Chalcogenide Glasses

The unique properties and functionalities of chalcogenide glasses make them promising materials for photonic applications. Chalcogenide glasses are transparent from the visible to the near infrared region and can be moulded into lenses or drawn into fibres. They have useful commercial applications as components for lenses for infrared cameras, and chalcogenide glass fibres and optical components are used in waveguides for use with lasers, for optical switching, chemical and temperature sensing and phase change memories. Chalcogenide glasses comprehensively reviews the latest technological advances in this field and the industrial applications of the technology. Part one outlines the preparation methods and properties of chalcogenide glasses, including the thermal properties, structure, and optical properties, before going on to discuss mean coordination and topological constraints in chalcogenide network glasses, and the photo-induced phenomena in chalcogenide glasses. This section also covers the ionic conductivity and physical aging of chalcogenide glasses, deposition techniques for chalcogenide thin films, and transparent chalcogenide glass-ceramics. Part two explores the applications of chalcogenide glasses. Topics discussed include rare-earth-doped chalcogenide glass for lasers and amplifiers, the applications of chalcogenide glasses for infrared sensing, microstructured optical fibres for infrared applications, and chalcogenide glass waveguide devices for all-optical signal processing. This section also discusses the control of light on the nanoscale with chalcogenide thin films, chalcogenide glass resists for lithography, and chalcogenide for phase change optical and electrical memories. The book concludes with an overview of chalcogenide glasses as electrolytes for batteries. Chalcogenide glasses comprehensively reviews the latest technological advances and applications of chalcogenide glasses, and is an essential text for academics, materials scientists and electrical engineers working in the photonics and optoelectronics industry. Outlines preparation methods and properties, and explores applications of chalcogenide glasses. Covers the ionic conductivity and physical aging of chalcogenide glasses, deposition techniques for chalcogenide thin films, and transparent chalcogenide glass-ceramics Discusses the control of light on the nanoscale with chalcogenide thin films, chalcogenide glass resists for lithography, and chalcogenide for phase change optical and electrical memories

This book reviews techniques used to characterize non-linear optical constants of chalcogenide glasses in bulk or thin films, and presents the properties of many chalcogenide systems. A range of applications of these glasses are surveyed, including ultra-fast switching, optical limiting, second harmonic generation and electro-optic effects. Also addressed are suitability of chalcogenide films in all-optical integrated circuits, fabrication of rib as well as ridge waveguides and of fiber gratings.

Cutting-edge techniques for yielding high-quality chalcogenide glasses This pioneering work describes the technology, developed over a 50-year period, to utilize chalcogenide glasses as infrared optical materials. Methods for qualitatively identifying chalcogenide glass compositions and producing high-purity homogeneous glass are discussed. Chalcogenide Glasses for Infrared Optics includes unique production techniques developed through the author's work at both Texas Instruments (TI) and Amorphous Materials, Inc. (AMI). The production of vacuum float zoned silicon, gallium arsenide, and cadmium telluride, all useful in infrared technology, is explained. The book highlights examples of how glass composition can be changed to enhance a particular property. Coverage includes: Transmission of light by solids Physical properties of chalcogenide glasses Glass production Careful characterization of glass properties Conventional lens fabrication--spherical surfaces Molding of unconventional aspheric lenses with diffractive surfaces Glass processes for other applications IR imaging bundles made from chalcogenide glass fibers Production of infrared crystalline materials at AMI Development of an automatic ellipsometer system at TI

This is introductory book for researchers, scientists and students in the area of organic and inorganic composite materials. This book has addressed timely the innovative topic "chalcogenide-multiwalled carbon nanotubes and chalcogenide-bilayer graphene" composite materials under a glassy regime. This book will give a clear idea on the concepts of the newly established composite materials area, by providing interpretations of inside physio-chemical mechanism. The remarkable landmark innovations related to this newly introduced research field are included in this book. Additionally, the possible futuristic applications in the area of nanoelectronics, optoelectronics, biomedical etc are also addressed.

The earliest experimental data on an oxygen-free glass have been published by Schulz-Sellack in 1870 [1]. Later on, in 1902, Wood [2], as well as Meier in 1910 [3], carried out the first researches on the optical properties of vitreous selenium. The interest in the glasses that exhibit transparency in the infrared region of the optical spectrum rose at the beginning of the twentieth century. Firstly were investigated the heavy metal oxides and the transparency limit was extended from (the case of the classical oxide glasses) up to wavelength. In order to extend this limit above the scientists tried the chemical compositions based on the elements of the sixth group of the Periodic Table, the chalcogens: sulphur, selenium and tellurium. The systematic research in the field of glasses based on chalcogens, called chalcogenide glasses, started at the middle of our century. In 1950 Frerichs [4] investigated the glass and published the paper: “New optical glasses transparent in infrared up to 12 . Several years later he started the study of the selenium glass and prepared several binary glasses with sulphur [5]. Glaze and co-workers [6] developed in 1957 the first method for the preparation of the glass at the industrial scale, while Winter-Klein [7] published reports on numerous chalcogenides prepared in the vitreous state.

The Workshop on Physics and Application of Non-crystalline Semiconductors in Optoelectronics was held from 15 to 17 October 1996 in Chisinau. republic of Moldova and was devoted to the problems of non-crystalline semiconducting materials. The reports covered two mjlin topics: theoretical basis of physics of non -crystalline materials and experimental results. In the framework of these major topics there were treated many subjects. concerning the physics of non-crystalline semiconductors and their specific application: -optical properties of non-crystalline semiconductors; -doping of glassy semiconductors and photoinduced effects in chalcogenide glasses and their application for practical purposes; -methods for investigation of the structure in non-crystalline semiconductors -new glassy materials for IR trasmittance and optoelectronics. Reports and communications were presented on various aspects of the theory. new physical principles. studies of the atomic structure. search and development of optoelectronics devices. Special attention was paid to the actual subject of photoinduced transformations and its applications. Experimental investigations covered a rather wide spectrum of materials and physical phenomena. As a novel item it is worth to mention the study of nonlinear optical effects in amorphous semiconducting films. The third order optical non linearities. fast photoinduced optical absorption and refraction. acusto-optic effects recently discovered in non-crystalline semiconductors could potentially be utilised for optical signal processing. The important problems of photoinduced structural transformations and related phenomena. which are very attractive and actual both from the scientific and practical points of view. received much attention in discussions at the conference.

This book provides introductory, comprehensive, and concise descriptions of amorphous chalcogenide semiconductors and related materials. It includes comparative portraits of the chalcogenide and related materials including amorphous hydrogenated Si, oxide and halide glasses, and organic polymers. It also describes effects of non-equilibrium disorder, in comparison with those in crystalline semiconductors.

Chalcogenide glass is made up of many elements from the Chalcogenide group. The glass is transparent to infrared light and is useful as a semiconductor in many electronic devices. For example, chalcogenide glass fibers are a component of devices used to perform laser surgery. Semiconducting Chalcogenide Glass III: Applications of Chalcogenide Glasses is a comprehensive overview of designs of various chalcogenide glass devices are presented, including switches, phase inverters, voltage stabilizers, oscillators, indicators and display control circuits, memory devices, and sensors. A special chapter is devoted to chalcogenide glass applications in optical fibers. This collective monograph is intended to survey the current state of chalcogenide glass applications to facilitate further development. The first collective monograph written by Eastern European scientists covering electrical and optical properties of chalcogenide vitreous semiconductors (CVS) Contributions by B.G. Kolomiets, who discovered the properties of chalcogenide glass in 1955! Provides evidence and discussion by authors from opposing positions