Plasmonic Nanomaterials

This book comprehensively explores the field of plasmonic nanomaterials and their significant impact on organic synthesis and catalysis. It provides an in-depth understanding of the characterization techniques used for studying these unique materials. It emphasizes the role of plasmonic nanomaterials as efficient catalysts in organic synthesis, showcasing their ability to enhance reaction rates and selectivity. It covers a wide range of organic reactions, including carbon–carbon and carbon–heteroatom bond formation, oxidation, reduction, and so on. It presents detailed case studies and examples that illustrate the successful application of plasmonic nanomaterials in these catalytic processes. The book is a valuable resource for researchers, students, and professionals interested in the synthesis, characterization, and applications of plasmonic nanomaterials in organic chemistry and catalysis.

Plasmonic nanoparticles (NPs) represent an outstanding class of nanomaterials that have the capability to localize light at the nanoscale by exploiting a phenomenon called localized plasmon resonance. The book is aimed at reviewing recent efforts devoted to utilize NPs in many research fields, such as photonics, optics, and plasmonics. In this framework, particular interest is devoted to active plasmonics, a quite broad concept that indicates those applications in which NPs play an active role, like realization of gain-assisted means, utilization of NPs embedded in liquid crystalline and flexible materials, and exploitation of renewable solar energy. The book puts together contributions from outstanding research groups in the field of plasmonic nanomaterials all over the world. It provides basic and advanced knowledge in the fields of plasmonics, photonics, and optics and covers research on plasmonic nanomaterials for applications ranging from plasmonics to photonics.

Surface-enhanced Raman scattering (SERS) is a research technique that was discovered in the mid-1970s. SERS is a powerful and fast tool for analysis, which has a high detection sensitivity for a great number of chemical and biological molecules. However, it is in this last decade that a very significant explosion of the fabrication of highly sensitive SERS substrates has occurred using novel designs of plasmonic nanostructures and novel fabrication techniques of the latter, as well as new plasmonic materials and hybrid nanomaterials. Thus, this Special Issue is dedicated to reporting on the latest advances in novel plasmonic nanomaterials that are applied to the SERS domain. These developments are illustrated through several articles and reviews written by researchers in this field from around the world.

World Scientific Reference on Plasmonic Nanomaterials: Principles, Design and Bio-applications is a book collection that encompasses multiple aspects of the exciting and timely field of nanoplasmonics, under the coordination of international plasmonic nanomaterials expert, Dr Luis Liz-Marzán. Plasmonics has a long history, from stained glass in ancient cathedrals, through pioneering investigations by Michael Faraday, all the way into the nanotechnology era, where it blossomed into an extremely active field of research with potential applications in a wide variety of technologies.Given the breadth of the materials, phenomena and applications related to plasmonics, this Reference Set offers a collection of chapters within dedicated volumes, focusing on the description of selected phenomena, with an emphasis in chemistry as an enabling tool for the fabrication of, often sophisticated, plasmonic nanoarchitectures and biomedicine as the target application.Basic principles of surface plasmon resonances are described, as well as those mechanisms related to related phenomena such as surface-enhanced spectroscopies or plasmonic chirality. Under the guidance of theoretical models, wet chemistry methods have been implemented toward the synthesis of a wide variety of nanoparticles with different compositions and tailored morphology. But often the optimal nanoarchitecture requires post-synthesis treatments, including functionalization of nanoparticle surfaces, application of external stimuli toward self-assembly into well-defined supraparticle structures and so-called supercrystals. All such nanomaterials can find applications in various biomedical aspects, most often in relation to diagnosis, through either the detection of disease biomarkers at extremely low concentrations or the design of bioimaging methods for in vivo monitoring. Additionally, novel therapeutic tools can also profit from plasmonic nanomaterials, such as photothermal therapy or nanocatalysis.The reference set thus offers comprehensive information of an extremely active subset within the world of plasmonic nanomaterials and their applications, which aims at not just collecting existing knowledge but also promoting further research and technology transfer into the market and the clinic.

Nanoparticles with their unique properties are interesting building blocks for the construction of new nanomaterials. By controlling the composition as well as the structure of these nanoparticle-based materials, novel properties can emerge. In this thesis, a new type of protein-based materials was realized by using an innovative design approach with two oppositely charged ferritin protein containers as template for the precise positioning of the nanoparticles. Nanoparticle incorporation inside the protein container cavity was performed by encapsulation of surface functionalized gold nanoparticles with a dis- and reassembly approach or synthesis of metal oxide nanoparticles in situ inside the protein container cavity. The crystallization of oppositely charged protein containers with nanoparticle cargo yielded highly ordered nanoparticle superlattices as free-standing crystals, with up to a few hundred micrometers in size. Structural studies and characterization of optical as well as catalytic properties of the binary crystals were performed. Because the protein scaffold is independent of the nanoparticle cargo, this modular approach will enable tuning of the material properties by choice of nanoparticle content, assembly type and protein container type.

Plasmonics is a rapidly developing field that combines fundamental research and applications ranging from areas such as physics to engineering, chemistry, biology, medicine, food sciences, and the environmental sciences. Plasmonics appeared in the 1950s with the discovery of surface plasmon polaritons. Plasmonics then went through a novel propulsion in the mid-1970s, when surface-enhanced Raman scattering was discovered. Nevertheless, it is in this last decade that a very significant explosion of plasmonics and its applications has occurred. Thus, this book provides a snapshot of the current advances in these various areas of plasmonics and its applications, such as engineering, sensing, surface-enhanced fluorescence, catalysis, and photovoltaic devices.

Plasmonic Materials and Metastructures: Fundamentals, Current Status, and Perspectives reviews the current status and emerging trends in the development of conventional and alternative plasmonic materials. Sections cover fundamentals and emerging trends of plasmonic materials development, including synthesis strategies (chemical and physical) and optical characterization techniques. Next, the book addresses fundamentals, properties, remaining barriers for commercial translation, and the latest advances and opportunities for conventional noble metal plasmonic materials. Fundamentals and advances for alternative plasmonic materials are also reviewed, including two-dimensional hybrid materials composed of graphene, monolayer transition metal dichalcogenides, boron nitride, etc. In addition, other sections cover applications of plasmonic metastructures enabled by plasmonic materials with improved material properties and newly discovered functionalities. Applications reviewed include quantum plasmonics, topological plasmonics, chiral plasmonics, nanolasers, imaging (metalens), active, and integrated technologies. Provides an overview of materials properties, characterization and fabrication techniques for plasmonic metastructured materials Includes key concepts and advances for a wide range of metastructured materials, including metamaterials, metasurfaces and epsilon-near-zero plasmonic metastructures Discusses emerging applications and barriers to commercial translation for quantum plasmonics, topological plasmonics, nanolasers, imaging and integrated technologies

Biosensors Based on Nanomaterials and Nanodevices links interdisciplinary research from leading experts to provide graduate students, academics, researchers, and industry professionals alike with a comprehensive source for key advancements and future trends in nanostructured biosensor development. It describes the concepts, principles, materials, device fabrications, functions, system integrations, and applications of various types of biosensors based on signal transduction mechanisms, including fluorescence, photonic crystal, surface-enhanced Raman scattering, electrochemistry, electro-luminescence, field-effect transistor, and magnetic effect. The book: Explains how to utilize the unique properties of nanomaterials to construct nanostructured biosensors to achieve enhanced performance Features examples of biosensors based on both typical and emerging nanomaterials, such as gold nanoparticles, quantum dots, graphene, graphene oxides, magnetic nanoparticles, carbon nanotubes, inorganic nanowires/nanorods, plasmonic nanostructures, and photonic crystals Demonstrates the broad applications of nanostructured biosensors in environmental monitoring, food safety, industrial quality assurance, and in vitro and in vivo health diagnosis Inspires new ideas for tackling multiscale and multidisciplinary issues in developing high-performance biosensors for complex practical biomedical problems Focusing on the connection between nanomaterials research and biosensor development, Biosensors Based on Nanomaterials and Nanodevices illustrates the exciting possibilities and critical challenges of biosensors based on nanomaterials and nanodevices for future health monitoring, disease diagnosis, therapeutic treatments, and beyond.