The Tragicomical History Of Thermodynamics 1822 1854

Modern thermodynamics is a unique but still not a logically self-consistent field of knowledge. It has a proven universal applicability and significance but its actual potential is still latent. The development of the foundations of thermodynamics was in effect non-stop but absolutely no one has any idea about this. This book is the first of its kind that will motivate researchers to build up a logically consistent field of thermodynamics. It greatly appreciates the actual depth and potential of thermodynamics which might also be of interest to readers in history and philosophy of scientific research. The book presents the life stories of the protagonists in detail and allows readers to cast a look at the whole scene of the field by showcasing a significant number of their colleagues whose works have fittingly complemented their achievements. It also tries to trigger a detailed analysis of the reasons why the actual work in this extremely important field has in effect gone astray. It comprises five chapters and introduces three scientists in the first two chapters, which are specifically devoted to the Scandinavian achievements in macroscopic thermodynamics. These introductions are novel and call for a detailed reconsideration of the field. The third chapter acquaints the readers with their fourth colleague in Germany who was working on the proper link between the macroscopic thermodynamics, kinetics, and the atomistic representation of matter. The fourth chapter brings in their fifth colleague in the United States who could formally infer the famous formula S = k * ln(W), ingeniously guessed by Ludwig Boltzmann, and thus clarify the physical sense of the entropy notion. The last chapter summarizes the above-mentioned discourses.

This book deals with different modern topics in probability, statistics and operations research. It has been written lucidly in a novel way. Wherever necessary, the theory is explained in great detail, with suitable illustrations. Numerous references are given, so that young researchers who want to start their work in a particular area will benefit immensely from the book.The contributors are distinguished statisticians and operations research experts from all over the world.

Mon but n'a jamais be de m'occuper des ces matieres comme physicien, mais seulement comme /ogicien ... F. REECH, 1856 I do not think it possible to write the history of a science until that science itself shall have been understood, thanks to a clear, explicit, and decent logical structure. The exuberance of dim, involute, and undisciplined his torical essays upon classical thermodynamics reflects the confusion of the theory itself. Thermodynamics, despite its long history, has never had the benefit of a magisterial synthesis like that which EULER gave to hydro dynamics in 1757 or that which MAXWELL gave to electromagnetism in 1873; the expositions in the works of discovery in thermodynamics stand a pole apart from the pellucid directness of the notes in which CAUCHY presented his creation and development of the theory of elasticity from 1822 to 1845. Thermodynamics was born in obscurity and disorder, not to say confusion, and there the common presentations of it have remained. With this tractate I aim to provide a simple logical structure for the classical thermodynamics of homogeneous fluid bodies. Like any logical structure, it is only one of many possible ones. I think it is as simple and pretty as can be.

An account of the concepts and intellectual structure of classical thermodynamics that reveals the subject's simplicity and coherence. Students of physics, chemistry, and engineering are taught classical thermodynamics through its methods—a “problems first” approach that neglects the subject's concepts and intellectual structure. In Thermodynamic Weirdness, Don Lemons fills this gap, offering a nonmathematical account of the ideas of classical thermodynamics in all its non-Newtonian “weirdness.” By emphasizing the ideas and their relationship to one another, Lemons reveals the simplicity and coherence of classical thermodynamics. Lemons presents concepts in an order that is both chronological and logical, mapping the rise and fall of ideas in such a way that the ideas that were abandoned illuminate the ideas that took their place. Selections from primary sources, including writings by Daniel Fahrenheit, Antoine Lavoisier, James Joule, and others, appear at the end of most chapters. Lemons covers the invention of temperature; heat as a form of motion or as a material fluid; Carnot's analysis of heat engines; William Thomson (later Lord Kelvin) and his two definitions of absolute temperature; and energy as the mechanical equivalent of heat. He explains early versions of the first and second laws of thermodynamics; entropy and the law of entropy non-decrease; the differing views of Lord Kelvin and Rudolf Clausius on the fate of the universe; the zeroth and third laws of thermodynamics; and Einstein's assessment of classical thermodynamics as “the only physical theory of universal content which I am convinced will never be overthrown.”

The material included in this book was first presented in a series of lectures de livered at the University of Minnesota in June 1983 in connection with the con ference "Thermodynamics and Phase Transitions". This conference was one of the principal events in the first year of operation of the Institute for Mathematics and its Applications (lMA) at the University of Minnesota. The Institute was founded under the auspices of the National Science Foun dation of the United States and the University of Minnesota and is devoted to strengthening and fostering the relation of mathematics with its various applica tions to problems of the real world. The present volume constitutes an important element in the continuing pub lication program of the Ipstitute. Previous publications in this program have ap peared as lecture notes in the well-known Springer series, and future ones will be part of a new series "IMA Volumes in Applied Mathematics". Preface Until recently it was believed that thermodynamics could be given a rigorous foundation only in certain restricted circumstances, particularly those involving reversible and quasi-static processes. More general situations, commonly arising in continuum theories, have therefore been treated on the assumption that inter nal energy, entropy and absolute temperature are a priori given quantities, or have been dealt with on a more or less ad hoc basis, with emphasis for example on various types of variational formulations and maximization rules.

In the first edition of this book I tried to survey in brief compass the main ideas, methods, and discoveries of rational thermodynamics as it then stood, only five years after Messrs. COLEMAN & NOLL, while in Baltimore, had written the fundamental memoir that provided for the new science the one root theretofore wanting. A survey in the same style today would require an almost wholly new book, three or four times as long. As it was in 1968, again in 1983 a consecutive treatise restricted to the foundations would be premature, for at this moment they are under earnest discussion, probing analysis, and powerful attack by several students and from several directions. Because, although in the first edition I expressed some opinions I no longer hold and made some statements I should now recast or even re tract, it seems even yet to offer a simple introduction to some aspects of the field that remain current, I have chosen to reprint it unaltered except for emendation of slips and bettering of the English here and there.