The Determination Of Organic Peroxides

Monographs in Organic Functional Group Analysis, Volume 4: The Determination of Organic Peroxides focuses on the analytical chemistry of organic peroxides. The monograph first offers information on the compositions, properties, and reactions of lipid peroxides, polymers, and petrochemicals. The text then reviews the iodometric methods, including choice of solvents, reaction conditions, and titration with thiosulfate. The ferrous ion methods are also discussed. Considerations include choice of reagents and solvents and titration with titanous, dichromate, and mercurous ions. The book also focuses on titrimetric methods, including arsenious, stannous, and titanous methods, titration with anions, and sulfides and mercaptans. Numerical representations are provided. The text puts emphasis on colorimetric and polarographic methods. Polarographic techniques for peroxides; nature and concentration of peroxides; leuco base of methylene blue; and ferrous ions are described. The book also discusses paper, thin-layer, and gas chromatography. The monograph is an important guide for readers interested in the analytical chemistry of organic peroxides.

The understanding of functional groups is key for the understanding of all organic chemistry. In the tradition of the Patai Series each volume treats all aspects of functional groups. Each volume contains chapters on the theoretical and physicochemical foundations; on analytical aspects; on reaction mechanisms; on applications in synthesis. Depending on the functional group there are additional chapters on industrial use, on medical use, and on human and environmental toxicity issues. The last volume in the series on the topic (Peroxides Vol. 2) was published in 2006. In the eight years since then a lot of developments have taken place, especially in the areas of synthesis, analysis and a better theoretical understanding of the reaction mechanism, all of which are covered here. As with all new volumes, the chapters are first published online in Patai's Chemistry of Functional Groups. Once a volume is completed online, it is then published in print format. The printed book offers the traditional quality of the Patai Book Series, complete with an extensive index.

The Chemistry of Peroxides is a new volume in the Chemistry of Functional Groups series. This series covers all aspects of organic chemistry with each volume containing chapters on: General and theoretical aspects Computational approaches Thermodynamics and kinetics NMR and ESR Mass Spectrometry Spectroscopies Analytical aspects Reaction mechanisms Syntheses Biological effects Environmental effects Industrial applications Edited by Zvi Rappoport, this series provides outstanding reviews on all aspects of functional groups in analytical, physical, synthetic and applied chemistry.

This book is designed as a practical text for use in the laboratories of the plastic producer and user industries and by others such as universities and institutions who are concerned with problems associated with additives and adventitious impurities in polymers. For example, powerful new analytical tools have been made available to the chemist by a combination of various chromatographic techniques with methods of identifying separated additives and their degradation products by techniques based on infrared and mass spectrometry. In particular supercritical fluid chromatography combined with m.