Fly Ash Zeolites

This book presents a thorough review of the state-of-knowledge and recent innovations in the synthesis of pure and improved grades of fly ash zeolites (FAZ). Addressing improvements to conventional methods, it also showcases a novel technique for the synthesis of high cation exchangers from fly ash and detailed characterization techniques for the products obtained. In addition, it examines in detail various areas of specific applications of fly ash zeolites. Over the years, several methods such as hydrothermal, fusion prior to hydrothermal, microwave assisted hydrothermal and molten salt techniques for producing FAZ have been developed. However, one-step and two-step reactions between the fly ash and alkali usually generate alkaline wastes that may cause environmental contamination. In addition, the separation of FAZ from the partially activated fly ash (the impurities) remains a major concern for researchers and industrialists alike. /divIn view of these challenges, this book presents a novel technique for three-step activation (TSA), which focuses on recycling the fly ash-NaOH-water reaction by-products until zeolitic residue is formed. The FAZ (the final residue after third step reactions) synthesized in this manner exhibits exceptionally high cation exchange capacity, specific surface area and pore area. This book offers a comprehensive compendium of reading material on fly ash and its recycled product, the zeolites. Students at both undergraduate and graduate levels, researchers, and practicing engineers will all find this book to be a valuable guide in their respective fields.

This book collects recent results about research activities on zeolites, from synthesis to application. It is composed of two sections. The first is devoted to articles and brief review articles on the synthesis of zeolite from fly ash and final application of these newly formed minerals to solve environmental problems. The second part of the book provides useful information on different applications both of natural and synthetic zeolites ranging from environmental pollution to industrial and commercial applications. The performance of zeolite molecular sieves, hollow titanium zeolites and luminescent zeolites is interesting considering the new frontiers reached by the research on zeolites. This book is a useful instrument for researchers, teachers and students who are interested in investigating innovative aspects of the studies on zeolite.

Coal fly ash (CFA) is one of the most complex anthropogenic materials. It is estimated that only about 20 to 30% of the globally generated fly ash is employed and utilised in building materials mainly as an additive in cement, concrete, and structural filling as well as in small scale production of zeolite. This book provides new research on the characteristics, uses and performance of fly ash.

This book presents a number of innovative uses of fly ash. Fly ash is a fine powder that is a byproduct of burning pulverized coal in thermal power plants. It is a pozzolan – a substance containing aluminous and siliceous material that when mixed with lime and water forms a compound similar to Portland cement. Though fly ash was a problem in terms of its disposal, it now has a variety of uses, such as a prime material in blocks, bricks, and PCC paving, and further applications are being investigated. As such, the recovery and reuse of fly ash wastes plays an important role in the implementation of the circular economy concept. Featuring selected, high-quality research papers presented at IconSWM 2018, the book provides valuable insights for the recycling industries, power plants, researchers, and governments.