Modelling Electroanalytical Experiments By The Integral Equation Method

This comprehensive presentation of the integral equation method as applied to electro-analytical experiments is suitable for electrochemists, mathematicians and industrial chemists. The discussion focuses on how integral equations can be derived for various kinds of electroanalytical models. The book begins with models independent of spatial coordinates, goes on to address models in one dimensional space geometry and ends with models dependent on two spatial coordinates. Bieniasz considers both semi-infinite and finite spatial domains as well as ways to deal with diffusion, convection, homogeneous reactions, adsorbed reactants and ohmic drops. Bieniasz also discusses mathematical characteristics of the integral equations in the wider context of integral equations known in mathematics. Part of the book is devoted to the solution methodology for the integral equations. As analytical solutions are rarely possible, attention is paid mostly to numerical methods and relevant software. This book includes examples taken from the literature and a thorough literature overview with emphasis on crucial aspects of the integral equation methodology.

This book explains how the partial differential equations (pdes) in electroanalytical chemistry can be solved numerically. It guides the reader through the topic in a very didactic way, by first introducing and discussing the basic equations along with some model systems as test cases systematically. Then it outlines basic numerical approximations for derivatives and techniques for the numerical solution of ordinary differential equations. Finally, more complicated methods for approaching the pdes are derived. The authors describe major implicit methods in detail and show how to handle homogeneous chemical reactions, even including coupled and nonlinear cases. On this basis, more advanced techniques are briefly sketched and some of the commercially available programs are discussed. In this way the reader is systematically guided and can learn the tools for approaching his own electrochemical simulation problems. This new fourth edition has been carefully revised, updated and extended compared to the previous edition (Lecture Notes in Physics Vol. 666). It contains new material describing migration effects, as well as arrays of ultramicroelectrodes. It is thus the most comprehensive and didactic introduction to the topic of electrochemical simulation.

This monograph covers the most relevant applications of chemometrics in electrochemistry with special emphasis on electroanalytical chemistry. It reviews the use of chemometric methods for exploratory data analysis, experimental design and optimization, calibration, model identification, and experts systems. The book also provides a brief introduction to the fundamentals of the main chemometric methods and offers examples of data treatment for calibration and model identification. Due to the comprehensive coverage, this book offers an invaluable resource for graduate and postgraduate students, as well as for researchers in academic and industrial laboratories working in the area of electroanalysis and electrochemical sensors.

Flow Batteries The premier reference on flow battery technology for large-scale, high-performance, and sustainable energy storage From basics to commercial applications, Flow Batteries covers the main aspects and recent developments of (Redox) Flow Batteries, from the electrochemical fundamentals and the materials used to their characterization and technical application. Edited by a team of leading experts, including the “founding mother of vanadium flow battery technology” Maria Skyllas-Kazacos, the full scope of this revolutionary technology is detailed, including chemistries other than vanadium and organic flow batteries. Other key topics covered in Flow Batteries include: Flow battery computational modeling and simulation, including quantum mechanical considerations, cell, stack, and system modeling, techno-economics, and grid behavior A comparison of the standard vanadium flow battery variant with new and emerging flow batteries using different chemistries and how they will change the field Commercially available flow batteries from different manufacturers, their technology, and application ranges The pivotal role of flow batteries in overcoming the global energy crisis Flow Batteries is an invaluable resource for researchers and engineers in academia and industry who want to understand and work with this exciting new technology and explore the full range of its current and future applications.

This book addresses the main challenges in implementing the concepts that aim to replace the regular fossil-fuels based energy pattern with the novel energy pattern relying on renewable energy. As the built environment is one major energy consumer, well known and exploited by each community member, the challenges addressing the built environment has to be solved with the consistent contribution of the community inhabitants and its administration. The transition phase, which already is under implementation, is represented by the Nearly Zero Energy Communities (nZEC). From the research topics towards the large scale implementation, the nZEC concept is analyzed in this book, starting with the specific issues of the sustainable built environment, beyond the Nearly Zero Energy Buildings towards a more integrated view on the community (Chapter1) and followed by various implementation concepts for renewable heating & cooling (Chapter 2), for renewable electrical energy production at community level (Chapter 3) and for sustainable water use and reuse (Chapter 4). As the topic is still new, specific instruments supporting education and training (Chapter 5) are needed, aiming to provide the knowledge that can drive the communities in the near future and is expected to increase the acceptance towards renewable energy implemented at community level. The sub-chapters of this book are the proceedings of the 5th edition of the Conference for Sustainable Energy, during 19-21 October 2017, organized by the R&D Centre Renewable Energy Systems and Recycling, in the R&D Institute of the Transilvania University of Brasov. This event was organized under the patronage of the International Federation for the Science of Machines and Mechanisms (IFToMM) - the Technical Committee Sustainable Energy Systems, of the European Sustainable Energy Alliance (ESEIA) and of the Romanian Academy of Technical Sciences.

New Frontiers in Nanochemistry: Concepts, Theories, and Trends, Volume 1: Structural Nanochemistry is the first volume of the new three-volume set that explains and explores the important concepts from various areas within the nanosciences. This first volume focuses on structural nanochemistry and encompasses the general fundamental aspects of nanochemistry while simultaneously incorporating crucial material from other fields, in particular mathematic and natural sciences, with specific attention to multidisciplinary chemistry. Under the broad expertise of the editor, the volume contains 50 concise yet comprehensive entries from world-renowned scholars, alphabetically organizing a multitude of essential basic and advanced concepts, ranging from algebraic chemistry to new energy technology, from the bondonic theory of chemistry to spintronics, and from fractal dimension and kinetics to quantum dots and tight binding—and much more. The entries contain definitions, short characterizations, uses and usefulness, limitations, references, and more.

New Frontiers in Nanochemistry: Concepts, Theories, and Trends, 3-Volume Set explains and explores the important fundamental and advanced modern concepts from various areas of nanochemistry and, more broadly, the nanosciences. This innovative and one-of-a kind set consists of three volumes that focus on structural nanochemistry, topological nanochemistry, and sustainable nanochemistry respectively, collectively forming an explicative handbook in nanochemistry. The compilation provides a rich resource that is both thorough and accessible, encompassing the core concepts of multiple areas of nanochemistry. It also explores the content through a trans-disciplinary lens, integrating the basic and advanced modern concepts in nanochemistry with various examples, applications, issues, tools, algorithms, and even historical notes on the important people from physical, quantum, theoretical, mathematical, and even biological chemistry.