Functionalization Of Semiconductor Surfaces

This book presents both fundamental knowledge and latest achievements of this rapidly growing field in the last decade. It presents a complete and concise picture of the the state-of-the-art in the field, encompassing the most active international research groups in the world. Led by contributions from leading global research groups, the book discusses the functionalization of semiconductor surface. Dry organic reactions in vacuum and wet organic chemistry in solution are two major categories of strategies for functionalization that will be described. The growth of multilayer-molecular architectures on the formed organic monolayers will be documented. The immobilization of biomolecules such as DNA on organic layers chemically attached to semiconductor surfaces will be introduced. The patterning of complex structures of organic layers and metallic nanoclusters toward sensing techniques will be presented as well.

This book presents both fundamental knowledge and latest achievements of this rapidly growing field in the last decade. It presents a complete and concise picture of the the state-of-the-art in the field, encompassing the most active international research groups in the world. Led by contributions from leading global research groups, the book discusses the functionalization of semiconductor surface. Dry organic reactions in vacuum and wet organic chemistry in solution are two major categories of strategies for functionalization that will be described. The growth of multilayer-molecular architectures on the formed organic monolayers will be documented. The immobilization of biomolecules such as DNA on organic layers chemically attached to semiconductor surfaces will be introduced. The patterning of complex structures of organic layers and metallic nanoclusters toward sensing techniques will be presented as well.

The primary objective of the NATO Advanced Study Institute (ASI) titled “Functionalized Nanoscale Materials, Devices, and Systems for Chem. -Bio Sensors, Photonics, and Energy Generation and Storage” was to present a contemporary and comprehensive overview of the field of nanostructured materials and devices and its applications in chem. -bio sensors, nanophotonics, and energy generation and storage devices. The study has become one of the most promising disciplines in science and technology, as it aims at the fundamental understanding of new physical, che- cal, and biological properties of systems and the technological advances arising from their exploration. Such systems are intermediate in size, between the isolated atoms and molecules and bulk material, where the unique transitional characteristics between the two can be understood, controlled, and manipulated. Nanotechnologies refer to the creation and utilization of functional materials, devices, and systems with novel properties and functions that are achieved through the control of matter, atom-by-atom, molecule-by-molecule, or at a micro-mo- cular level. Advances made over the last few years provide new opportunities for scientific and technological developments in nanostructures and nanosystems with new architectures with improved functionality. The field is very actively and rapidly evolving and covers a wide range of disciplines. Recently, various nanoscale materials, devices, and systems with remarkable properties have been developed, with numerous unique applications in chemical and biological sensors, nanophotonics, nano-biotechnology, and in-vivo analysis of cellular processes at the nanoscale.

Semiconductor Surfaces and Interfaces deals with structural and electronic properties of semiconductor surfaces and interfaces. The first part introduces the general aspects of space-charge layers, of clean-surface and adatom-included surfaces states, and of interface states. It is followed by a presentation of experimental results on clean and adatom-covered surfaces which are explained in terms of simple physical and chemical concepts and models. Where available, results of more refined calculations are considered. A final chapter is devoted to the band lineup at semiconductor interfaces.

Within nanoscience, an emerging discipline is the study of the physics and chemistry of single molecules. Molecules may be considered as the ultimate building blocks, and are therefore interesting for the development of molecular devices and for surface functionalization. Thus, it is interesting to study their properties when adsorbed on a suitable substrate such as a solid or crystal surface, and also for their potential applications in nano- or molecular-electronics and nanosensing. Investigations have been made possible by the advent of high resolution surface imaging and characterization techniques, commonly referred to as Scanning Probe Microscopes. This book focuses on the fascinating properties of the single molecules, and the difference between single molecules and ensembles of molecules is emphasized. As the first book intended for graduate courses in the field, after each chapter, students should be able to answer the question: “What physical or chemical properties do you learn from a single molecule in this particular context?” Contributed by experts across the disciplines, the book provides useful reference material for specialized practitioners in surface science, nanoscience and nanoelectronics. Contents:Introduction:Basic Properties of Metal Surfaces (A L Vázquez de Parga & R Miranda)Basic Properties of Silicon Surfaces (M J Butcher & M Y Simmons)Experimental Methods:Scanning Tunneling Microscopy and Scanning Force Microscopy (S Hembacher & F Giessibl)Optical Detection of Single Molecules at Interfaces (B Hecht)Theoretical Methods:Ab Initio Modeling of Molecular Electronics (D Roubtsov et al.)Perturbation Methods in Scanning Tunneling Microscopy (W A Hofer)Spectroscopy of Single Molecule(s) on Surfaces:Properties of Single Molecules: Manipulation, Dissociation and Synthesis with the Scanning Tunneling Microscope (K-F Braun & S-W Hla)Single Molecule Vibrational Spectroscopy and Chemistry (J I Pascual & N Lorente)Local Modification of Surfaces Induced by Adsorbed Molecules:Superlattices of Atoms, Molecules and Islands (H Brune)Mobility of Complex Organic Species at Metal Surfaces (J V Barth)Molecular Monolayers on Silicon Surfaces (G P Lopinski & D D M Wayner)Functionalization of Semiconductor Surfaces by Organic Layers: Concerted Cycloaddition versus Stepwise Free-Radical Reaction Mechanisms (A Bilic et al.)Electronic Properties of Single Molecules on Metal Surfaces:Molecular Electronics (R Stadler)Exploring the Catalytic Activity of a Noble Metal: The Ag Catalyzed Ethylene Epoxidation Reaction (M-L Bocquet & A Michaelides) Readership: Graduate students, scientists, researchers in condensed matter physics, physical chemistry, materials and nanoscience. Keywords:Nanoscience;Molecular Electronics;Scanning Probe Microscopy;Molecule-Surface InteractionsKey Features:Each chapter is self-contained and written in a readable style, accessible to a broad audience of non-specialistsAll chapters have been peer-reviewedReviews:“On the whole, the book offers some outstanding reviews of single molecule research in the past decade with a particular emphasis on scanning tunneling microscopy.”Journal of the American Chemical Society “I found all of the articles to be of real interest and to contain information that broadened my existing knowledge. The articles were also helpful in not only presenting current research, but in providing critical comment and highlighting areas for future work. I was also impressed by the balance between experiment and theory … I believe that this book would be a very valuable text for graduate students, teachers and researchers interested in the interaction of organic molecules with surfaces.”Australian Physics

This book is a sequel to the first volume of The Chemistry of Nanostructured Materials. It covers the most exciting developments in the nanostructured materials field for the past five to ten years, with a particular focus on their applications in energy conversion and energy storage. Prominent authors of recognized authority in the field contribute their expertise in the review chapters.

Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, Seven Volume Set summarizes current, fundamental knowledge of interfacial chemistry, bringing readers the latest developments in the field. As the chemical and physical properties and processes at solid and liquid interfaces are the scientific basis of so many technologies which enhance our lives and create new opportunities, its important to highlight how these technologies enable the design and optimization of functional materials for heterogeneous and electro-catalysts in food production, pollution control, energy conversion and storage, medical applications requiring biocompatibility, drug delivery, and more. This book provides an interdisciplinary view that lies at the intersection of these fields. Presents fundamental knowledge of interfacial chemistry, surface science and electrochemistry and provides cutting-edge research from academics and practitioners across various fields and global regions