Reactive Transport Modeling Of Fluid Rock Interactions Associated With Carbonate Diagenesis And Implications For Reservoir Quality Prediction

Diagenesis research is the foundation of hydrocarbon reservoir characterization and exploration. Reactive transport modeling (RTM) is an emerging approach for diagenesis research, with unique capability of quantification and forward modeling of the coupled thermo-hydro-chemical processes of diagenesis. Using TOUGHREACT simulator, this thesis investigates the two most important fluid-rock interactions in carbonate rocks, i.e., dolomitization and karstification, based on generic model analyses and a case study in the Ordos Basin, China. In particular, this study attempts to quantitatively characterize the diagenetic processes and to reconstruct the diagenesis-porosity evolution of carbonate reservoirs. Some controversies in carbonate diagenesis research, which cannot be well explained by classical geological methods, have also been discussed. The results are helpful to better understand the spatial-temporal distribution and co-evolution of diagenesis-mineral-porosity during the complicated diagenetic processes with their potential controlling factors, and to reduce the uncertainty of reservoir quality prediction.

Teaches the application of Reactive Transport Modeling (RTM) for subsurface systems in order to expedite the understanding of the behavior of complex geological systems This book lays out the basic principles and approaches of Reactive Transport Modeling (RTM) for surface and subsurface environments, presenting specific workflows and applications. The techniques discussed are being increasingly commonly used in a wide range of research fields, and the information provided covers fundamental theory, practical issues in running reactive transport models, and how to apply techniques in specific areas. The need for RTM in engineered facilities, such as nuclear waste repositories or CO2 storage sites, is ever increasing, because the prediction of the future evolution of these systems has become a legal obligation. With increasing recognition of the power of these approaches, and their widening adoption, comes responsibility to ensure appropriate application of available tools. This book aims to provide the requisite understanding of key aspects of RTM, and in doing so help identify and thus avoid potential pitfalls. Reactive Transport Modeling covers: the application of RTM for CO2 sequestration and geothermal energy development; reservoir quality prediction; modeling diagenesis; modeling geochemical processes in oil & gas production; modeling gas hydrate production; reactive transport in fractured and porous media; reactive transport studies for nuclear waste disposal; reactive flow modeling in hydrothermal systems; and modeling biogeochemical processes. Key features include: A comprehensive reference for scientists and practitioners entering the area of reactive transport modeling (RTM) Presented by internationally known experts in the field Covers fundamental theory, practical issues in running reactive transport models, and hands-on examples for applying techniques in specific areas Teaches readers to appreciate the power of RTM and to stimulate usage and application Reactive Transport Modeling is written for graduate students and researchers in academia, government laboratories, and industry who are interested in applying reactive transport modeling to the topic of their research. The book will also appeal to geochemists, hydrogeologists, geophysicists, earth scientists, environmental engineers, and environmental chemists.

Reservoir quality is studied using a wide range of similar techniques in both sandstones and carbonates. Sandstone and carbonate reservoir quality both benefit from the study of modern analogues and experiments, but modelling approaches are currently quite different for these two types of reservoirs. There are many common controls on sandstone and carbonate reservoir quality, but also distinct differences due primarily to mineralogy. Numerous controversies remain including the question of oil inhibition, the key control on pressure solution and geochemical flux of material to or from reservoirs. This collection of papers contains case-study-based examples of sandstone and carbonate reservoir quality prediction as well as modern analogue, outcrop analogue, modelling and advanced analytical approaches.

This volume highlights key challenges for fluid-flow prediction in carbonate reservoirs, the approaches currently employed to address these challenges and developments in fundamental science and technology. The papers span methods and case studies that highlight workflows and emerging technologies in the fields of geology, geophysics, petrophysics, reservoir modelling and computer science. Topics include: detailed pore-scale studies that explore fundamental processes and applications of imaging and flow modelling at the pore scale; case studies of diagenetic processes with complementary perspectives from reactive transport modelling; novel methods for rock typing; petrophysical studies that investigate the impact of diagenesis and fault-rock properties on acoustic signatures; mechanical modelling and seismic imaging of faults in carbonate rocks; modelling geological influences on seismic anisotropy; novel approaches to geological modelling; methods to represent key geological details in reservoir simulations and advances in computer visualization, analytics and interactions for geoscience and engineering.

The interaction of the lithosphere and hydrosphere sets the boundary conditions for life, as water and the nutrients extracted from rocks are essential to all known life-forms. Water-rock interaction also affects the fate and transport of pollutants, mediates the long-term cycling of fluids and metals in the earth's crust, impacts the migration and

Volume 70 of Reviews in Mineralogy and Geochemistry represents an extensive review of the material presented by the invited speakers at a short course on Thermodynamics and Kinetics of Water-Rock Interaction held prior to the 19th annual V. M. Goldschmidt Conference in Davos, Switzerland (June 19-21, 2009). Contents: Thermodynamic Databases for Water-Rock Interaction Thermodynamics of Solid Solution-Aqueous Solution Systems Mineral Replacement Reactions Thermodynamic Concepts in Modeling Sorption at the Mineral-Water Interface Surface Complexation Modeling: Mineral Fluid Equilbria at the Molecular Scale The Link Between Mineral Dissolution/Precipitation Kinetics and Solution Chemistry Organics in Water-Rock Interactions Mineral Precipitation Kinetics Towards an Integrated Model of Weathering, Climate, and Biospheric Processes Approaches to Modeling Weathered Regolith Fluid-Rock Interaction: A Reactive Transport Approach Geochemical Modeling of Reaction Paths and Geochemical Reaction Networks