Marine Chemistry Analytical Methods

This textbook offers a comprehensive and authoritative introduction to the latest analytical methods, tools and techniques used in the marine environment, bringing together the two fields of chemical oceanography and analytical chemistry. Divided into 11 chapters, the book starts with an overview of the main parameters of the marine carbon system, and it covers different sampling strategies used by the marine scientific community, and the different chemical analyses to measure trace metals, radionuclides and organic matter in the marine environment. Particular attention is given to the identification and quantification of marine persistent organic pollutants, emerging organic contaminants and microplastics. Readers will also find accessible explanations and real life examples of the application of remote sensing and in-situ sensing technologies to monitor the marine environment. The textbook finishes with a chapter on data treatment that outlines the relevant statistical approaches, uncertainty estimation and quality assurance of marine chemical measurements. This textbook provides both students and professionals alike with a transdisciplinary and comprehensive foundation for the chemical analysis of our oceans and seas.

This book introduces the general principles of reaction equilibria and kinetics involved in marine geochemical cycles. The major electrolytes dramatically affect the rates and equilibria of the chemical reactions in the sea. In order to understand these interactions, it is necessary to have a detailed knowledge of the major, minor and trace chemical components. This volume is also focused on the development and applications of analytical techniques for accurate determination and speciation in seawater, and on the effect of pollution on the marine environment, since small quantities of other elements may have a significant influence on global chemical cycling. Audience: This book is of value for marine chemists, biogeochemists, ecologists, oceanographers, environmental engineers and analytical chemists.

As we discover more about the role of the ocean in global changes and identify the effects of global change on the ocean, understanding its chemical composition and processes becomes increasingly paramount. However, understanding these processes requires a wide range of measurements in the vast ocean, from the sea surface to deep-ocean trenches, from the tropics to the poles. Practical Guidelines for the Analysis of Seawater provides a common analytical basis for generating quality-assured and reliable data on chemical parameters in the ocean. A source of practical know-how, the book covers sampling and storage, analytical methodology, and guidelines and procedures for quality assurance. It presents analytical methods with the step-by-step procedures that help practitioners implement these methods successfully into the laboratory, making them instantly applicable without consulting further literature. The book also contains essential information for developing or improving quality control and quality assurance programs in the laboratory. It includes the availability and measurement of standard reference materials, blank estimation and correction, control of recoveries, and statistical evaluation of quality assurance data. Analytical chemistry is a very active and fast moving area. Despite the development of innovative new analytical techniques for chemical trace element research, obtaining reliable data at ultra-trace levels remains a formidable challenge. A complete and practical guide, this book delineates proven methods that consistently yield reproducible data in routine work.

Combining laboratory experience with research and policy developments, this book provides an insight into the historical background of marine monitoring, its regulatory frameworks and science–policy interactions. With experience in the European Commission, the author draws from practical experience in research and policy implementation to present a concise review of marine monitoring on an international level. The author deals with monitoring and related QA/QC principles, focusing on monitoring types, while describing general features of analytical methods used in marine monitoring. The book concludes with a discussion about how to achieve metrology principles (measurement traceability) in marine monitoring.

Analysis of Seawater deals with the investigation of the micro-constituents in seawater in terms of nutrient content and environmental concerns. The book describes sampling, determination of anions, analysis of dissolved gases, and metal preconcentration techniques. The book also deals with monitoring radioactive elements, the determination of seawater organics, organometallic compounds, and the oxygen-demand parameters in seawater. It describes in detail surface and deep water sampling, the types of devices used, storage, preservation, and prevention of contamination during sample analysis. In examining dissolved gases, the investigator can use the amperometric titrimetric method (with some reservations) on chlorine, the ultraviolet method on ozone, electron capture gas chromatography on nitric oxide, and also the flow injection analysis on hydrogen sulphide. The methods for determining metals in seawater concern either for single element or for groups of elements. The investigator should always initiate various pre-concentration techniques when determining metals due to their low concentration and occurrence in seawater. The investigator uses various methods to determine different radioactive compounds such as uranium, polonium, thorium, radium, barium, radon, plutonium, strontium-90, and cesium-137. The book can be beneficial for meteorologists, environmentalists, marine ecologists, biologists, oceanographers, fisheries experts, for students studying hydrology, meteorology, as well as for river and lake authorities.