Materials Modification By Electronic Excitation

Electronic excitation is a means to change materials properties. This book analyses the important features of the changes induced by electronic excitation, identifies what is critical, and provides a basis from which materials modification can be developed successfully. Electronic excitation by lasers or electron beams can change the properties of materials. In the last few years, there has been a mix of basic science, of new laser and electron beam tools, and of new needs from microelectronics, photonics and nanotechnology. This book extends and synthesises the science, addressing ideas like energy localisation and charge localisation, with detailed comparisons of experiment and theory. It also identifies the ways this understanding links to technological needs, like selective removal of material, controlled changes, altering the balance between process steps, and possibilities of quantum control. This book will be of particular interest to research workers in physics, chemistry, electronic engineering and materials science.

Electronic excitation is a means to change materials properties. This book analyses the important features of the changes induced by electronic excitation, identifies what is critical, and provides a basis from which materials modification can be developed successfully. Electronic excitation by lasers or electron beams can change the properties of materials. In the last few years, there has been a mix of basic science, of new laser and electron beam tools, and of new needs from microelectronics, photonics and nanotechnology. This book extends and synthesises the science, addressing ideas like.

Contents:Overview of Defect Processes Induced by Electronic Excitation in Insulators (N Itoh)Excitonic Mechanism of Defect Formation in Alkali Halides as Spontaneous Symmetry Breaking (Y Kayanuma)Luminescence and Self-Trapping of Excitons in Alkali Halides (H Nishimura)Time-Resolved Studies of Photochemistry in Alkali Halides (M Hirai)Cascade-Excitation Spectroscopy for Recombination-Induced Defect Production in Halide Crystals (K Tanimura)Atomic Processes Induced by Electron Excitation at Surfaces (N Itoh) Readership: Condensed matter physicists. Keywords:Materials Modification;Electronic Excitation;Color Centers;Defect Formation;Sputtering;Excitons;Self-Trapped Excitons;Polarons;Luminescence;Radiation Damage

Ion beams have been used for decades for characterizing and analyzing materials. Now energetic ion beams are providing ways to modify the materials in unprecedented ways. This book highlights the emergence of high-energy swift heavy ions as a tool for tailoring the properties of materials with nanoscale structures. Swift heavy ions interact with materials by exciting/ionizing electrons without directly moving the atoms. This opens a new horizon towards the 'so-called' soft engineering. The book discusses the ion beam technology emerging from the non-equilibrium conditions and emphasizes the power of controlled irradiation to tailor the properties of various types of materials for specific needs.

A comprehensive discussion of the key role of modern spectroscopic investigations in interdisciplinary materials science and engineering, covering emerging materials that are either absolutely novel or well-known materials with recently discovered, exciting properties. The types of spectroscopy discussed include optical, electronic and magnetic, UV-visible absorption, Rayleigh scattering, photoluminescence, vibrational, magnetic resonance, electron energy loss, EXAFS, XANES, optical tomography, time-resolved spectroscopy, and point contact spectroscopy. The materials studied are highly topical, with a focus on carbon and silicon nanomaterials including nanotubes, fullerenes, nanoclusters, metallic superconducting phases, molecular materials, magnetic and charge-stripe oxides, and biomaterials. Theoretical treatments are presented of molecular vibrational dynamics, vibration-induced decay of electronic excited states, nanoscale spin-orbit coupling in 2D Si-based structures, and the growth of semiconductor clusters.

Researchers and engineers working in nuclear laboratories, nuclear electric plants, and elsewhere in the radiochemical industries need a comprehensive handbook describing all possible radiation-chemistry interactions between irradiation and materials, the preparation of materials under distinct radiation types, the possibility of damage of material

This book presents theoretical treatments on various electronic and atomic processes in non-metallic materials from a unified point of view. It starts with the basic properties of semiconductors, treating the system as a macroscopic association of electrons and ions. In their ground state, fruitful results are derived, such as the band theory for electrons in a periodic lattice and a useful concept of “hole.” The electron–lattice interaction is then introduced as a dynamical response of condensed matter when it is electronically excited. With the aid of proper configuration coordinate diagrams, various phenomena are precisely examined, including carrier scattering, polaron formation, lattice relaxation, Stokes shift and phonon side band in optical spectrum, intrinsic and extrinsic self-trapping, and structural changes. The book provides readers a deep understanding of the physics underlying these phenomena and excellent insight to develop their further research. Graduate students who have finished the basic study on solid-state physics and quantum mechanics and research scientists and engineers in materials science and engineering will benefit immensely from it.

Quickly becoming the hottest topic of the new millennium (2.4 billion dollars funding in US alone) Current status and future trends of micro and nanoelectronics research Written by leading experts in the corresponding research areas Excellent tutorial for graduate students and reference for "gurus" Provides a broad overlook and fundamentals of nanoscience and nanotechnology from chemistry to electronic devices