Nonlinearity And Chaos In Molecular Vibrations

Nonlinearity and Chaos in Molecular Vibrations deals systematically with a Lie algebraic approach to the study of nonlinear properties of molecular highly excited vibrations. The fundamental concepts of nonlinear dynamics such as chaos, fractals, quasiperiodicity, resonance, and the Lyapunov exponent, and their roles in the study of molecular vibrations are presented.The 20 chapters cover the basic ideas, the concept of dynamical groups, the integrable two-mode SU(2) system, the unintegrable three-mode SU(3) system, the noncompact su(1,1) algebraic application, su(3) symmetry breaking and its application and the quantal effect of asymmetric molecular rotation. Emphasis is given to: resonance and chaos, the fractal structure of eigencoefficients, the C-H bend motion of acetylene, regular and chaotic motion of DCN, the existence of approximately conserved quantum numbers, one-electronic motion in multi-sites, the Lyapunov exponent, actions of periodic trajectories and quantization, the H function and its application in vibrational relaxation as well as the Dixon dip and its destruction and chaos in the transitional states. This approach bridges the gap between molecular vibrational spectroscopy and nonlinear dynamics.The book presents a framework of information that readers can use to build their knowledge, and is therefore highly recommended for all those working in or studying molecular physics, molecular spectroscopy, chemical physics and theoretical physics. * Discusses nonlinearity and chaotic phenomena in molecular vibrations* Approaches the complicated highly excited molecular vibration* Provides clear information for students and researchers looking to expand knowledge in this field

This book focuses on the main idea that highly-excited molecular vibration is a nonlinear, many-body and semiclassical system. Therefore, many ideas and techniques in nonlinear fields such as chaos, resonance, Lyapunov exponent, etc. can be incorporated into this study. Together with the Lie algebraic coset algorithm, readers are able to approach the topics in a simple arithmetic and realistic way in contrast to the traditional solving of Schrödinger equation. Covering the author's research in over two decades, these works bridge the gaps between molecular vibration and nonlinear sciences, many new characters are introduced for molecular highly-excited vibration from a fresh viewpoint of nonlinearity, especially, the chaos. Related works of the elementary ideas in this field can be found in the first three chapters for the readers to be familiar with, while the rest of the chapters offer concrete examples with flourishing ideas and results on system dynamics which are not known or neglected by the traditional wave function algorithm.

Contents: Dissipative Systems: Introduction Nonlinearity Period Doubling to Chaos Lyapunov Exponent Power Spectra Correlations Remarks Feigenbaum Universality Feigenbaum Universality: Outline of Exact Renormalization Theory Experimental Observations Duffing Oscillator Period Doubling to Chaos in a CO2 Laser Experiment Bifurcations Intermittency (Pomeau-Manneville) Route to Chaos Quasiperiodicity to Chaos: Ruelle-Takens-Newhouse Scenario Strange Attractors, Dimensions, and Fractals Measuring Lyapunov Exponents Measuring Dimensions Kolmogorov Entropy Noise Maxwell-Bloch Equations Lorentz Model and Single-Mode Laser Single-Mode Instabilities: Homogeneous Broadening Mode Splitting Inhomogeneous Broadening: Chaos Associated with Casperson Instability Inhomogeneous Broadening: Experiments Multimode Instabilities Physical Explanations of Self-Pulsing Instabilities Transverse Mode Effects More Laser Instabilities Optical Bistability Chaos in Optically Bistability Hamiltonian Systems: Classical Hamiltonian Systems Integrability and Action-Angle Variables Integrability, Invariant Tori, and Quasiperiodicity Ergodicity, Mixing, and Chaos Fermi-Pasta-Ulam Model KAM Theorem Overlapping Resonances Henon-Heiles Model Characterization of Chaotic Behavior Is Classical Physics Really Deterministic? Kicked Pendulum and Standard Mapping Chaos in a Classical Model of Multiple-Photon Excitation of Molecular Vibrations Chaos in a Classical Model of a Rotating Molecule in a Laser Field Stochastic Excitation Quantum Chaos Regular and Irregular Spectra Kicked Two-State System Chaos in the Jaynes-Cummings Model Quantum Theory of the Kicked Pendulum Localization Classical and Quantum Calculations for a Hydrogen Atom in a Microwave Field Epilogue Readership: Laser scientists and engineers, physicists, applied mathematicians and researchers in nonlinear dynamics. Related Books Free and Guided Optical Beams Laser Cleaning II A Bouquet of Numbers and Other Scientific Offerings Universal Fluctuations Geometric Perturbation Theory in Physics

Very Good,No Highlights or Markup,all pages are intact.

This text, directed to the microwave engineers and Master and PhD students, is on the use of electromagnetics to the development and design of advanced integrated components distinguished by their extended field of applications. The results of hundreds of authors scattered in numerous journals and conference proceedings are carefully reviewed and classed. Several chapters are to refresh the knowledge of readers in advanced electromagnetics. New techniques are represented by compact electromagnetic–quantum equations which can be used in modeling of microwave-quantum integrated circuits of future In addition, a topological method to the boundary value problem analysis is considered with the results and examples. One extended chapter is for the development and design of integrated components for extended bandwidth applications, and the technology and electromagnetic issues of silicon integrated transmission lines, transitions, filters, power dividers, directional couplers, etc are considered. Novel prospective interconnects based on different physical effects are reviewed as well. The ideas of topology is applicable to the electromagnetic signaling and computing, when the vector field maps can carry discrete information, and this area and the results in topological signaling obtained by different authors are analyzed, including the recently designed predicate logic processor operating spatially represented signal units. The book is rich of practical examples, illustrations, and references and useful for the specialists working at the edge of contemporary technology and electromagnetics.

The new edition will provide the sole comprehensive resource available for non-linear optics, including detailed descriptions of the advances over the last decade from world-renowned experts.

Nonlinear dynamics has been successful in explaining complicated phenomena in well-defined low-dimensional systems. Now it is time to focus on real-life problems that are high-dimensional or ill-defined, for example, due to delay, spatial extent, stochasticity, or the limited nature of available data. How can one understand the dynamics of such sys