Perovskite Based Solar Cells

"Perovskite-Based Solar Cells: From Fundamentals to Tandem Devices" gives fundamental understanding of perovskite solar cells from the chemical composition of each thin layer composing the different stacks to the whole device. Special attention has been given to the development of the materials forming the perovskite solar cell and their effect on the device performance, in addition to the recent progress of this emerging technology. Moreover, light has been shed on the perovskite elaboration techniques, in addition to the several techniques proposed to improve both the efficiency and the stability of perovskite solar cells. Furthermore, special emphasis was given to the three types of tandem solar cells and their recent advances starting from Perovskite/perovskite tandem solar cells to Perovskite/ CIGS tandem cells to perovskite/ heterojunction silicon tandem solar cells. The latter constitute a promising solution to improve photovoltaic solar cells performance.

Perovskite Photovoltaics: Basic to Advanced Concepts and Implementation examines the emergence of perovskite photovoltaics, associated challenges and opportunities, and how to achieve broader development. Consolidating developments in perovskite photovoltaics, including recent progress solar cells, this text also highlights advances and the research necessary for sustaining energy. Addressing different photovoltaics fields with tailored content for what makes perovskite solar cells suitable, and including commercialization examples of large-scale perovskite solar technology. The book also contains a detailed analysis of the implementation and economic viability of perovskite solar cells, highlighting what photovoltaic devices need to be generated by low cost, non-toxic, earth abundant materials using environmentally scalable processes. This book is a valuable resource engineers, scientists and researchers, and all those who wish to broaden their knowledge on flexible perovskite solar cells. Includes contributions by leading solar cell academics, industrialists, researchers and institutions across the globe Addresses different photovoltaics fields with tailored content for what makes perovskite solar cells different Provides commercialization examples of large-scale perovskite solar technology, giving users detailed analysis on the implementation, technical challenges and economic viability of perovskite solar cells

Presents a thorough overview of perovskite research, written by leaders in the field of photovoltaics The use of perovskite-structured materials to produce high-efficiency solar cells is a subject of growing interest for academic researchers and industry professionals alike. Due to their excellent light absorption, longevity, and charge-carrier properties, perovskite solar cells show great promise as a low-cost, industry-scalable alternative to conventional photovoltaic cells. Perovskite Solar Cells: Materials, Processes, and Devices provides an up-to-date overview of the current state of perovskite solar cell research. Addressing the key areas in the rapidly growing field, this comprehensive volume covers novel materials, advanced theory, modelling and simulation, device physics, new processes, and the critical issue of solar cell stability. Contributions by an international panel of researchers highlight both the opportunities and challenges related to perovskite solar cells while offering detailed insights on topics such as the photon recycling processes, interfacial properties, and charge transfer principles of perovskite-based devices. Examines new compositions, hole and electron transport materials, lead-free materials, and 2D and 3D materials Covers interface modelling techniques, methods for modelling in two and three dimensions, and developments beyond Shockley-Queisser Theory Discusses new fabrication processes such as slot-die coating, roll processing, and vacuum sublimation Describes the device physics of perovskite solar cells, including recombination kinetics and optical absorption Explores innovative approaches to increase the light conversion efficiency of photovoltaic cells Perovskite Solar Cells: Materials, Processes, and Devices is essential reading for all those in the photovoltaic community, including materials scientists, surface physicists, surface chemists, solid state physicists, solid state chemists, and electrical engineers.

Perovskite supercapacitors have a promising future in the area of energy storage; due to their superior optoelectronic characteristics, simple device construction and increased efficiency. The book focuses on organic-inorganic perovskite solar cells (PSCs); organometallic halides-based perovskite solar cells (OMHP-SCs); power conversion efficiency (PCE); ferroelectric-based perovskites; recycling of perovskite-based solar cell modules; lead-free perovskite solar cells (PSCs); and inorganic tin perovskite solar cells. Keywords: Energy Storage, Solar Cells, Perovskite Supercapacitors, Organometallic Halides-Based Perovskite, Ferroelectric Materials, Recycling and Recovery of Solar Cells, Lead-Free Perovskite Solar Cells, Organic/Inorganic Based Hybrid Perovskite, Optical Absorption, Charge Transfer, Raw Materials, Optoelectronic Characteristics, Device Construction Procedure, Environmental Instability, Power Conversion Efficiency, Passivation Techniques, Capacitors, Fuel Cells, Toxicity of Lead, Cost Analysis of Recycling, AHP Methodology.

Unparalleled coverage of the most vibrant research field in photovoltaics! Hybrid perovskites, revolutionary game-changing semiconductor materials, have every favorable optoelectronic characteristic necessary for realizing high efficiency solar cells. The remarkable features of hybrid perovskite photovoltaics, such as superior material properties, easy material fabrication by solution-based processing, large-area device fabrication by an inkjet technology, and simple solar cell structures, have brought enormous attentions, leading to a rapid development of the solar cell technology at a pace never before seen in solar cell history. Hybrid Perovskite Solar Cells: Characteristics and Operation covers extensive topics of hybrid perovskite solar cells, providing easy-to-read descriptions for the fundamental characteristics of unique hybrid perovskite materials (Part I) as well as the principles and applications of hybrid perovskite solar cells (Part II). Both basic and advanced concepts of hybrid perovskite devices are treated thoroughly in this book; in particular, explanatory descriptions for general physical and chemical aspects of hybrid perovskite photovoltaics are included to provide fundamental understanding. This comprehensive book is highly suitable for graduate school students and researchers who are not familiar with hybrid perovskite materials and devices, allowing the accumulation of the accurate knowledge from the basic to the advanced levels.

The increasing use of metal halide perovskites as light harvesters has stunned the photovoltaic community. The book, Perovskite Solar Cells: Technology and Practices, covers the basics and provides up-to-date research in the field of perovskite photovoltaics—a fast trending branch of the thin film photovoltaic generation. This comprehensive handbook provides a broad and overall picture of perovskite solar cells (PSCs), starting with the history of development and revolution of PSCs. The authors then delve into electron-transporting materials, hole-transporting materials, and lead-free alternatives. An important chapter on tandem solar cells is also included. The chapters discuss how different layers in PSCs are fabricated and function and how their roles are as important as the perovskite layer itself. It explores what has been done and what can probably be done to further improve the performance of this device.

Hybrid organic and inorganic perovskites (HOIP) have shown remarkable progress since the first realization of efficient PSCs with a PCE of 3.9% in 2009; the record PCE reached 23.3% in 2018. The next step will undoubtedly be developing scale-up techniques for transitioning small-area devices to large-area modules. Most books outline only the basic theoretical background, fabrication methods and/or applications. To bridge the gap between academia and industry, a profound understanding of the recent advancements in the HOIPs field is necessary. Experts' insights in this book present an in-depth overview of information regarding the materials synthesis methodologies, effects of dopants, optimized optoelectronic properties, suitable deposition methods, engineering and improving the stability of various device architectures using printing methods for flexible large-area PSC modules, including the module concept, discuss various challenges and issues that can open the door for the researchers towards commercialization of durable perovskite solar cells.Moreover, this book also covers the developments on the zero-, two-, and three-dimensional non-toxic perovskite/non-perovskite materials, the radiation degradation of solar cells, the synergetics of cooperative phenomena in tandem systems and provide some recommendations to overcome the challenges for improving the photoconversion efficiency.

Perovskite is a well-known structure with the chemical formula ABX3, where A and B are cations coordinated with 12 and 6 anions, respectively, and X is an anion. When a halogen anion is used, the monovalent A and divalent B cations can be stabilized with respect to a tolerance factor ranging from ~0.8 to 1. Since the first report on ~10% efficiency and long-term stability of solid-state perovskite solar cells (PSCs) in 2012 and two subsequent seed reports on perovskite-sensitized solar cells in 2009 and 2011, PSCs have received increasing attention. The power conversion efficiency of PSCs was certified to be more than 25% in 2020, surpassing thin-film solar cell technologies. Methylammonium or formamidinium organic ion–based lead iodide perovskite has been used for high-efficiency PSCs. The first report on solid-state PSCs triggered perovskite photovoltaics, leading to more than 23,000 publications as of October 2021. In addition, halide perovskite has shown excellent performance when applied to light-emitting diodes (LEDs), photodetectors, and resistive memory, indicating that halide perovskite is multifunctional. This book explains the electro-optical and ferroelectric properties of perovskite and details the recent progress in scalable and tandem PSCs as well as perovskite LEDs and resistive memory. It is a useful textbook and self-help study guide for advanced undergraduate- and graduate-level students of materials science and engineering, chemistry, chemical engineering, and nanotechnology; for researchers in photovoltaics, LEDs, resistive memory, and perovskite-related opto-electronics; and for general readers who wish to gain knowledge about halide perovskite.