Atlas Of Point Contact Spectra Of Electron Phonon Interactions In Metals

The characteristics of electrical contacts have long attracted the attention of researchers since these contacts are used in every electrical and electronic device. Earlier studies generally considered electrical contacts of large dimensions, having regions of current concentration with diameters substantially larger than the characteristic dimensions of the material: the interatomic distance, the mean free path for electrons, the coherence length in the superconducting state, etc. [110]. The development of microelectronics presented to scientists and engineers the task of studying the characteristics of electrical contacts with ultra-small dimensions. Characteristics of point contacts such as mechanical stability under continuous current loads, the magnitudes of electrical fluctuations, inherent sensitivity in radio devices and nonlinear characteristics in connection with electromagnetic radiation can not be understood and altered in the required way without knowledge of the physical processes occurring in contacts. Until recently it was thought that the electrical conductivity of contacts with direct conductance (without tunneling or semiconducting barriers) obeyed Ohm's law. Nonlinearities of the current-voltage characteristics were explained by joule heating of the metal in the region of the contact. However, studies of the current-voltage characteristics of metallic point contacts at low (liquid helium) temperatures [142] showed that heating effects were negligible in many cases and the nonlinear characteristics under these conditions were observed to take the form of the energy dependent probability of inelastic electron scattering, induced by various mechanisms.

Various experimental techniques for point contact production are described. Examples of point-contact spectra are presented for pure metals, alloys and compounds, as well as for semimetals and semiconductors, heavy fermion systems, Kond-lattices, mixed valence compounds and more. Superconducting point contacts are considered in respect to Andreev reflection and Josephson effects. Special attention is paid to contact conductance fluctuation, and new trends of research are outlined.

Over the last decade, techniques for materials preparation and processing at nanometer scale have advanced rapidly, leading to the introduction of novel principles for a new generation of sensors and detectors. At the same time, the chemical industry, transport and agriculture produce huge amounts of dangerous waste gases and liquids, leading to soil, air and water contamination. One more modern threat - international terrorism - demands that scientists make efforts to apply new principles and technologies to protect society against chemical, biological, radiological and nuclear (CBRN) attacks and to develop novel effective technologies for the remediation of large contaminated areas. Accordingly, the main goal of this book is to bring together experts (theorists, experimentalists, engineers and technologists) for an extensive discussion covering: novel principles for functional nanostructures and detector fabrication and implementation, the development of novel technologies for the deactivation of CBRN agents, their experimental realization and their application in novel monitoring and control systems, and technological processes for soil and water remediation, with a view to environmental protection and defence against CBRN-based terrorism. In keeping with the book’s main goal, the following topics are highlighted and discussed: - Sensors and detectors - detection of chemicals, principles of “artificial nose” and chemical “micro-lab on a chip” design, surface and underground water quality monitoring systems, molecular electronics, superconducting electronic devices, quantum detectors and Qubits. - Environmental protection and CBRN - detection of infrared, microwave, X-ray and terahertz radiation. Principles for novel IR-, UV-, and Terahertz-wave devices for the detection of low-contrast objects. - Novel technological processes for CBRN destruction and deactivation. All these topics are strongly interrelated, both with regard to fundamental aspects and to fabrication and implementation technologies; in addition, they are highly promising for application in novel functional devices, computer logics, sensing and detection of low-concentration chemicals, weak and extremely weak magnetic and microwave fields, infrared and ultraviolet radiation. Given its scope, the book will be a useful and interesting guide for a broad readership of engineers, scientists, PhD students and experts in the area of defence against environmental terrorism.

The great breakthroughs in the science and technology of superconducting and magnetic materials in recent years promoted many outstanding representatives of various scientific disciplines (physics, chemistry and materials science) to present their latest findings in a scientific atmosphere of the highest standard at the MSM-99 conference. Over 200 eminent scientists from 50 countries gathered to discuss the physics, materials science and application of magnetic and superconducting materials, and to foster research and development collaborations between the scientists and technologists of the regional countries and also with the international scientific community. The main topics of this book are the physics, materials science and application of magnetic and superconducting materials having a close relationship between the strong correlated electron system and magnetism.

The great breakthroughs in the science and technology of superconducting and magnetic materials in recent years promoted many outstanding representatives of various scientific disciplines (physics, chemistry and materials science) to present their latest findings in a scientific atmosphere of the highest standard at the MSM-99 conference. Over 200 eminent scientists from 50 countries gathered to discuss the physics, materials science and application of magnetic and superconducting materials, and to foster research and development collaborations between the scientists and technologists of the regional countries and also with the international scientific community.The main topics of this book are the physics, materials science and application of magnetic and superconducting materials having a close relationship between the strong correlated electron system and magnetism.

This volume contains most of the contributions presented at the NATO Advanced Research Workshop on Rare Earth Transition Metal Borocarbides (Nitrides): Superconducting, Magnetic and Normal State Properties, held in Dresden, Germany at 13 - 18 June 2000. The Workshop was chaired by K. -H. MUller and V. N. Narozhnyi. This was the first meeting specially focused on the quaternary rare-earth transition-metal borocarbides and nitrides - a new class of magnetic superconductors discovered in 1994. The motivation for organizing this workshop was to bring together scientists (both experimentalists and theoreticians), actively working in this field in different countries, using different methods, to exchange their points of view on the properties ofthese materials and to recognize the directions for future research. Totally 48 participants from 17 countries ofEurope, the United States, BraZil, India, Israel and Japan took part in this meeting. In addition about 15 observers (mainly from Germany) attended. The scientific Programme of the Workshop was composed of 7 sections. The section Introduction and Overview was followed by the Electronic Structure and Properties and Phonon Spectra; Magnetic Properties and CEF Effects; Interplay between Superconductivity and Magnetism; Vortex Lattice; Thin Films; Nature of the Superconducting State in Borocarbides sections. Totally 50 presentations were given (45 ofthem in oral form). Considerable attention was devoted to the characterization of the particular place of borocarbides amongst the other magnetic and superconducting systems and, especially, magnetic superconductors.

Ongoing developments in nanofabrication technology and the availability of novel materials have led to the emergence and evolution of new topics for mesoscopic research, including scanning-tunnelling microscopic studies of few-atom metallic clusters, discrete energy level spectroscopy, the prediction of Kondo-type physics in the transport properties of quantum dots, time dependent effects, and the properties of interacting systems, e.g. of Luttinger liquids. The overall understanding of each of these areas is still incomplete; nevertheless, with the foundations laid by studies in the more traditional systems there is no doubt that these new areas will advance mesoscopic electron transport to a new phenomenological level, both experimentally and theoretically. Mesoscopic Electron Transport highlights selected areas in the field, provides a comprehensive review of such systems, and also serves as an introduction to the new and developing areas of mesoscopic electron transport.

1. The birth of molecular electronics. 1.1. Why molecular electronics?. 1.2. A brief history of molecular electronics. 1.3. Scope and structure of the book -- 2. Fabrication of metallic atomic-size contacts. 2.1. Introduction. 2.2. Techniques involving the scanning electron microscope (STM). 2.3. Methods using atomic force microscopes (AFM). 2.4. Contacts between macroscopic wires. 2.5. Transmission electron microscope. 2.6. Mechanically controllable break-junctions (MCBJ). 2.7. Electromigration technique. 2.8. Electrochemical methods. 2.9. Recent developments. 2.10. Electronic transport measurements. 2.11. Exercises -- 3. Contacting single molecules: Experimental techniques. 3.1. Introduction. 3.2. Molecules for molecular electronics. 3.3. Deposition of molecules. 3.4. Contacting single molecules. 3.5. Contacting molecular ensembles. 3.6. Exercises -- 4. The scattering approach to phase-coherent transport in nanocontacts. 4.1. Introduction. 4.2. From mesoscopic conductors to atomic-scale junctions. 4.3. Conductance is transmission : heuristic derivation of the Landauer formula. 4.4. Penetration of a potential barrier : tunnel effect. 4.5. The scattering matrix. 4.6. Multichannel Landauer formula. 4.7. Shot noise. 4.8. Thermal transport and thermoelectric phenomena. 4.9. Limitations of the scattering approach. 4.10. Exercises -- 5. Introduction to Green's function techniques for systems in equilibrium. 5.1. The Schrodinger and Heisenberg pictures. 5.2. Green's functions of a noninteracting electron system. 5.3. Application to tight-binding Hamiltonians. 5.4. Green's functions in time domain. 5.5. Exercises -- 6. Green's functions and Feynman diagrams. 6.1. The interaction picture. 6.2. The time-evolution operator. 6.3. Perturbative expansion of causal Green's functions. 6.4. Wick's theorem. 6.5. Feynman diagrams. 6.6. Feynman diagrams in energy space. 6.7. Electronic self-energy and Dyson's equation. 6.8. Self-consistent diagrammatic theory : the Hartree-Fock approximation. 6.9. The Anderson model and the Kondo effect. 6.10. Final remarks. 6.11. Exercises -- 7. Nonequilibrium Green's functions formalism. 7.1. The Keldysh formalism. 7.2. Diagrammatic expansion in the Keldysh formalism. 7.3. Basic relations and equations in the Keldysh formalism. 7.4. Application of Keldysh formalism to simple transport problems. 7.5. Exercises -- 8. Formulas of the electrical current : exploiting the Keldysh formalism. 8.1. Elastic current : microscopic derivation of the Landauer formula. 8.2. Current through an interacting atomic-scale junction. 8.3. Time-dependent transport in nanoscale junctions. 8.4. Exercises -- 9. Electronic structure I: Tight-binding approach. 9.1. Basics of the tight-binding approach. 9.2. The extended Huckel method. 9.3. Matrix elements in solid state approaches. 9.4. Slater-Koster two-center approximation. 9.5. Some illustrative examples. 9.6. The NRL tight-binding method. 9.7. The tight-binding approach in molecular electronics. 9.8. Exercises -- 10. Electronic structure II : density functional theory. 10.1. Elementary quantum mechanics. 10.2. Early density functional theories. 10.3. The Hohenberg-Kohn theorems. 10.4. The Kohn-Sham approach. 10.5. The exchange-correlation functionals. 10.6. The basic machinery of DFT. 10.7. DFT performance. 10.8. DFT in molecular electronics. 10.9. Exercises -- 11. The conductance of a single atom. 11.1. Landauer approach to conductance: brief reminder. 11.2. Conductance of atomic-scale contacts. 11.3. Conductance histograms. 11.4. Determining the conduction channels. 11.5. The chemical nature of the conduction channels of oneatom contacts. 11.6. Some further issues. 11.7. Conductance fluctuations. 11.8. Atomic chains : parity oscillations in the conductance. 11.9. Concluding remarks. 11.10. Exercises -- 12. Spin-dependent transport in ferromagnetic atomic contacts. 12.1. Conductance of ferromagnetic atomic contacts. 12.2. Magnetoresistance of ferromagnetic atomic contacts. 12.3. Anisotropic magnetoresistance in atomic contacts. 12.4. Concluding remarks and open problems -- 13. Coherent transport through molecular junctions I : basic concepts. 13.1. Identifying the transport mechanism in single-molecule junctions. 13.2. Some lessons from the resonant tunneling model. 13.3. A two-level model. 13.4. Length dependence of the conductance. 13.5. Role of conjugation in [symbol]-electron systems. 13.6. Fano resonances. 13.7. Negative differential resistance. 13.8. Final remarks. 13.9. Exercises -- 14. Coherent transport through molecular junctions II : test-bed molecules. 14.1. Coherent transport through some test-bed molecules. 14.2. Metal-molecule contact : the role of anchoring groups. 14.3. Tuning chemically the conductance : the role of side-groups. 14.4. Controlled STM-based single-molecule experiments. 14.5. Conclusions and open problems -- 15. Single-molecule transistors : Coulomb blockade and Kondo physics. 15.1. Introduction. 15.2. Charging effects in transport through nanoscale devices. 15.3. Single-molecule three-terminal devices. 15.4. Coulomb blockade theory : constant interaction model. 15.5. Towards a theory of Coulomb blockade in molecular transistors. 15.6. Intermediate coupling : cotunneling and Kondo effect. 15.7. Single-molecule transistors : experimental results. 15.8. Exercises -- 16. Vibrationally-induced inelastic current I : experiment. 16.1. Introduction. 16.2. Inelastic electron tunneling spectroscopy (IETS). 16.3. Highly conductive junctions : point-contact spectroscopy (PCS). 16.4. Crossover between PCS and IETS. 16.5. Resonant inelastic electron tunneling spectroscopy (RIETS). 16.6. Summary of vibrational signatures -- 17. Vibrationally-induced inelastic current II : theory. 17.1. Weak electron-phonon coupling regime. 17.2. Intermediate electron-phonon coupling regime. 17.3. Strong electron-phonon coupling regime. 17.4. Concluding remarks and open problems. 17.5. Exercises -- 18. The hopping regime and transport through DNA molecules. 18.1. Signatures of the hopping regime. 18.2. Hopping transport in molecular junctions : experimental examples. 18.3. DNA-based molecular junctions. 18.4. Exercises -- 19. Beyond electrical conductance : shot noise and thermal transport. 19.1. Shot noise in atomic and molecular junctions. 19.2. Heating and heat conduction. 19.3. Thermoelectricity in molecular junctions -- 20. Optical properties of current-carrying molecular junctions. 20.1. Surface-enhanced Raman spectroscopy of molecular junctions. 20.2. Transport mechanisms in irradiated molecular junctions. 20.3. Theory of photon-assisted tunneling. 20.4. Experiments on radiation-induced transport in atomic and molecular junctions. 20.5. Resonant current amplification and other transport phenomena in ac driven molecular junctions. 20.6. Fluorescence from current-carrying molecular junctions. 20.7. Molecular optoelectronic devices. 20.8. Final remarks. 20.9. Exercises -- 21. What is missing in this book?