Melt Rheology And Its Role In Plastics Processing

This book is designed to fulfill a dual role. On the one hand it provides a description of the rheological behavior of molten poly mers. On the other, it presents the role of rheology in melt processing operations. The account of rheology emphasises the underlying principles and presents results, but not detailed deriva tions of equations. The processing operations are described qualita tively, and wherever possible the role of rheology is discussed quantitatively. Little emphasis is given to non-rheological aspects of processes, for example, the design of machinery. The audience for which the book is intended is also dual in It includes scientists and engineers whose work in the nature. plastics industry requires some knowledge of aspects of rheology. Examples are the polymer synthetic chemist who is concerned with how a change in molecular weight will affect the melt viscosity and the extrusion engineer who needs to know the effects of a change in molecular weight distribution that might result from thermal degra dation. The audience also includes post-graduate students in polymer science and engineering who wish to acquire a more extensive background in rheology and perhaps become specialists in this area. Especially for the latter audience, references are given to more detailed accounts of specialized topics, such as constitutive relations and process simulations. Thus, the book could serve as a textbook for a graduate level course in polymer rheology, and it has been used for this purpose.

This review encompasses fundamental principles and rheological equations of state, polymer melt rheology (shear and extensional flow, viscoelasticity, die swell and melt fracture) and rheological c094 techniques. It describes the main plastics processing techniques, and explains the influence of polymer melt rheology upon their operation. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.

This book is designed to fulfill a dual role. On the one hand it provides a description of the rheological behavior of molten poly mers. On the other, it presents the role of rheology in melt processing operations. The account of rheology emphasises the underlying principles and presents results, but not detailed deriva tions of equations. The processing operations are described qualita tively, and wherever possible the role of rheology is discussed quantitatively. Little emphasis is given to non-rheological aspects of processes, for example, the design of machinery. The audience for which the book is intended is also dual in nature. It includes scientists and engineers whose work in the plastics industry requires some knowledge of aspects of rheology. Examples are the polymer synthetic chemist who is concerned with how a change in molecular weight will affect the melt viscosity and the extrusion engineer who needs to know the effects of a change in molecular weight distribution that might result from thermal degra dation. The audience also includes post-graduate students in polymer science and engineering who wish to acquire a more extensive background in rheology and perhaps become specialists in this area. Especially for the latter audience, references are given to more detailed accounts of specialized topics, such as constitutive relations and process simulations. Thus, the book could serve as a textbook for a graduate level course in polymer rheology, and it has been used for this purpose.

This is the second edition of Melt Rheology and its Role in Plastics Processing, although the title has changed to reflect its broadened scope. Advances in the recent years in rheometer technology and polymer science have greatly enhanced the usefulness of rheology in the plastics industry. It is now possible to design polymers having specific molecular structures and to predict the flow properties of melts having those structures. In addition, rheological properties now provide more precise information about molecular structure. This book provides all the information that is needed for the intelligent application of rheology in the development of new polymers, the determination of molecular structure and the correlation of processability with laboratory test data. Theory and equations are limited to what is essential for the use of rheology in the characterization of polymers, the development of new plastics materials and the prediction of plastics processing behavior. The emphasis is on information that will be of direct use to practitioners. Extensive references are provided for those wishing to pursue certain issues in greater depth. While the primary audience is applied polymer scientists and plastics engineers, the book will also be of use to postgraduate students in polymer science and engineering and as a text for a graduate course.

This book explores the ways in which melt flow behaviour can be exploited by the plastics engineer and technician for increased efficiency of processing operation, control of end product properties and selection and development of polymers for specific purposes. (reissued with minor corrections 1994)

Presents rheological data on a number of polymers, making use of the master curve approach to determine unified curves for each generic type of polymer. The text offers a step-by-step procedure for developing a speadsheet computer program to obtain accurate thermoplastic rheograms at any tempertature without using sophisticated rheometres. It inclu

Understanding the elastic properties of polymer melts is necessary for ensuring successful polymer processing and thus producing high-quality plastic parts. This unique book is the first to focus on this important topic. Starting with the molecular origin of elastic behavior and an explanation of the physical quantities involved, experimental methods and the dependence of elastic behavior on experimental parameters are then presented. Elastic properties of filled and unfilled systems are compared directly, and polymer blends are also considered. Elastic effects in various applications are included, such as in extrudate swell, internal stresses, and shrink films, to illustrate the importance of this field in the plastics processing industry.