Geochemical Aspects Of Radioactive Waste Disposal

There is an extremely voluminous literature on radioactive waste and its disposal, much in the form of government-sponsored research reports. To wade through this mountain of literature is indeed a tedious task, and it is safe to speculate that very few, if any, individuals have the time to examine each report that has been issued during the preceding ten years. This book attempts to summarize much of this literature. Further, many workers in the geosciences have not received training in the nuclear sciences, and many nuclear scientists could be better versed in geology. In this book an attempt is made to cover some background material on radioactive wastes and geotoxicity that may not be an integral part of a geologist's training, and background material on geology and geochemistry for the nuclear scientist. The geochemical material is designed for both the geoscientist and the nuclear scientist. There is no specific level for this book. Certainly, it should be useful to advanced undergraduates and graduates studying geology and nuclear science. It does not pretend to cover a tremendous amount of detail in all subjects, yet the references cited provide the necessary source materials for follow-up study. It is my intention that the reader of this book will have a better, broader understanding of the geochemical aspects of radioactive waste disposal than is otherwise available in anyone source.

In order to validate predictive models of the very long-term processes which affect the performance of radioactive waste repositories, there has been an increased interest in the information and understanding which can be obtained from studying similar mechanisms in natural systems. These "natural analogues", as they are known in the jargon of waste management, have been studied sporadically for many years, but there has been a considerable rejuvenation of interest in the last four years, possibly owing to the fact that performance assessment methodolo gy is gradually maturing to the point where it needs the kind of support which analogues can offer. Since 1982, the Commission of the European Communities has been involved in specific work on natural analogues in the framework of its activities on radioactive waste management, principally within the MIRAGE project which concerns migration of radionuclides in the geosphere. As a consequence, the Commission took the initiative, in 1985, of establish ing a Natural Analogue Working Group (NAWG) whose members can benefit from the overall expertise available for managing their own natural analogue research programmes. In this group, modeller' s requirements and the results of field research are exchanged at regular intervals. A number of wide-ranging investigation programmes, both on national and international scales. are currently underway or being initiated, and several of these have been discussed recently at the NAWG.

This text considers chemical processes within the geosphere that may be harnessed to contain a wide range of wastes. It contains contributions from experts in waste containment technologies and covers many issues such as radioactive waste management.

The Geological Disposal of Nuclear Waste Neil A. Chapman and Ian G. McKinley The disposal of radioactive wastes is becoming a central issue in the nuclear debate and any consideration of the future of nuclear power, and its effect on the environment, must take waste management into account. Nuclear waste is currently a significant political issue in Western Europe and North America and is becoming increasingly important in all other countries with existing or planned nuclear programmes. This is the first book to tackle in a comprehensive and integrated fashion the problems associated with the geological disposal of nuclear waste. International research and development launched during the last decade has enabled the authors to describe detailed concepts for the long-term management and disposal of such material. The level of presentation is such that readers with high school science will be able to understand the issues involved. However, the broad scope of coverage with references provided throughout as well as a guide to the key sources of information, make this an invaluable book for both the researcher and the lay environmental scientist.

Coupled Processes Associated with Nuclear Waste Repositories covers the proceedings of the 1985 International Symposium on Coupled Processes Associated with Nuclear Waste Repositories. The study of the behavior of geologic waste repositories is based on the coupled thermal, hydrologic, chemical, and mechanical processes that may occur in these systems. The symposium is sponsored by the U.S. Nuclear Regulatory Commission and the U.S. Department of Energy, in collaboration with the Nuclear Energy Authority in Paris and the Commission of the European Communities in Brussels. This book is organized into five parts encompassing 58 chapters. The introductory parts survey the concerns and interests from American and European agencies that have responsibilities in nuclear waste isolation research. These parts also provide overviews of coupled processes, with a particular emphasis on hydrology, geomechanics, and geochemistry. These topics are followed by summaries of major field projects on nuclear waste repositories in the U.S.A., France, Sweden, Canada, Belgium, and Switzerland. The fourth part covers considerable research results from topical studies of particular coupled processes. The concluding part provides the comments and discussion of various international researchers on the subject. This work will be of value to geology, hydrology, chemistry, thermodynamics, and rock mechanics students and researchers.

Many countries are currently exploring the option to dispose of highly radioactive solid wastes deep underground in purpose built, engineered repositories. A number of surface and shallow repositories for less radioactive wastes are already in operation. One of the challenges facing the nuclear industry is to demonstrate confidently that a repository will contain wastes for so long that any releases that might take place in the future will pose no significant health or environmental risk. One method for building confidence in the long-term future safety of a repository is to look at the physical and chemical processes which operate in natural and archaeological systems, and to draw appropriate parallels with the repository. For example, to understand why some uranium orebodies have remained isolated underground for billions of years. Such studies are called 'natural analogues'. This book investigates the concept of geological disposal and examines the wide range of natural analogues which have been studied. Lessons learnt from studies of archaeological and natural systems can be used to improve our capabilities for assessing the future safety of a radioactive waste repository.

The safe disposal of radioactive wastes by burial in deep geological formations requires long-term predictions of the future behaviour of the wastes and their engineered repository. Such predictions can be tested by evaluating processes analogous to those which will occur in a repository, which have been long active in the natural geochemical environment. The Pocos de Caldas Project is a comprehensive study of two ore deposits in Minas Gerais, Brazil, aimed at looking at uranium and thorium series radionuclide and rare-earth element mobility, the development and movement of redox fronts, and the nature of natural groundwater colloids. A multidisciplinary team of experts from 27 laboratories carried out a fully integrated study of the geology, geomorphology, hydrogeology, geochemistry, hydrochemistry and geomicrobiology of the two sites for nearly four years. This book contains 20 papers covering the detailed findings, with particular emphasis on their significance for radioactive waste disposal, especially on the use of the data in testing models of radionuclide movement. It will interest economic geologists, geochemists and performance assessment modellers involved in the geological disposal of radioactive wastes.