Electrochemical Methods Of Nanostructure Preparation

This book summarizes the electrochemical routes of nanostructure preparation in a systematic and didactic manner. It provides a comprehensive overview of electrodeposition, anodization, carbon nanotube preparation and other methods of nanostructure fabrication, combining essential information on the physical background of electrochemistry with materials science aspects of the field. The book includes a brief introduction to general electrochemistry with an emphasis on physico-chemical aspects, followed by a description of the sample preparation methods. In each chapter, an overview of the particular method is accompanied by a discussion of the relevant physical or chemical properties of the materials, including magnetic, mechanical, optical, catalytic, sensoric and other features. While some preparation methods are discussed in connection with the theories of physical electrochemistry (e.g. electrodeposition), the book also covers methods that are more heuristic but nonetheless utilize electric current (e.g. anodization of porous alumina or synthesis of carbon nanotubes by means of electric arc discharge).

Providing the unique and vital link between the worlds of electrochemistry and nanomaterials, this reference and handbook covers advances in electrochemistry through the nanoscale control of electrode structures, as well as advances in nanotechnology through electrochemical synthesis strategies. It demonstrates how electrochemical methods are of great scientific and commercial interest due to their low cost and high efficiency, and includes the synthesis of nanowires, nanoparticles, nanoporous and layered nanomaterials of various compositions, as well as their applications -- ranging from superior electrode materials to energy storage, biosensors, and electroanalytical devices.

Engineering of nanophase materials and devices is of vital interest in electronics, semiconductors and optics, catalysis, ceramics and magnetism. Research associated with nanoparticles has widely spread and diffused into every field of scientific research, forming a trend of nanocrystal engineered materials. Electrochemical methods are widely used for the preparation of nanoparticles and the electrochemical properties of such nanomaterials are most relevant for their applications. This comprehensive reference work will appeal to advanced graduate students and researchers in the field specialized in electrochemistry, materials physics and materials science.

For centuries, electrochemistry has played a key role in technologically important areas such as electroplating or corrosion. In recent decades, electrochemical methods are receiving increasing attention in important strongly growing fields of science and technology such as nanosciences (nanoelectrochemistry) and life-sciences (organic and biological electrochemistry). Characterization, modification and understanding of various electrochemical interfaces or electrochemical processes at the nanoscale, has led to a huge increase of the scientific interest in electrochemical mechanisms as well as of application of electrochemical methods in novel technologies. This book presents exciting emerging scientific and technological aspects of the introduction of the nanodimension in electrochemical approaches are presented in 12 chapters/subchapters.

The book is devoted to novel nanostructured materials and nanotechnology. A comprehensive analysis of the condensing methods of preparation of novel nanostructured materials is given. The methodology of power-consuming preparation of nanostructured materials is discussed, including thermolysis, photo- and radiolytic, electrochemical and mechanochemical methods. The peculiarities of chemical transformations in organic and inorganic matrices are compared. Special attention is given to kinetics and mechanism of the formation of nanocomposites. The structure and properties of such nanostructured materials are analysed.

This book provides an overview of electrodeposition of nanomaterials from principles to modern concepts for advanced materials in science and technology. Electrochemical deposition or electrodeposition is explained for fabrication and mass production of functional and nanostructured device materials. The present book spans from principles to modern insights and concepts. It gives a comprehensive overview of the electrochemistry of materials, which is useful as basic information to understand concepts used for nanostructuring of electrodeposited materials, reviews the electrodeposition constituents, thermodynamics and kinetics of electrodeposition, electrochemical and instrumental assessment techniques and other physical factors affecting the electrodeposition mechanisms. A wide variety of nanostructured materials and related concepts and applications are explained with respect to nanocrystals, nanocrystalline films, template-based nanostructures, nanocomposite films, nanostructures on semiconductors, multilayers, mesoporous films, scanning microscopical probe assisted fabrication and galvanic replacement. This book is useful for researchers in materials science, engineering technologists and graduate students. It can also be used as a textbook for undergraduates and graduate students studying related disciplines.

This edited book is devoted to different electrochemical aspects of nano materials. This comprehensive reference text is basically divided in 3 parts: electrochemical synthesis routes for nanosized materials, electrochemical properties of nano materials and electrochemical characterization methods for nanostructures. The Handbook is a reference work to chemists and materials scientists interested in the nano aspects of electrochemistry. The chapters are written by a number of international experts in the field and the content will assist members of both electrochemical and materials communities to keep abreast of developments in the field.

Volume XVII in the "Advances in Electrochemical Science and Engineering" series, this monograph covers progress in this rapidly developing field with a particular emphasis on important applications, including spectroscopy, medicinal chemistry and analytical chemistry. As such it covers nanopatterned and nanoparticle-modified electrodes for analytical detection, surface spectroscopy, electrocatalysis and a fundamental understanding of the relation between the electrode structure and its function. Written by a group of international experts, this is a valuable resource for researchers working in such fields as electrochemistry, materials science, spectroscopy, analytical and medicinal chemistry.