Solid State Chemistry V

Preparative Methods in Solid State Chemistry deals with the preparative methods used in solid state chemistry and highlights the importance of the chemist's role in preparing materials of desired quality as well as obtaining materials according to the requirements of the user such as the physicist. Topics covered range from high-pressure techniques in preparative chemistry to methods of growing single crystals of high-melting-point oxides. This book is comprised of 14 chapters and begins with an overview of possibilities for high-pressure synthesis, as well as the methods used to obtain high pressures, including transmission by gaseous or liquid fluids or in the solid state. The method of shock waves is then considered both from the point of view of thermodynamics and thermoelasticity, along with the possibility of using superpressures for evidently revolutionary applications. Subsequent chapters focus on the synthesis of single crystals of refractory oxides either at high temperatures (essentially liquid-solid transformations) or at lower temperatures in the presence of a solvent or a chemical reagent. The production of single crystals by electrolytic reduction in molten salts is also described. Numerous examples of vapor transport reactions in a temperature gradient are presented. This monograph should be of interest to chemists and students of solid state chemistry.

Volume is indexed by Thomson Reuters CPCI-S (WoS). This book features 100 refereed papers, grouped under the following six headings: Advanced Synthesis & Characterization Techniques of Materials, Structure & Electron Structure of Solids, Chemistry of Glasses, Novel Inorganic Materials, Layered Compounds, Clathrates & Intercalates, Deposited Films & Surface Chemistry.

The book on solid state chemistry presents studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids. Research areas covered in this book include: bonding in solids, crystal chemistry, crystal growth mechanisms, diffusion epitaxy, high-pressure processes, magnetic properties of materials, optical characterisation of materials, order-disorder, phase equilibria and transformation mechanisms, reactions at surfaces, statistical mechanics of defect interactions, structural studies and transport phenomena.

Solid-state chemistry continues to span and to spawn multiple materials research areas, attracting investigators from chemistry, condensed-matter physics, materials science and engineering, ceramics, chemical engineering, and mineralogy/geology, to name a few. The common challenge is to understand and to predict structures and properties of new materials. As with earlier volumes in this series from the Materials Research Society, the presentations here represent interdisciplinary research from around the world and explore not only recent advances in the solid-state chemistry of inorganic materials, but also their impact on commercial applications. The book covers a broad range of topics, including synthesis and characterization of novel functional materials; design and fabrication of nanostructures and nanomaterials; crystal and structural chemistry; catalysis; gas separation and storage; and magnetic and optical applications. Both theoretical and computational studies of solid-state inorganic materials are featured. Joint presentations with solid-state ionics are also particularly fruitful.

The whole of Volume 22 is devoted to the kinetics and mechanisms of the decomposition and interaction of inorganic solids, extended to include metal carboxylates. After an introductory chapter on the characteristic features of reactions in the solid phase, experimental methods of investigation of solid reactions and the measurement of reaction rates are reviewed in Chapter 2 and the theory of solid state kinetics in Chapter 3. The reactions of single substances, loosely grouped on the basis of a common anion since it is this constituent which most frequently undergoes breakdown, are discussed in Chapter 4, the sequence being effectively that of increasing anion complexity. Chapter 5 covers reactions between solids, and includes catalytic processes where one solid component remains unchanged, double compound formation and rate processes involving the interactions of more than three crystalline phases. The final chapter summarises the general conclusions drawn in the text of Chapter 2-5.

Solid-state chemistry continues to span and to spawn multiple materials research areas, attracting investigators from chemistry, condensed-matter physics, materials science and engineering, ceramics, chemical engineering, and mineralogy/geology, to name a few. The common challenge is to understand and to predict structures and properties of new materials. As with earlier volumes in this series from the Materials Research Society, the presentations here represent interdisciplinary research from around the world and explore not only recent advances in the solid-state chemistry of inorganic materials, but also their impact on commercial applications. The book covers a broad range of topics, including synthesis and characterization of novel functional materials; design and fabrication of nanostructures and nanomaterials; crystal and structural chemistry; catalysis; gas separation and storage; and magnetic and optical applications. Both theoretical and computational studies of solid-state inorganic materials are featured. Joint presentations with solid-state ionics are also particularly fruitful.

The book on solid state chemistry presents studies of chemical, structural, thermodynamic, electronic, magnetic, and optical properties and processes in solids. Research areas include: bonding in solids, crystal chemistry, crystal growth mechanisms, diffusion epitaxy, high-pressure processes, magnetic properties of materials, optical characterisation of materials, order-disorder, phase equilibria and transformation mechanisms, reactions at surfaces, statistical mechanics of defect interactions, structural studies and transport phenomena.