Tritium And Radiocarbon

Compounds labeled with carbon-14 and tritium are indispensable tools for research in biomedical sciences, discovery and development of pharmaceuticals and agrochemicals. Preparation of Compounds Labeled with Tritium and Carbon-14 is a comprehensive, authoritative and up-to-date discussion of the strategies, synthetic approaches, reactions techniques, and resources for the preparation of compounds labeled with either of these isotopes. A large number of examples are presented for the use of isotopic sources and building blocks in the preparation of labeled target compounds, illustrating the range of possibilities for embedding isotopic labels in selected moieties of complex structures. Topics include: Formulation of synthetic strategies for preparing labeled compounds Isotope exchange methods and synthetic alternatives for preparing tritiated compounds In-depth discussion of carbon-14 building blocks and their utility in synthesis Preparation of enantiomerically pure isotopically labeled compounds Applications of biotransformations Preparation of Compounds Labeled with Tritium and Carbon-14 is an essential guide to the specialist strategies and tactics used by chemists to prepare compounds tagged with theradioactive atoms carbon-14 and tritium.

Tritium and radiocarbon are pure beta emitters. Tritium has an average energy of 5.7 keV and endpoint energy of 18.6 keV [1]. Radiocarbon has an average energy of 49.5 keV and endpoint energy of 156 keV. The half-life of tritium and radiocarbon is 12.3 years and 5730 years, respectively. Hydrogen has three isotopes, namely hydrogen (1H), deuterium (2H), and tritium (3H). Among the three isotopes, tritium alone is a radioactive isotope. The natural abundance of hydrogen, deuterium, and tritium are 99.985%, 0.015%, and 1x10-18%. Carbon is also having three isotopes 12C, 13C, and 14C. The isotopes 12C and 13C are stable, whereas 14C is radioactive. The natural abundance of 12C, 13C and 14C are approximately 98.89%%, 1.11% and 1.2 x 10-10% respectively. Tritium is continuously produced in the atmosphere with cosmic-ray induced neutron activation of atmospheric gases. The reaction occurs with fast neutrons. The threshold neutron energy for the 14N (1n, 3H) 12C is 4 MeV [1].

Data Analysis Methods in Physical Oceanography is a practical referenceguide to established and modern data analysis techniques in earth and oceansciences. This second and revised edition is even more comprehensive with numerous updates, and an additional appendix on 'Convolution and Fourier transforms'. Intended for both students and established scientists, the fivemajor chapters of the book cover data acquisition and recording, dataprocessing and presentation, statistical methods and error handling,analysis of spatial data fields, and time series analysis methods. Chapter 5on time series analysis is a book in itself, spanning a wide diversity oftopics from stochastic processes and stationarity, coherence functions,Fourier analysis, tidal harmonic analysis, spectral and cross-spectralanalysis, wavelet and other related methods for processing nonstationarydata series, digital filters, and fractals. The seven appendices includeunit conversions, approximation methods and nondimensional numbers used ingeophysical fluid dynamics, presentations on convolution, statisticalterminology, and distribution functions, and a number of importantstatistical tables. Twenty pages are devoted to references. Featuring:. An in-depth presentation of modern techniques for the analysis of temporal and spatial data sets collected in oceanography, geophysics, and other disciplines in earth and ocean sciences.. A detailed overview of oceanographic instrumentation and sensors - old and new - used to collect oceanographic data.. 7 appendices especially applicable to earth and ocean sciences ranging from conversion of units, through statistical tables, to terminology and non-dimensional parameters. In praise of the first edition: "(...)This is a very practical guide to the various statistical analysis methods used for obtaining information from geophysical data, with particular reference to oceanography(...)The book provides both a text for advanced students of the geophysical sciences and a useful reference volume for researchers." Aslib Book Guide Vol 63, No. 9, 1998 "(...)This is an excellent book that I recommend highly and will definitely use for my own research and teaching." EOS Transactions, D.A. Jay, 1999 "(...)In summary, this book is the most comprehensive and practical source of information on data analysis methods available to the physical oceanographer. The reader gets the benefit of extremely broad coverage and an excellent set of examples drawn from geographical observations." Oceanography, Vol. 12, No. 3, A. Plueddemann, 1999 "(...)Data Analysis Methods in Physical Oceanography is highly recommended for a wide range of readers, from the relative novice to the experienced researcher. It would be appropriate for academic and special libraries." E-Streams, Vol. 2, No. 8, P. Mofjelf, August 1999

The fundamentals of methods in nuclear geophysics and their practical applications in engineering geology, hydrology, hydrogeology, agriculture and environmental science are discussed in this book. The methods and apparatus based on absorption and scattering of gamma and neutron radiation for determination of density and soil moisture in natural conditions are presented in Chapters 2, 3, and 4. The theoretical fundamentals and installations of the penetration logging techniques where gamma, gamma-gamma and neutron logging in combination with static penetration form common complexes for engineering geology and hydrogeology exploration without boring holes are described. The developed constructions and practical use penetration logging installations for applications on land and marine shelves are described in Chapters 5, 6, 7, and 8. The physical fundamentals for the use of the natural stable and radioactive isotopes for study of the global hydrological cycle are provided. The experimental data, origin and distribution of cosmogenic and radiogenic isotopes in the oceans, atmospheric moisture, surface and underground waters are presented in Chapters 9, 10, and 11. The sources and conditions of the radioactive contamination of the natural waters are discussed in Chapters 12 and 13. This book will be of interest to scientists and researchers who use nuclear geophysics methods in engineering geology, hydrology, hydrogeology and hydrogeoecology. Lecturers, students, and postgraduates in these subjects will also find it useful.

Written by chemists for chemists, this is a comprehensive guide to the important radionuclides as well as techniques for their separation and analysis. It introduces readers to the important laboratory techniques and methodologies in the field, providing practical instructions on how to handle nuclear waste and radioactivity in the environment.