The Photochemistry Of Atmospheres

The Photochemistry of Atmospheres: Earth, the Other Planets, and Comets discusses the photochemical and chemical processes in atmospheres This book focuses on the earth’s atmosphere in the past, present, and future, atmospheres of other planets and their satellites, and comets. General topics in atmospheric photochemistry, such as composition and structure, transfer of incoming solar radiation, and principles governing the rates of photochemical and chemical processes are also elaborated. This text also covers the role of eddy and molecular transport and continuity-transport equation used in theoretical numerical modeling studies. This publication is recommended for advanced-level courses in the atmospheric and planetary sciences, as well as reference for those interested in learning about atmospheric/climatic environmental problems, their causes and consequences, and discoveries concerning the atmospheres of neighboring worlds.

The Photochemistry of Atmospheres ...

Spacecraft study of the Solar system is one of humanity's most outstanding achievements. Thanks to this study, our present knowledge of properties of and conditions on the planets exceeds many-fold that of 20 years ago: planets have been rediscovered. This is especially the case for planetary atmospheres, whose properties were for the most part either not at all or only erroneously known. Much research has been invested in the study of the atmospheres of Mars and Venus, and their chemical composition and photochemistry are basic problems in these studies. In the present publication I have tried to summarize all findings in this field. The English version of the book includes new data in the field from the last 3 years since the book was published in Russian. I wish to thank U. von Zahn, who initiated my talks with Springer-Verlag and acted as technical editor. December 2, 1985 V. A. KRASNOPOLSKY Contents Introduction . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 1 Chemical Composition and Structure of the Martian Atmosphere 4 1. 1 Carbon Dioxide and Atmospheric Pressure . . . . . . . . . . . . . . . . . . . 4 1. 2 CO and O Mixing Ratios . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 8 2 1. 3 Ozone. . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10 1. 4 Water Vapor . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18 1. 5 Composition of the Upper Atmosphere as Determined from Airglow Spectroscopy . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23 1. 6 Mass Spectrometric Measurements of the Atmospheric Composition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31 1. 7 Ionospheric Composition . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34 1. 8 Temperature Profile of the Lower Atmosphere. . . . . . . . . . . . . . . . 36 1. 9 Temperature of the Upper Atmosphere . . . . . . . . . . . . . . . . . . . . . . 40 1. 10 Eddy Diffusion Coefficient . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 42 2 Photochemistry of the Martian Atmosphere . . . . . . . . . . . . . . . . . .

This valuable reference presents detailed studies of eleven planetary atmospheres: four for the giant planets (Jupiter, Saturn, Uranus, and Neptune), four for the small bodies (Io, Titan, Triton, and Pluto), and three for the terrestrial planets (Mars, Venus, and Earth). Also, using the database provided by recent space missions supplemented by Earth-based observations, the authors offer an extensive survey of the principal chemical cycles that control the present composition and past history of planetary atmospheres.

This volume reviews all aspects of Mars atmospheric science from the surface to space, and from now and into the past.

Reviews the fundamentals for studying chemical compositions of planetary atmospheres and ionospheres, for graduate students and researchers.

Here is the most comprehensive and up-to-date treatment of one of the hottest areas of chemical research. The treatment of fundamental kinetics and photochemistry will be highly useful to chemistry students and their instructors at the graduate level, as well as postdoctoral fellows entering this new, exciting, and well-funded field with a Ph.D. in a related discipline (e.g., analytical, organic, or physical chemistry, chemical physics, etc.). Chemistry of the Upper and Lower Atmosphere provides postgraduate researchers and teachers with a uniquely detailed, comprehensive, and authoritative resource. The text bridges the "gap" between the fundamental chemistry of the earth's atmosphere and "real world" examples of its application to the development of sound scientific risk assessments and associated risk management control strategies for both tropospheric and stratospheric pollutants. Serves as a graduate textbook and "must have" reference for all atmospheric scientists Provides more than 5000 references to the literature through the end of 1998 Presents tables of new actinic flux data for the troposphere and stratospher (0-40km) Summarizes kinetic and photochemical date for the troposphere and stratosphere Features problems at the end of most chapters to enhance the book's use in teaching Includes applications of the OZIPR box model with comprehensive chemistry for student use

Photochemistry of Air Pollution provides information pertinent to air pollution and atmospheric chemistry. This book discusses the photochemical reactions produced by sunlight may convert relatively harmless pollutants into substances that constitute a nuisance, create possible health hazard, and cause economic problem to humans. Organized into 10 chapters, this book starts with an overview of the problem of air pollution, particularly photochemical smog. This text then discusses the factors that collectively determine the amount and spectral distribution of the radiation entering a surface layer of the atmosphere. Other chapters compare the specific absorption rates of several absorbers that are present in the air during periods of photochemical smog, including oxygen, ozone, nitrogen dioxide, sulfur dioxide, ketones, peroxides, and particulate matter. The final chapter deals with the process of formation of the substances responsible for the physiological effects of eye irritation and plant damage. This book is a valuable resource for photochemists and air pollution scientists.