Spectroscopic Applications Of Terahertz Quantum Cascade Lasers

Quantum cascade lasers (QCLs) are attractive for high-resolution spectroscopy because they can provide high power and a narrow linewidth. They are particularly promising in the terahertz (THz) range since they can be used as local oscillators for heterodyne detection as well as transmitters for direct detection. However, THz QCL-based technologies are still under development and are limited by the lack of frequency tunability as well as the frequency and output power stability for free-running operation. In this dissertation, frequency tuning and linewidth of THz QCLs are studied in detail by using rotational spectroscopic features of molecular species. In molecular spectroscopy, the Doppler eff ect broadens the spectral lines of molecules in the gas phase at thermal equilibrium. Saturated absorption spectroscopy has been performed that allows for sub-Doppler resolution of the spectral features. One possible application is QCL frequency stabilization based on the Lamb dip. Since the tunability of the emission frequency is an essential requirement to use THz QCL for high-resolution spectroscopy, a new method has been developed that relies on near-infrared (NIR) optical excitation of the QCL rear-facet. A wide tuning range has been achieved by using this approach. The scheme is straightforward to implement, and the approach can be readily applied to a large class of THz QCLs. The frequency and output stability of the local oscillator has a direct impact on the performance and consistency of the heterodyne spectroscopy. A technique has been developed for a simultaneous stabilization of the frequency and output power by taking advantage of the frequency and power regulation by NIR excitation. The results presented in this thesis will enable the routine use of THz QCLs for spectroscopic applications in the near future.

A state-of-the-art overview of this rapidly expanding field, featuring fundamental theory, practical applications, and real-life examples.

The terahertz regime of the electromagnetic spectrum was largely unexplored due to the lack of technology needed to generate and detect the radiation. However, in the last couple of decades, there has been a dramatic increase in tools needed to harness the radiation. This remarkable progress made in the development of terahertz sources, components, and detectors has resulted in an ever-increasing inquisitiveness of the applications of terahertz technology in a wide range of fields including medicine, pharmaceuticals, security, sensing, and quality assurance. This book, Terahertz Spectroscopy - A Cutting Edge Technology, presents an overview of the recent advances in terahertz technology and their application in a vast array of fields. The scientists and students are encouraged to read and share the content of this volume. The book also provides a good starting point for researchers who are new to the terahertz regime. The various chapters of the book have been written by renowned scientists in different parts of the world who are at the forefront of terahertz research fields. It is our (InTech publisher, editor, and authors) hope that this book will enhance knowledge and stimulate more interest and future research in terahertz technology.

Terahertz (THz) radiation with frequencies between 100 GHz and 30 THz has developed into an important tool of science and technology, with numerous applications in materials characterization, imaging, sensor technologies, and telecommunications. Recent progress in THz generation has provided ultrashort THz pulses with electric field amplitudes of up to several megavolts/cm. This development opens the new research field of nonlinear THz spectroscopy in which strong light-matter interactions are exploited to induce quantum excitations and/or charge transport and follow their nonequilibrium dynamics in time-resolved experiments. This book introduces methods of THz generation and nonlinear THz spectroscopy in a tutorial way, discusses the relevant theoretical concepts, and presents prototypical, experimental, and theoretical results in condensed matter physics. The potential of nonlinear THz spectroscopy is illustrated by recent research, including an overview of the relevant literature.

Learn how the rapidly expanding area of mid-infrared and terahertz photonics has been revolutionized in this comprehensive overview. State-of-the-art practical applications are supported by real-life examples and expert guidance. Also featuring fundamental theory enabling you to improve performance of both existing and future devices.

This book covers the latest advances in the techniques employed to manage the THz radiation and its potential uses. It has been subdivided in three sections: THz Detectors, THz Sources, Systems and Applications. These three sections will allow the reader to be introduced in a logical way to the physics problems of sensing and generation of the terahertz radiation, the implementation of these devices into systems including other components and finally the exploitation of the equipment for real applications in some different field. All of the sections and chapters can be individually addressed in order to deepen the understanding of a single topic without the need to read the whole book. The THz Detectors section will address the latest developments in detection devices based on three different physical principles: photodetection, thermal power detection, rectification. The THz Sources section will describe three completely different generation methods, operating in three separate scales: quantum cascade lasers, free electron lasers and non-linear optical generation. The Systems and Applications section will take care of introducing many of the aspects needed to move from a device to an equipment perspective: control of terahertz radiation, its use in imaging or in spectroscopy, potential uses in security, and will address also safety issues. The text book is at a level appropriate to graduate level courses up to researchers in the field who require a reference book covering all aspects of terahertz technology.

A quantum cascade (QC) laser is a specific type of semiconductor laser that operates through principles of quantum mechanics. In less than a decade QC lasers are already able to outperform previously designed double heterostructure semiconductor lasers. Because there is a genuine lack of compact and coherent devices which can operate in the far-infrared region the motivation exists for designing a terahertz QC laser. A device operating at this frequency is expected to be more efficient and cost effective than currently existing devices. It has potential applications in the fields of spectroscopy, astronomy, medicine and free-space communication as well as applications to near-space radar and chemical/biological detection. The overarching goal of this research was to find QC laser parameter combinations which can be used to fabricate viable structures. To ensure operation in the THz region the device must conform to the extremely small energy level spacing range from Æ10-15 meV. The time and expense of the design and production process is prohibitive, so an alternative to fabrication was necessary. To accomplish this goal a model of a QC laser, developed at Worchester Polytechnic Institute with sponsorship from the Air Force Research Laboratory Sensors Directorate, and the General Multiobjective Parallel Genetic Algorithm (GenMOP), developed at the Air Force Institute of Technology, were integrated to form a computer simulation which stochastically searches for feasible solutions.

The book highlights recent developments in the field of spectroscopy by providing the readers with an updated and high-level of overview. The focus of this book is on the introduction to concepts of modern spectroscopic techniques, recent technological innovations in this field, and current examples of applications to molecules and materials relevant for academia and industry. The book will be beneficial to researchers from various branches of science and technology, and is intended to point them to modern techniques, which might be useful for their specific problems. Spectroscopic techniques, that are discussed include, UV-Visible absorption spectroscopy, XPS, Raman spectroscopy, SERS, TERS, CARS, IR absorption spectroscopy, SFG, LIBS, Quantum cascade laser (QCL) spectroscopy, fluorescence spectroscopy, ellipsometry, cavity-enhanced absorption spectroscopy, such as cavity ring-down spectroscopy (CRDS) and evanescent wave-CRDS both in gas and condensed phases, time-resolved spectroscopy etc. Applications introduced in the different chapters demonstrates the usefulness of the spectroscopic techniques for the characterization of fundamental properties of molecules, e.g. in connection with environmental impact, bio-activity, or usefulness for pharmaceutical drugs, and materials important e.g. for nano-science, nuclear chemistry, or bio-applications. The book presents how spectroscopic techniques can help to better understand substances, which have also great impact on questions of social and economic relevance (environment, alternative energy, etc.).