Black Liquor Gasification

Black Liquor Gasification (BLG) is a first of its kind to guide chemical engineers, students, operators of paper plants, technocrats, and entrepreneurs on practical guidelines and a holistic techno-enviro-economic perspective applicable to their future or existing projects based on the treatment of black liquor for energy production. BLG describes the gasification process as a more efficient alternative to current processes for the conversion of black liquor biomass into energy. BLG operates largely in sync with other methods to improve pulp-making efficiency. This book explains how BLG offers a way to generate electricity and to reclaim pulping chemicals from black liquor, and why BLG would replace the Tomlinson recovery boiler for the recovery of spent chemicals and energy. Describes the utilization of black liquor as a source of energy Provides a detailed account of black liquor gasification processes for the production of energy and chemicals from black liquor Provides guidelines to chemical engineers for the treatment of black liquor

Pulp and Paper Industry: Chemical Recovery examines the scientific and technical advances that have been made in chemical recovery, including the very latest developments. It looks at general aspects of the chemical recovery process and its significance, black liquor evaporation, black liquor combustion, white liquor preparation, and lime reburning. The book also describes the technologies for chemical recovery of nonwood black liquor, as well as direct alkali regeneration systems in small pulp mills. In addition, it includes a discussion of alternative chemical recovery processes, i.e. alternative causticization and gasification processes, and the progress being made in the recovery of filler, coating color, and pigments. Furthermore, it discusses the utilization of new value streams (fuels and chemicals) from residuals and spent pulping liquor, including related environmental challenges. Offers thorough and in-depth coverage of scientific and technical advances in chemical recovery in pulp making Discusses alternative chemical recovery processes, i.e., alternative causticization and gasification processes Covers the progress being made in the recovery of filler, coating color, and pigments Examines utilization of new value streams (fuels and chemicals) from residuals and spent pulping liquor Discusses environmental challenges (air emissions, mill closure) Presents ways in which the economics, energy efficiency, and environmental protection associated with the recovery process can be improved

Gasification is a process that if properly utilized can transform the world in which we live. Comprehensive in its coverage, this second edition continues the tradition of the first by providing engineers and scientists with an up-to-date overview of commercial processes and applications relevant to today's demands. Gasification, 2nd edition is expanded and provides more detail on the integration issues for current generation, state-of-the-art Integrated Gasification Combined Cycles (IGCC); CO2 capture in the IGCC context addressing the issues of pre-investment and retrofitting as well as defining what the term "CO2 capture ready" might mean in practice; issues of plant reliability, availability and maintainability (RAM) including as evaluation of feedback from existing plants; implementation of fuel cell technology in IGCC concepts. All statistics, processes and projects, including descriptions of a number of processes not covered in the previous edition. *Up-to-date overview of commercial processes *Covers applications relevant to today's demands *Addresses the issues of pre-investment and retrofitting *Provides more detail on the integration issues for Integrated Gasification

The world is currently consuming about 85 million barrels of oil a day, and about two-thirds as much natural gas equivalent, both derived from non-renewable natural sources. In the foreseeable future, our energy needs will come from any available alternate source. Methanol is one such viable alternative, and also offers a convenient solution for efficient energy storage on a large scale. In this updated and enlarged edition, renowned chemists discuss in a clear and readily accessible manner the pros and cons of humankind's current main energy sources, while providing new ways to overcome obstacles. Following an introduction, the authors look at the interrelationship of fuels and energy, and at the extent of our non-renewable fossil fuels. They also discuss the hydrogen economy and its significant shortcomings. The main focus is on the conversion of CO2 from industrial as well as natural sources into liquid methanol and related DME, a diesel fuel substitute that can replace LNG and LPG. The book is rounded off with an optimistic look at future possibilities. A forward-looking and inspiring work that vividly illustrates potential solutions to our energy and environmental problems.

Officially, the use of biomass for energy meets only 10-13% of the total global energy demand of 140 000 TWh per year. Still, thirty years ago the official figure was zero, as only traded biomass was included. While the actual production of biomass is in the range of 270 000 TWh per year, most of this is not used for energy purposes, and mostly it

This book documents the recent accomplishments of integrated forest biorefineries and their future in the pulp, paper, and fiber-processing industries.

Gasification of black liquor is an alternative to the combustion of black liquor, which is currently the dominant form of chemical recovery in the paper industry. Gasification of black liquor offers the possibility of higher thermal efficiencies than combustion, reducing manufacturing costs and creating new revenue streams through a forest biorefinery. Pressurizing the gasification reactor further enhances the efficiency advantage of gasification over combustion. This study uses a pressurized entrained flow reactor (PEFR) to study black liquor gasification behavior under pressures, temperatures, and heating rates similar to those of next-generation high-temperature black liquor gasifiers. The effects of pressure on black liquor char morphology, gasification rates, pyrolysis carbon yields, and sulfur phase distribution were studied. These characteristics were investigated in three main groups of experiments at 900oC: pyrolysis (100% N2), gasification with constant partial pressure (0.25 bar H2O and 0.50 bar CO2), and gasification with constant mole fraction (10% CO2, 2% H2O, 1.7% CO, 0.3% H2), under five, ten, and fifteen bar total pressure. It was found that pressure had an impact on the char physical characteristics immediately after the char entered the reactor. Increasing pressure had the effect of decreasing the porosity of the chars. Pressure also affected particle destruction and reagglomeration mechanisms. Surface areas of gasification chars decreased with increasing pressures, but only at low carbon conversions. The rate of carbon conversion in gasification was shown to be a function of the gas composition near the particle, with higher levels of inhibiting gases slowing carbon conversion. The same phenomenon of product gas inhibition observed in gasification was used to explain carbon conversions in pyrolysis reactions. Sulfur distribution between condensed and gas phases was unaffected by increasing total pressure in the residence times investigated. Significant amounts of sulfur are lost during initial devolatilization. With water present this gas phase sulfur forms H2S and did not return to the condensed phase.

In legislation appropriating funds for DOE's fiscal year (FY) 2000 energy R&D budget, the House Interior Appropriations Subcommittee directed an evaluation of the benefits that have accrued to the nation from the R&D conducted since 1978 in DOE's energy efficiency and fossil energy programs. In response to the congressional charge, the National Research Council formed the Committee on Benefits of DOE R&D on Energy Efficiency and Fossil Energy. From its inception, DOE's energy R&D program has been the subject of many outside evaluations. The present evaluation asks whether the benefits of the program have justified the considerable expenditure of public funds since DOE's formation in 1977, and, unlike earlier evaluations, it takes a comprehensive look at the actual outcomes of DOE's research over two decades.