Palladium Oxides

With platinum and rhodium, palladium is one of the most important members of the platinum metal group. The last Gmelin treatment of it was in 1942, and knowledge of its properties and chemistry has made enormous strides since then. This volume is primarily concerned with binary compounds and with the coordination complexes derived from them. Although it is a member of the nickel-palladium-platinum triad, it more closely resernblas platinum in its binary and coordination chemistry, though being a second-row transition element it displays less tendency than does platinum to assume higher oxidation states. ln heterogeneous and homogeneous catalysis, referred to at appropriate points, palladium and its complexes are of great importance in bulk and fine chemieals production, effecting a wide variety of organic transformations. The arrangement of material in this volume follows the traditional Gmelin arrangement. Within each category of compounds or complexes the material is arranged, as usual, in order of ascending metal oxidation states (e. g., palladium(ll) precedes palladium(IV)). The chemistry of the palladium-hydrogen system is so large that it merits a separate volume, so this book starts with the binary oxides and oxopalladates followed by hydroxides, hydroxo complexes and aquo complexes. Then nitrides and nitrates are treated. They are followed by the large chapters on halides and their complexes (172 pages). The largest single chapter in this volume (11 0 pages) deals with chlorides, chloropalladates and other chloro complexes.

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Approx.530 pages Provides an overview of the material preparation and synthesis strategies of metal oxide composite and metal oxide hybrid materials for use in gas and humidity sensors Reviews emerging advanced metal oxide materials such as perovskites, spinel ferrites, and quaternary materials for gas and VOC sensors Discusses the potential opportunities and challenges to be circumvented in the use of metal oxide materials to enable new sensor technologies

Complex and Composite Metal Oxides for Gas, VOC, and Humidity Sensors focuses on an overview of the advanced nanocomposite metal oxide materials for use in sensors for environmental monitoring applications. Volume 1 Fundamentals and Approaches introduces the ground rules essential for the development of smart gas, VOC and humidity sensors. This volume familiarizes researchers with the different sensors (resistive, electrolyte, FET, optical etc.) developed on various properties that includes electrical, SPR, luminescence, fiber optics etc. fabricated using metal oxide hybrids and nanocomposites. Introduces fundamentals of electrical and optical gas and humidity sensors Reviews metal oxide hybrid materials for gas and humidity sensor applications, including metal oxide/polymer and metal oxide/carbon composite materials Discusses metal oxide candidate materials for use in gas, VOC, and humidity sensors