Electronic Properties Of Polymers And Related Compounds

At the International Winter School on "Electronic Properties of Polymers and Related Compounds" particular attention was paid to a very new and special field in polymer research. It is concerned with the study of the electronic structure of polymers and with physical and chemical properties directly re lated to this structure. In particular, tutorial and research contributions on electrical, electrochemical, optical, magnetic, lattice dynamical and structural properties were presented. In addition, review reports on related topics such as charge transfer complexes and linear-chain compounds (transi tion-metal trichalcogenides) were included. In two discussion meEjtings, the special role of polyacetylene and possible present and future applications of the electronic properties of polymers, as e.g. conductors or as electrodes in electrochemical cells, were elucidated. The electronic properties of polymers cover a wide range of research problems which are of particular interest for polymers with a 1T-electron system. Thus, a great part of the work presented was concerned with conjuga ted systems. Additional presentations dealt with other systems such as bio polymers, photopolymers or electrets, which are of significant scientific and technical importance. It was demonstrated how their electronic proper ties are increasingly being investigated from a fundamental point of view by applying known concepts of snlid-state science.

Vol. 1: Semiconductors;Vol. 2: Semiconductors Devices;Vol. 3: High-Tc Superconductors and Organic Conductors; Vol. 4: Ferroelectrics and Dielectrics; Vol. 5: Chalcogenide Glasses and Sol-Gel Materials; Vol. 6 Nanostructured Materials; Vol. 7: Liquid Crystals, Display and Laser Materials; Vol. 8: Conducting Polymers; Vol. 9: Nonlinear Optical Materials; Volume 10: Light-Emitting Diodes, Lithium Batteries and Polymer Devices

This book deals with electrical, electrochemical, structural, magnetic, optical and lattice dynamical properties of conjugated polymers such as polyaniline, polyacetylene, polydiacetylene, polypyrrole, polyparaphenylene and polythiophene. Several new conjugated systems and model polyenes are also considered. Since the previous winter school on this topic held in 1985, the focus of interest in the field has broadened and now covers not only conductivity and relaxation phenomena of polyacetylene but also nonlinear optical properties, highly oriented and single crystal polymers, and electrochemical and opto-electrochemical properties of special materials. Particular attention is paid in this volume to the possible applications of these systems, for example, in electrochemical cells as electrode materials and in nonlinear optics devices, which now appear to be much more realistic than previously. The detailed contributions are complemented by short reviews of thin film polymers (Langmuir-Blodgett layers), filled polymers, ferromagnetic polymers, superconducting low-dimensional systems (including organic superconductors and high-temperature superconductors) and the application of fractal models to polymers.

The International Winter School on Electronic Properties of Polymers Orien tation and Dimensionality of Conjugated Systems, held March 9-16, 1991, in Kirchberg, ('lYrol) Austria, was a sequel to three meetings on similar subjects held there. The 1991 winter school was again organized in cooperation with the "Bundesministerium fUr Wissenschaft und Forschung" in Austria, and with the "Bundesministerium fUr Forschung und Technologie" in the Federal Republic of Germany. The basic idea of the meeting was to provide an opportunity for experienced scientists from universities and industry to discuss their most re cent results and for students and young scientists to become familiar with the present status of research and applications in the field. Like the previous winter schools on polymers, this one concentrated on the electronic structure and potential~ for application of polymers with conjugated double bonds. This time, however, special attention was paid to the effects of orientation and dimensionality. Anisotropy of the electric conductivity in stretch-oriented samples and whether the transport mechanisms are one-, two-, or three-dimensional or might even have a "fractal dimensionality" were there fore central topics. The problem of orientation was extended to systems such as Langmuir-Blodgett films and other layered structures. Accordingly, thin films were the focus of most of the application oriented contributions. Whereas in the previous winter schools discussions on applications dealt with "large volume applications" such as electromagnetic shielding and energy storage, this time "molecular materials for electronics" and prospects of "molecular electronics" were at the center of interest.

A comprehensive update on the fundamentals and recent advancements of electrical properties of polymers.

This convenient desk reference is one of a series of volumes containing carefully selected reprints from the world-renowned Encyclopedia of Polymer Science and Engineering. It brings together the original, complete articles related to electric and electronic properties of polymers, with full text, tables, figures, and reference materials. All articles are by industrial or academic experts in their fields, and the final work has been carefully reviewed by specialists. Arranged alphabetically, the articles cover nearly every aspect of the conductive and insulating properties of polymeric materials, providing detailed information on methods of synthesis and uses. Cross-referenced, with an extensive index.