Carbonate Geochemistry

Selected papers and abstracts of the symposium held August 6 through 9, 2011, Billings, Montana

This book covers the more basic aspects of carbonate minerals and their interaction with aqueous solutions; modern marine carbonate formation and sediments; carbonate diagenesis (early marine, meteoric and burial); the global cycle of carbon and human intervention; and the role of sedimentary carbonates as indicators of stability and changes in the Earth's surface environment. The selected subjects are presented with sufficient background information to enable the non-specialist to understand the basic chemistry involved. Tested on classes taught by the authors, and approved by the students, this comprehensive volume will prove itself to be a valuable reference source to students, researchers and professionals in the fields of oceanography, geochemistry, petrology, environmental science and petroleum geology.

Carbonate rocks have diverse characteristics. They can be excellent reservoirs as well as prolific source rocks for oil. Oils from carbonate rocks commonly have distinctive bulk chemical and molecular characteristics that reveal their origin. The papers collected here are descriptions and interpretations (that is, case histories) of specific carbonate source rocks that range in age from Precambrian to Miocene.

Volume 11 of Reviews in Mineralogy attempts to synthesize our present understanding of certain aspects of the mineralogy and chemistry of the rock-forming carbonates. This review follows, by ten years, a major assessment of (sedimentary) carbonate minerals by Lippmann (1973). There is only minor overlap of subject material, and I hope that this difference reflects fairly how this field has developed. In this volume, some of the papers are general (i.e., those addressing crystal chemistry and phase relations), and they provide overviews of a fundamental nature and are of interest to many. Others are more specialized in coverage and generally reflect the different approaches used in carbonate geochemistry. The final chapter introduces transmission electron microscopy, a relatively new and powerful technique for mineralogical research that has great potential in carbonate research.

This book provides an up-to-date compilation of the latest research on the petrography, facies, paleonvironmental significance and economic aspects of continental carbonates. The overall organization of the book first emphasizes the descriptive aspects and processes operating on carbonate deposits in greatly varied settings, and then considers applications for basin analysis, as well as economic and historical aspects. This volume will be a valuable tool for graduate and postgraduate students as well as for experienced researchers. The first part (volume 61 in this series) will deal with the facies, environments, and processes of carbonates in continental settings. Covering the greatly varied aspects of carbonate deposits from continental settings deposits Clear and easy to follow organization of the book Graduate to postgraduate level Up to date information, so readers can find references from the classic literature to the most recent research

Environmental and Low-Temperature Geochemistry presents conceptual and quantitative principles of geochemistry in order to foster understanding of natural processes at and near the earth’s surface, as well as anthropogenic impacts and remediation strategies. It provides the reader with principles that allow prediction of concentration, speciation, mobility and reactivity of elements and compounds in soils, waters, sediments and air, drawing attention to both thermodynamic and kinetic controls. The scope includes atmosphere, terrestrial waters, marine waters, soils, sediments and rocks in the shallow crust; the temporal scale is present to Precambrian, and the spatial scale is nanometers to local, regional and global. This second edition of Environmental and Low-Temperature Geochemistry provides the most up-to-date status of the carbon cycle and global warming, including carbon sources, sinks, fluxes and consequences, as well as emerging evidence for (and effects of) ocean acidification. Understanding environmental problems like this requires knowledge based in fundamental principles of equilibrium, kinetics, basic laws of chemistry and physics, empirical evidence, examples from the geological record, and identification of system fluxes and reservoirs that allow us to conceptualize and understand. This edition aims to do that with clear explanations of fundamental principles of geochemistry as well as information and approaches that provide the student or researcher with knowledge to address pressing questions in environmental and geological sciences. New content in this edition includes: Focus Boxes – one every two or three pages – providing case study examples (e.g. methyl isocyanate in Bhopal, origins and health effects of asbestiform minerals), concise explanations of fundamental concepts (e.g. balancing chemical equations, isotopic fractionation, using the Keq to predict reactivity), and useful information (e.g. units of concentration, titrating to determine alkalinity, measuring redox potential of natural waters); Sections on emerging contaminants for which knowledge is rapidly increasing (e.g. perfluorinated compounds, pharmaceuticals and other domestic and industrial chemicals); Greater attention to interrelationships of inorganic, organic and biotic phases and processes; Descriptions, theoretical frameworks and examples of emerging methodologies in geochemistry research, e.g. clumped C-O isotopes to assess seawater temperature over geological time, metal stable isotopes to assess source and transport processes, X-ray absorption spectroscopy to study oxidation state and valence configuration of atoms and molecules; Additional end-of-chapter problems, including more quantitatively based questions. Two detailed case studies that examine fate and transport of organic contaminants (VOCs, PFCs), with data and interpretations presented separately. These examples consider the chemical and mineralogical composition of rocks, soils and waters in the affected system; microbial influence on the decomposition of organic compounds; the effect of reduction-oxidation on transport of Fe, As and Mn; stable isotopes and synthetic compounds as tracers of flow; geological factors that influence flow; and implications for remediation. The interdisciplinary approach and range of topics – including environmental contamination of air, water and soil as well as the processes that affect both natural and anthropogenic systems – make it well-suited for environmental geochemistry courses at universities as well as liberal arts colleges.

This book provides an up-to-date compilation of the latest research on the petrography, facies, paleonvironmental significance and economic aspects of continental carbonates. The overall organization of the book first emphasizes the descriptive aspects and processes operating on carbonate deposits in greatly varied settings, and then considers applications for basin analysis, as well as economic and historical aspects. This volume will be a valuable tool for graduate and postgraduate students as well as for experienced researchers. The second part (volume 62 in this series) will deal with the geochemistry, diagenesis and applications of carbonates in continental settings. Covering the greatly varied aspects of carbonate deposits from continental settings deposits Clear and easy to follow organization Up to date information, so readers can find references from the classic literature to the most recent research