Synthetic Methods In Step Growth Polymers

Alles über die Stufenwachstums-Polymerisation - von Syntheseverfahren und Reinigungsmethoden bis zur Charakterisierung der Produkte - finden Sie in diesem Buch. - bietet einen Ausblick auf zukünftige Trends - mit historischen Informationen - erläutert die Klassifikation von Stufenwachstumspolymeren

Synthetic Methods in Step-Growth Polymers By Martin E. Rogers

Presents the latest work in transition metal catalyzed polymerization, dendritic and hyperbranched systems, poly(aryl ether) synthesis, polyimides, and high-temperature polymers. Describes recent research on commercially important polymers based on step-growth polymerization. Includes well-referenced overview articles that review step-growth polymerization and indicate how individual research papers have impacted the field.

Edited by a leading authority in the field, the first book on this important and emerging topic provides an overview of the latest trends in sequence-controlled polymers. Following a brief introduction, the book goes on to discuss various synthetic approaches to sequence-controlled polymers, including template polymerization, genetic engineering and solid-phase chemistry. Moreover, monomer sequence regulation in classical polymerization techniques such as step-growth polymerization, living ionic polymerizations and controlled radical polymerizations are explained, before concluding with a look at the future for sequence-controlled polymers. With its unique coverage of this interdisciplinary field, the text will prove invaluable to polymer and environmental chemists, as well as biochemists and bioengineers.

A concise and practical overview of the most important modern synthetic aspects of conjugated polymers and carbon materials, including their properties and applications. Well structured, this book summarizes recent achievements, outlines the current state and reviews research trends. As such, a wide variety of polymerization techniques are included on both a strategic as well as a practical level, including Stille, Suzuki , and direct (hetero)arylation polymerizations. Furthermore, it covers various carbon-rich materials, such as graphene and carbon nanotubes, followed by a look at how the different synthetic pathways and strategies influence their final properties, for example, for use in organic electronic devices. The whole is rounded off with a discussion of future technology advances. An essential reference for newcomers as well as experienced researchers in the field.

The literature in polymerization reaction engineering has bloomed sufficiently in the last several years to justify our attempt in putting together this book. Rather than offer a comprehensive treatment of the entire field, thereby duplicating earlier texts as well as some ongoing bookwriting efforts, we decided to narrow down our aim to step growth polymerization systems. This not only provides us the lUxury of a more elaborate presentation within the constraints of production costs, but also enables us to remain on somewhat familiar terrain. The style and format we have selected are those of a textbook. The first six chapters present the principles of step growth polymerization. These are quite general, and can easily be applied in such diverse and emerging fields as polymerization applications in photolithography and microelec tronics. A detailed discussion of several important step growth polymeriz ations follows in the next five chapters. One could cover the first six chapters of this book in about six to eight weeks of a three-credit graduate course on polymerization reactors, with the other chapters assigned for reading. This could be followed by a discussion of chain-growth and other polymeriz ations, with which our material blends well. Alternately, the entire contents of this book could be covered in a course on step growth systems alone.

The art and science of macromolecular architecture is based on synthesis, analysis, processing, and evaluation of physical properties of polymers. The growing specificity of available synthetic methods and the increasing refinement of analytical and physical analysis are gradually providing a deeper insight into structure-property relationships of polymers, upon which many applications can be based. This book deals with recent methods for polymer synthesis. Those that lead to specific structures have been selected especially. Background, mechanism scope and limitations, and illustrative procedures are given for each method. With this layout the editor hopes that the book will provide a practical guideline, for the synthetic polymer chemist in industry or at a university graduate school, on how to apply the methods in the design of new polymer structures. The editor is grateful to the authors not only for their contributions containing interesting new developments in polymer synthesis, but also for the way they have fitted their text into the general framework of the book. The elegant chemistry described in the following chapters will, it is hoped, inspire more organic chemists to apply their skills to polymer synthesis, where the beauty of organic chemistry in terms of structural control and reactivity may be even more apparent than in the low molecular field.

Over the last few years, nanoscience and nanotechnology have been the focus of significant research attention, both from academia and industry. This sustained focus has in-turn driven the interdisciplinary field of material science research to the forefront of scientific inquiry through the creation and study of nanomaterials. Nanomaterials play an important role in the development of new materials as they can be used to influence and control physical properties and specific characteristics of other materials. Nanostructured materials that have been created include nanoparticles, nanocapsules, nanoporous materials, polymer multi-layers to name a few. These are increasingly used across applications as diverse as automotive, environment, energy, catalysis, biomedical, pharmaceutical, and polymer industries. The Encyclopedia of Polymeric Nanomaterials (EPN) intends to be a comprehensive reference work on this dynamic field studying nanomaterials within the context of the relationship between molecular structure and the properties of polymeric materials. Alphabetically organized as an encyclopedic Major Reference Work, EPN will cover the subject along multiple classification axes represented by name, source, properties, function, and structures or even processes, applications and usage. The underlying themes of the encyclopedia has been carefully identified to be based not just on material-based and function-based representation but also on structure- and process-based representation. The encyclopedia will have an exclusive focus on polymeric nanomaterials (for e.g., nanoceramics, nanocomposites, quantum dots, thin films) and will be a first of its kind work to have such an organization providing an overview to the concepts, practices and applications in the field. The encyclopedia intends to cover research and development work ranging from the fundamental mechanisms used for the fabrication of polymeric nanomaterials to their advanced application across multiple industries.