of mechanical behavior of solids under shock loading and highlights a multi-scale exchange process of energy and momentum between meso and macroscopic hierarchy. It also widely covers experimental approaches for the multi-scale response of solids to impacts including uniaxial strain conditions and high-velocity penetration processes. The content comprises two parts. The first part overviews modeling and theory of dynamically deformed solids from the multi-scale point of view. The second part describes experimental characterization of shock-induced solids and experimental probing of mesostructured and mesoscale dynamic processes in solids. The theory presented in the first part is then verified as it is compared with i) experiments of shock loading into different kinds of solids and ii) probed microstructure of post-shocked specimens by scanning electron microscopy, transmission electron microscopy and optical microscopy. The text is written on the basis of author’s lectures at universities and thus is concisely described for postgraduate students. It is also useful for researchers who work on the theory of multi-scale mechanics of solids and engineers who work on testing materials under dynamic loading.

1. The fundamental hypothesis of microstructured elastic solids. Structural-phenomenological model. 1.1. Mathematical models of solids with microstructure. 1.2. Definition of material constants -- 2. Gradient elasticity media. Dispersion. Dissipation. Non-linearity. 2.1. Dynamic equations. Energy and momentum variation law. 2.2. Dispersion properties of longitudinal and shear waves. Surface Rayleigh waves. 2.3. Dissipative properties. 2.4. Nonlinear plain stationary waves. 2.5. Quasi-plain wave beams. 2.6. Self-modulation of quasi-harmonic shear waves. 2.7. Resonant interaction of quasi-harmonic waves. 2.8. Noise waves -- 3. Gradient elasticity media. Damaged medium. Magnetoelasticity. 3.1. Waves in damaged medium with microstructure. 3.2. Magneto-elastic waves in the medium with microstructure -- 4. Cosserat continuum. 4.1. Basic equations of micropolar elasticity theory. 4.2. Dispersion properties of volume waves. 4.3. Wave reflection from the free interface of micropolar halfspace. Rayleigh surface waves. 4.4. Normal waves in a micropolar layer. 4.5. Nonlinear resonant interaction of longitudinal and rotation waves. 4.6. Waves in Cosserat pseudocontinuum. 4.7. Waves in the Cosserat continuum with symmetric stress tensor -- 5. Waves in two-component mixture of solids. 5.1. Dispersion properties. 5.2. Some nonlinear wave effects -- 6. Waves in micromorphic solids. 6.1. Dynamics equations. 6.2. Different types of volume waves and their dispersion properties. 6.3. Surface shear waves in the gradient-elastic half-space with surface energy -- 7. Elasto-plastic waves in the medium with dislocations. 7.1. Equations of dynamics. 7.2. Dispersion properties. 7.3. Some nonlinear problems. 7.4. Correlation of elasto-plastic continuum and Cosserat continuum. 7.5. Example of research of the influence of dislocations on dispersion and damping of ultrasound in solid body -- 8. Wave problems of micropolar hydrodynamics. 8.1. Rotational waves in micropolar liquids. 8.2. Shear surface wave at the interface of elastic body and micropolar liquid. 8.3. Shear surface wave at the interface between elastic half-space and conducting viscous liquid in a magnetic field.

This two-volume work covers ultrafast structural and electronic dynamics of elementary processes at solid surfaces and interfaces, presenting the current status of photoinduced processes. Providing valuable introductory information for newcomers to this booming field of research, it investigates concepts and experiments, femtosecond and attosecond time-resolved methods, as well as frequency domain techniques. The whole is rounded off by a look at future developments.