Gas Transfer At Water Surfaces

The transfer across the surface of environmental waters is of interest as an important phase in the geophysical and natural biochemical cycles of numer ous substances; indeed it governs the transition, one way or the other, be tween the dissolved state in the water and the gaseous state in the atmo sphere. Especially with increasing population and industrialization, gas transfer at water surfaces has become a critical factor in the understanding of the various pathways of wastes in the environment and of their engineering management. This interfacial mass transfer is, by its very nature, highly complex. The air and the water are usually in turbulent motion, and the interface be tween them is irregular, and disturbed by waves, sometimes accompanied by breaking, spray and bubble formation. Thus the transfer involves a wide variety of physical phenomena occurring over a wide range of scales. As a consequence, scientists and engineers from diverse disciplines and problem areas, have approached the problem, often with greatly differing analytical and experimental techniques and methodologies.

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This book arises from a NATO-sponsored Advanced Study Institute on 'The Role of Air-Sea Exchange in Geochemical Cycling' held at Bombann@§. near Bordeaux, France. from 16 to 27 September 1985. The chapters of the book are the written versions of the lectures given at the Institute. The aim of the book is to give a comprehensive up-to-date coverage of the subject. presented in a teaching mode. The chapters contain much recent research material and attempt to give the reader an understanding of how the role of air-sea exchange in geochemical cycling can be quantitatively assessed. In the last decade, major advances in the fields of marine and atmospheric chemistry have underlined the role of physical, chemical and biological processes at and near the air-sea interface in a number of geochemical cycles (C. S, N, metals etc ... ). Further, there is strong concern over the anthropogenic perturbation of these cycles on both regional and global scales. The first part of the book (Chapters 1 to 8) provides a review of topics fundamental to such studies. These topics include concepts in geochemical modelling, assessment of atmospheric transport from sources to the oceans. description of mixing and transport processes within the ocean for both dissolved and particulate materials, quantification of air-sea fluxes for both gases and particles, photochemical transformations in the atmospheric and oceanic boundary layers.

The book discusses the complex phenomena of gas transfer processes within the sciences of fluid dynamics and biogeochemistry. It covers: 1.) Effects of surface waves and turbulence on gas transfer. 2.) Effects of buoyancy and surfactants on gas transfer. 3.) Gas gransfer in strong turbulent flows. 4.) Remote sensing for large-scale gas transfer. 5.) gas transfer by aeration.