Interfacial Transport Processes Rheology

This textbook is designed to provide the theory, methods of measurement, and principal applications of the expanding field of interfacial hydrodynamics. It is intended to serve the research needs of both academic and industrial scientists, including chemical or mechanical engineers, material and surface scientists, physical chemists, chemical and biophysicists, rheologists, physiochemical hydrodynamicists, and applied mathematicians (especially those with interests in viscous fluid mechanics and continuum mechanics).As a textbook it provides materials for a one- or two-semester graduate-level course in interfacial transport processes. It may also be noted that, while separate practical and theoretical subdivisions of material have been introduced, a kind of cross-emphasis is often stressed: (i) to the academic scientist, or the importance of understanding major applications of interfacial transport; and (ii) to the industrial scientist, of the importance of understanding the underlying theory.

Transport processes are often characterized by the simultaneous presence of multiple dependent variables, multiple length scales, body forces, free boundaries and strong non-linearities. The various computational elements important for the prediction of complex fluid flows and interfacial transport are presented in this volume. Practical applications, presented in the form of illustrations and examples are emphasized, as well as physical interpretation of the computed results. The book is intended as a reference for researchers and graduate students in mechanical, aerospace, chemical and materials engineering. Both macroscopic and microscopic (but still continuum) features are addressed. In order to lay down a good foundation to facilitate discussion of more advanced techniques, the book has been divided into three parts. Part I presents the basic concepts of finite difference schemes for solving parabolic, elliptic and hyperbolic partial differential equations. Part II deals with issues related to computational modeling for fluid flow and transport phenomena. Existing algorithms to solve the Navier-Stokes equations can be generally classified as density-based methods and pressure-based methods. In this book the pressure-based method is emphasized. Recent efforts to improve the performance of the pressure-based algorithm, both qualitatively and quantitatively, are treated, including formulation of the algorithm and its generalization to all flow speeds, choice of coordinate system and primary velocity variables, issues of grid layout, open boundary treatment and the role of global mass conservation, convection treatment and convergence. Practical engineering applications, including gas-turbine combustor flow, heat transfer and convection in high pressure discharge lamps, thermal management under microgravity, and flow through hydraulic turbines are also discussed. Part III addresses the transport processes involving interfacial dynamics. Specifically those influenced by phase change, gravity, and capillarity are emphasized, and both the macroscopic and morphological (microscopic) scales are presented. Basic concepts of interface, capillarity, and phase change processes are summarized to help clarify physical mechanisms, followed by a discussion of recent developments in computational modeling. Numerical solutions are also discussed to illustrate the salient features of practical engineering applications. Fundamental features of interfacial dynamics have also been illustrated in the form of case studies, to demonstrate the interplay between fluid and thermal transport of macroscopic scales and their interaction with interfacial transport.

The present set of lectures and tutorial reviews deals with various topical aspects related to instabilities of interfacial processes and driven flows from both the theoretical and experimental point of views. New research has been spurred by demands for many applications in material sciences (melting, solidification, electro deposition), biomedical engineering and processing in microgravity environments. This book is intended as both a modern source of reference for researchers in the field as well as an introduction to postgraduate students and non-specialists from related areas.

A discussion of fundamental characteristics, theories and applications for liquid-liquid colloidal dispersions. It profiles experimental and traditional measurement techniques in a variety of emulsified systems, including rheology, nuclear magnetic resonance, dielectric spectroscopy, microcalorimetry, video enhanced microscopy, and conductivity.

There are several physico-chemical processes that determine the behavior of multiphase fluid systems – e.g., the fluid dynamics in the different phases and the dynamics of the interface(s), mass transport between the fluids, adsorption effects at the interface, and transport of surfactants on the interface – and result in heterogeneous interface properties. In general, these processes are strongly coupled and local properties of the interface play a crucial role. A thorough understanding of the behavior of such complex flow problems must be based on physically sound mathematical models, which especially account for the local processes at the interface. This book presents recent findings on the rigorous derivation and mathematical analysis of such models and on the development of numerical methods for direct numerical simulations. Validation results are based on specifically designed experiments using high-resolution experimental techniques. A special feature of this book is its focus on an interdisciplinary research approach combining Applied Analysis, Numerical Mathematics, Interface Physics and Chemistry, as well as relevant research areas in the Engineering Sciences. The contributions originated from the joint interdisciplinary research projects in the DFG Priority Programme SPP 1506 “Transport Processes at Fluidic Interfaces.”

This is the first book on interfacial rheology. It aims to describe both its history as well as the current, most frequently used experimental techniques for studying dilational and shear rheology of layers at liquid/gas and liquid/liquid interfaces. The book opens with a chapter on the fundamentals of interfacial rheology. All (16) contributions i

The subject matter covered in this volume covers a wide scope. It contains critical reviews in many frontier areas of interest to engineers and applied scientists. Multiphase transport ranging from floc breakage to flow through multiphase media is discussed. Difficult problems of bubble growth and devolatilisation from polymeric melts are treated. The question of solid-liquid phase change with flow is considered and the emerging quantitation of web drying technology through mathematical modeling is covered. Transport phenomena in high-tech materials ranging from zeolite catalysts to liquid crystalline materials are covered and formidable problems of transport of gases in porous media, which have implications in many different technologies, are also addressed. Finally, applications of newer techniques in numerical computation of transport processes are highlighted. These authorative, evaluative and timely reviews of topics of current and potential interest will serve the needs of practising engineers as well as academic and industrial researchers.