Metakaolin Based Geopolymers

A geopolymer is a solid aluminosilicate material usually formed by alkali hydroxide or alkali silicate activation of a solid precursor such as coal fly ash, calcined clay and/or metallurgical slag. Today the primary application of geopolymer technology is in the development of reduced-CO2 construction materials as an alternative to Portland-based cements. Geopolymers: structure, processing, properties and industrial applications reviews the latest research on and applications of these highly important materials.Part one discusses the synthesis and characterisation of geopolymers with chapters on topics such as fly ash chemistry and inorganic polymer cements, geopolymer precursor design, nanostructure/microstructure of metakaolin and fly ash geopolymers, and geopolymer synthesis kinetics. Part two reviews the manufacture and properties of geopolymers including accelerated ageing of geopolymers, chemical durability, engineering properties of geopolymer concrete, producing fire and heat-resistant geopolymers, utilisation of mining wastes and thermal properties of geopolymers. Part three covers applications of geopolymers with coverage of topics such as commercialisation of geopolymers for construction, as well as applications in waste management.With its distinguished editors and international team of contributors, Geopolymers: structure, processing, properties and industrial applications is a standard reference for scientists and engineers in industry and the academic sector, including practitioners in the cement and concrete industry as well as those involved in waste reduction and disposal. Discusses the synthesis and characterisation of geopolymers with chapters covering fly ash chemistry and inorganic polymer cements Assesses the application and commercialisation of geopolymers with particular focus on applications in waste management Reviews the latest research on and applications of these highly important materials

A Practical Guide from Top-Level Industry Scientists As advanced teaching and training in the development of cementitious materials increase, the need has emerged for an up-to-date practical guide to the field suitable for graduate students and junior and general practitioners. Get the Best Use of Different Techniques and Interpretations of the Results This edited volume provides the cement science community with a state-of-the-art overview of analytical techniques used in cement chemistry to study the hydration and microstructure of cements. Each chapter focuses on a specific technique, not only describing the basic principles behind the technique, but also providing essential, practical details on its application to the study of cement hydration. Each chapter sets out present best practice, and draws attention to the limitations and potential experimental pitfalls of the technique. Databases that supply examples and that support the analysis and interpretation of the experimental results strengthen a very valuable ready reference. Utilizing the day-to-day experience of practical experts in the field, this book: Covers sample preparation issues Discusses commonly used techniques for identifying and quantifying the phases making up cementitious materials (X-ray diffraction and thermogravimetric analysis) Presents good practice oncalorimetry and chemical shrinkage methods for studying cement hydration kinetics Examines two different applications of nuclear magnetic resonance (solid state NMR and proton relaxometry) Takes a look at electron microscopy, the preeminent microstructural characterization technique for cementitious materials Explains how to use and interpret mercury intrusion porosimetry Details techniques for powder characterization of cementitious materials Outlines the practical application of phase diagrams for hydrated cements Avoid common pitfalls by using A Practical Guide to Microstructural Analysis of Cementitious Materials. A one-of-a-kind reference providing the do’s and don’ts of cement chemistry, the book presents the latest research and development of characterisation techniques for cementitious materials, and serves as an invaluable resource for practicing professionals specializing in cement and concrete materials and other areas of cement and concrete technology.

This book presents select proceedings of the International Conference on Sustainable Construction and Building Materials (ICSCBM 2018), and examines a range of durable, energy-efficient, and next-generation construction and building materials produced from industrial wastes and byproducts. The topics covered include alternative, eco-friendly construction and building materials, next-generation concretes, energy efficiency in construction, and sustainability in construction project management. The book also discusses various properties and performance attributes of modern-age concretes including their durability, workability, and carbon footprint. As such, it offers a valuable reference for beginners, researchers, and professionals interested in sustainable construction and allied fields.

This volume focuses on research and practical issues linked to Calcined Clays for Sustainable Concrete. The main topics are geology of clays, hydration and performance of blended system with calcined clays, alkali activated binders, applications in concrete and mortar, durability of concrete under various aggressive conditions, and economic and environmental impacts of the use of calcined clays in cement based materials. This book compiles the different contributions of the 2nd International Conference on Calcined Clays for Sustainable Concrete, which took place in La Habana, December 5th-7th, 2017.The papers update the latest research in their field, carried out since the last conference in 2015. Overall it gives a broad view of research on calcined clays and their application in the field of construction, which will stimulate further research into calcined clays for sustainable concrete.

What can be done about the major concerns of our Global Economy on energy, global warming, sustainable development, user-friendly processes, and green chemistry? Here is an important contribution to the mastering of these phenomena today. Written by Joseph Davidovits, the inventor and founder of geopolymer science, it is an introduction to the subject for the newcomers, students, engineers and professionals. You will find science, chemistry, formulas and very practical information (including patents' excerpts) covering: - The mineral polymer concept: silicones and geopolymers, - Macromolecular structure of natural silicates and aluminosilicates, - Scientific Tools, X-rays, FTIR, NMR, - The synthesis of mineral geopolymers, Poly(siloxonate) and polysilicate, soluble silicate, Chemistry of (Na, K)-oligo-sialates: hydrous alumino-silicate gels and zeolites, Kaolinite / Hydrosodalite-based geopolymer, Metakaolin MK-750-based geopolymer, Calcium-based geopolymer, Rock-based geopolymer, Silica-based geopolymer, Fly ash-based geopolymer, Phosphate-based geopolymer, Organic-mineral geopolymer, - Properties: physical, chemical and long-term durability, - Applications: Quality controls, Development of user-friendly systems, Castable geopolymer, industrial and decorative applications, Geopolymer / fiber composites, Foamed geopolymer, Geopolymers in ceramic processing, Manufacture of geopolymer cement, Geopolymer concrete, Geopolymers in toxic and radioactive waste management. It is a textbook, a reference book instead of being a collection of scientific papers. Each chapter is followed by a bibliography of the relevant published literature including 80 patents, 125 tables, 363 figures, 560 references, 720 authors cited, representing the most up to date contributions of the scientific community. The industrial applications of geopolymers with engineering procedures and design of processes are also covered in this book

This book delves into the world of metakaolin (MK) and its impact on the properties of geopolymers. Beginning with an introduction to the abundance and versatility of kaolin, the author explores how calcination transforms it into the highly reactive material known as MK. The book investigates the incorporation of MK into different types of geopolymers and examines how factors such as precursor type and fineness, MK fineness, activator type and concentration, curing conditions, and testing age influence the resulting properties. Through a meticulous evaluation of prior studies, the text presents valuable insights into workability, setting time, density, compressive strength (with specific focus on slag, fly ash, and other precursors), flexural strength, splitting tensile strength, elastic modulus, porosity, water absorption, shrinkage, carbonation resistance, corrosion resistance, and other durability aspects. Drawing upon a wealth of knowledge, this work serves as a comprehensive reference for researchers and offers a roadmap for future investigations.