Introduction To Thermoelectricity

Introduction to Thermoelectricity is the latest work by Professor Julian Goldsmid drawing on his 55 years experience in the field. The theory of the thermoelectric and related phenomena is presented in sufficient detail to enable researchers to understand their observations and develop improved thermoelectric materials. The methods for the selection of materials and their improvement are discussed. Thermoelectric materials for use in refrigeration and electrical generation are reviewed. Experimental techniques for the measurement of properties and for the production of thermoelements are described. Special emphasis is placed on nanotechnology which promises to yield great improvements in the efficiency of thermoelectric devices. Chapters are also devoted to transverse thermoelectric effects and thermionic energy conversion, both techniques offering the promise of important applications in the future.

This introductory treatment provides an understanding of the fundamental concepts and principles involved in the study of thermoelectricity in solids and of conduction in general. Aimed at graduate-level students and those interested in basic theory, it will be especially valuable to experimental physicists working in fields connected with electron transport and to theoreticians seeking a survey of thermoelectricity and related questions. Chronicling the early history of thermoelectricity from its discovery to modern times, this text features a considerable amount of experimental data and discusses these findings at length wherever they bear a particular relevance to theory. The author, a well-known authority in this field, draws heavily from his own work on thermoelectrical phenomena as they are observed in the study of metals. Numerous illustrative figures appear throughout the text.

This book outlines the principles of thermoelectric generation and refrigeration from the discovery of the Seebeck and Peltier effects in the nineteenth century through the introduction of semiconductor thermoelements in the mid-twentieth century to the more recent development of nanostructured materials. It is shown that the efficiency of a thermoelectric generator and the coefficient of performance of a thermoelectric refrigerator can be related to a quantity known as the figure of merit. The figure of merit depends on the Seebeck coefficient and the ratio of the electrical to thermal conductivity. It is shown that expressions for these parameters can be derived from the band theory of solids. The conditions for favourable electronic properties are discussed. The methods for selecting materials with a low lattice thermal conductivity are outlined and the ways in which the scattering of phonons can be enhanced are described. The application of these principles is demonstrated for specific materials including the bismuth telluride alloys, bismuth antimony, alloys based on lead telluride, silicon-germanium and materials described as phonon-glass electron-crystals. It is shown that there can be advantages in using the less familiar transverse thermoelectric effects and the transverse thermomagnetic effects. Finally, practical aspects of thermoelectric generation and refrigeration are discussed. The book is aimed at readers who do not have a specialised knowledge of solid state physics.

Advanced Thermoelectric Materials for Energy Harvesting Applications is a research-intensive textbook covering the fundamentals of thermoelectricity and the process of converting heat energy into electrical energy. It covers the design, implementation, and performance of existing and advanced thermoelectric materials. Chapters examine such topics as organic/inorganic thermoelectric materials, performance and behaviors of thermoelectric devices, and energy harvesting applications of thermoelectric devices.

This book provides a concise but comprehensive introduction to the fundamentals and current state of the art in thermoelectrics. Addressing an audience of materials scientists and engineers, the book covers theory, materials selection, and applications, with a wide variety of case studies reflecting the most up-to-date research approaches from the past decade, from single crystal to polycrystalline form and from bulk to thin films to nano dimensions. The world is facing major challenges for finding alternate energy sources that can satisfy the increasing demand for energy consumption while preserving the environment. The field of thermoelectrics has long been recognized as a potential and ideal source of clean energy. However, the relatively low conversion efficiency of thermoelectric devices has prevented their utility on a large scale. While addressing the need for thermal management in materials, device components, and systems, thermoelectrics provides a fundamental solution to waste heat recovery and temperature control. This book summarizes the global efforts that have been made to enhance the figure of merit of various thermoelectric materials by choosing appropriate processes and their influence on properties and performance. Because of these advances, today, thermoelectric devices are found in mainstream applications such as automobiles and power generators, as opposed to just a few years ago when they could only be used in niche applications such as in aeronautics, infrared imaging, and space. However, the continued gap between fundamental theoretical results and actual experimental data of figure of merit and performance continues to challenge the commercial applications of thermoelectrics. This book presents both recent achievements and continuing challenges, and represents essential reading for researchers working in this area in universities, industry, and national labs.

Thermoelectrics is the science and technology associated with thermoelectric converters, that is, the generation of electrical power by the Seebeck effect and refrigeration by the Peltier effect. Thermoelectric generators are being used in increasing numbers to provide electrical power in medical, military, and deep space applications where combinations of their desirable properties outweigh their relatively high cost and low generating efficiency. In recent years there also has been an increase in the requirement for thermoelectric coolers (Peltier devices) for use in infrared detectors and in optical communications. Information on thermoelectrics is not readily available as it is widely scattered throughout the literature. The Handbook centralizes this information in a convenient format under a single cover. Sixty of the world's foremost authorities on thermoelectrics have contributed to this Handbook. It is comprised of fifty-five chapters, a number of which contain previously unpublished material. The contents are arranged in eight sections: general principles and theoretical considerations, material preparation, measurement of thermoelectric properties, thermoelectric materials, thermoelectric generation, generator applications, thermoelectric refrigeration, and applications of thermoelectric cooling. The CRC Handbook of Thermoelectrics has a broad-based scope. It will interest researchers, technologists, and manufacturers, as well as students and the well-informed, non-specialist reader.

This second edition is a comprehensive introduction to all aspects of thermoelectric energy conversion. It covers both theory and practice. The book is timely as it refers to the many improvements that have come about in the last few years through the use of nanostructures. The concept of semiconductor thermoelements led to major advances during the second half of the twentieth century, making Peltier refrigeration a widely used technique. The latest materials herald thermoelectric generation as the preferred technique for exploiting low-grade heat. The book shows how progress has been made by increasing the thermal resistivity of the lattice until it is almost as large as it is for glass. It points the way towards the attainment of similar improvements in the electronic parameters. It does not neglect practical considerations, such as the desirability of making thermocouples from inexpensive and environmentally acceptable materials. The second edition was extended to also include recent advances in thermoelectric energy conversion, particularly the production of bulk nanostructures, new materials with higher thermoelectric figures to use the possibility of large scale thermoelectric generation, as part of the worldwide strategy for making better use of energy resources. This book guides the newcomer towards the state of the art and shows the principles for further advancement to those who are already familiar with the subject. The author has been able to draw on his long experience to cover the science and technology in a balanced way while drawing on the expertise of others who have made major contributions to the field.

Thermoelectrics: Design and Materials HoSung Lee, Western Michigan University, USA A comprehensive guide to the basic principles of thermoelectrics Thermoelectrics plays an important role in energy conversion and electronic temperature control. The book comprehensively covers the basic physical principles of thermoelectrics as well as recent developments and design strategies of materials and devices. The book is divided into two sections: the first section is concerned with design and begins with an introduction to the fast developing and multidisciplinary field of thermoelectrics. This section also covers thermoelectric generators and coolers (refrigerators) before examining optimal design with dimensional analysis. A number of applications are considered, including solar thermoelectric generators, thermoelectric air conditioners and refrigerators, thermoelectric coolers for electronic devices, thermoelectric compact heat exchangers, and biomedical thermoelectric energy harvesting systems. The second section focuses on materials, and covers the physics of electrons and phonons, theoretical modeling of thermoelectric transport properties, thermoelectric materials, and nanostructures. Key features: Provides an introduction to a fast developing and interdisciplinary field. Includes detailed, fundamental theories. Offers a platform for advanced study. Thermoelectrics: Design and Materials is a comprehensive reference ideal for engineering students, as well as researchers and practitioners working in thermodynamics. Cover designed by Yujin Lee