Matter In Equilibrium

This book provides an expert introduction to active fluids systems, covering simple to complex environments.

Chemistry 2e is designed to meet the scope and sequence requirements of the two-semester general chemistry course. The textbook provides an important opportunity for students to learn the core concepts of chemistry and understand how those concepts apply to their lives and the world around them. The book also includes a number of innovative features, including interactive exercises and real-world applications, designed to enhance student learning. The second edition has been revised to incorporate clearer, more current, and more dynamic explanations, while maintaining the same organization as the first edition. Substantial improvements have been made in the figures, illustrations, and example exercises that support the text narrative. Changes made in Chemistry 2e are described in the preface to help instructors transition to the second edition.

This is a textbook which gradually introduces the student to the statistical mechanical study of the different phases of matter and to the phase transitions between them. Throughout, only simple models of both ordinary and soft matter are used but these are studied in full detail. The subject is developed in a pedagogical manner, starting from the basics, going from the simple ideal systems to the interacting systems, and ending with the more modern topics. The textbook provides the student with a complete overview, intentionally at an introductory level, of the theory of phase transitions. All equations and deductions are included.

The first volume of this work is organized in three levels, so that the portion and importance of thermodynamics and mathematics increase from level to level. The ground level shows that basics of phase equilibria can be understood without thermodynamics provided the concept of chemical potential is introduced early. The intermediate level introduces thermodynamics, culminating in the Gibbs energy as the arbiter for equilibrium. At the third level the accent is on binary systems, where one or more phases are solutions of the components. Priority is given throughout to the thermodynamic assessment of experimental data. 200 exercises are included with solutions.

Originally Part II of Physical Chemistry, Second Edition, and now published as its own volume, Matter in Equilibrium: Statistical Mechanics and Thermodynamics simultaneously develops the statistical molecular theory and the classical thermodynamic theory of the bulk properties of matter in a mutually reinforcing fashion. Despite presenting both a microscopic and macroscopic approach, this sophisticated text offers a rigorous treatment of classical thermodynamics and allows professors to separate the two theories if desired. Packed with tables, graphs, and figures, it describes the equilibrium properties of bulk matter and develops the tools needed to study gases, solids, liquids, phase transformations, solutions of nonelectrolytes, and solutions of electrolytes. The book makes extensive use of computer simulations of molecular behavior and, where appropriate, uses experimental data to illustrate concepts and principles. Ideal for advanced undergraduate and beginning graduate level courses, Matter in Equilibrium broadens and challenges student perspectives while offering valuable information to researchers.

The Second Volume of “Equilibrium between Phases of Matter”, when compared with the First Volume, by H.A.J. Oonk and M.T. Calvet, published in 2008, amounts to an extension of subjects, and a deepening of understanding. In the first three sections of the text an extension is given of the theory on isobaric binary systems. The fourth section gives an account of the thermodynamic analyses of four isobaric binary key systems, highlighting the power of empirical, (exo)thermodynamic correlations. The fifth section is devoted to the thermodynamic description of ternary systems. The last three sections concentrate on the properties of materials, and the phase behaviour of systems under the conditions of high temperature and high pressure – conditions that prevail in the interior of the Earth. A new equation of state is the subject of the sixth section. In the seventh section a move is made to statistical thermodynamics and vibrational models; the description of the systems has changed from mathematical to physical. The last section is on the system MgO – SiO2, looked upon from a geophysical point of view. Throughout the work high priority is given to the thermodynamic assessment of experimental data; numerous end-of-section exercises and their solutions are included. Along with the First Volume, the work is useful for materials scientists and geophysicists as a reference text. Audience Volume II is a lecture book for postgraduate students in chemistry, chemical engineering, geology and metallurgy. It is highly useful as a recommended text for teachers and researchers in all fields of materials science.

This book discusses in depth many of the key problems in non-equilibrium physics. The origin of macroscopic irreversible behavior receives particular attention and is illustrated in the framework of solvable models. An updated discussion on the linear response focuses on the correct electrodynamic aspects, which are essential for example, in the proof of the Nyquist theorem. The material covers the scaling relationship between different levels of description (kinetic to hydrodynamic) as well as spontaneous symmetry breaking in real time in terms of nonlinear dynamics (attractors), illustrated using the example of Bose-Einstein condensation. The presentation also includes the latest developments ? quantum kinetics ? related to modern ultrafast spectroscopy, where transition from reversible to irreversible behavior occurs.