Chemical Energy And Exergy

This book is a beginners introduction to chemical thermodynamics for engineers. In the textbook efforts have been made to visualize as clearly as possible the main concepts of thermodynamic quantities such as enthalpy and entropy, thus making them more perceivable. Furthermore, intricate formulae in thermodynamics have been discussed as functionally unified sets of formulae to understand their meaning rather than to mathematically derive them in detail. In this textbook, the affinity of irreversible processes, defined by the second law of thermodynamics, has been treated as the main subject, rather than the equilibrium of chemical reactions. The concept of affinity is applicable in general not only to the processes of chemical reactions but also to all kinds of irreversible processes. This textbook also includes electrochemical thermodynamics in which, instead of the classical phenomenological approach, molecular science provides an advanced understanding of the reactions of charged particles such as ions and electrons at the electrodes. Recently, engineering thermodynamics has introduced a new thermodynamic potential called exergy, which essentially is related to the concept of the affinity of irreversible processes. This textbook discusses the relation between exergy and affinity and explains the exergy balance diagram and exergy vector diagram applicable to exergy analyses in chemical manufacturing processes. This textbook is written in the hope that the readers understand in a broad way the fundamental concepts of energy and exergy from chemical thermodynamics in practical applications. Finishing this book, the readers may easily step forward further into an advanced text of their specified line. - Visualizes the main concepts of thermodynamics to show the meaning of the quantities and formulae. - Focuses mainly on the affinity of irreversible processes and the related concept of exergy. - Provides an advanced understanding of electrochemical thermodynamics.

This book is a beginners introduction to chemical thermodynamics for engineers. In the textbook efforts have been made to visualize as clearly as possible the main concepts of thermodynamic quantities such as enthalpy and entropy, thus making them more perceivable. Furthermore, intricate formulae in thermodynamics have been discussed as functionally unified sets of formulae to understand their meaning rather than to mathematically derive them in detail. In this textbook, the affinity of irreversible processes, defined by the second law of thermodynamics, has been treated as the main subject, rather than the equilibrium of chemical reactions. The concept of affinity is applicable in general not only to the processes of chemical reactions but also to all kinds of irreversible processes. This textbook also includes electrochemical thermodynamics in which, instead of the classical phenomenological approach, molecular science provides an advanced understanding of the reactions of charged particles such as ions and electrons at the electrodes. Recently, engineering thermodynamics has introduced a new thermodynamic potential called exergy, which essentially is related to the concept of the affinity of irreversible processes. This textbook discusses the relation between exergy and affinity and explains the exergy balance diagram and exergy vector diagram applicable to exergy analyses in chemical manufacturing processes. This textbook is written in the hope that the readers understand in a broad way the fundamental concepts of energy and exergy from chemical thermodynamics in practical applications. Finishing this book, the readers may easily step forward further into an advanced text of their specified line. - Visualizes the main concepts of thermodynamics to show the meaning of the quantities and formulae. - Focuses mainly on the affinity of irreversible processes and the related concept of exergy. - Provides an advanced understanding of electrochemical thermodynamics.

In addition to the exergy analysis of thermal processes, e.g. heat engines and commercial power stations, for which the methods described have been long established, the book considers the chemical and metallurgical process industries. Charts and tables are provided for the determination of the exergy of many typical substances. Examples are drawn from the fields of thermal, chemical and metallurgical engineering and the exergetic efficiency of typical processes is calculated. The book also discusses the application of the exergy concept to the problem of the economical optimization of complex plants and the implications to the environment of pollution due to external exergy losses. An Instructor's Manual is available which contains outline solutions to the problems listed at the end of each chapter.

This book deals with exergy and its applications to various energy systems and applications as a potential tool for design, analysis and optimization, and its role in minimizing and/or eliminating environmental impacts and providing sustainable development. In this regard, several key topics ranging from the basics of the thermodynamic concepts to advanced exergy analysis techniques in a wide range of applications are covered as outlined in the contents. Offers comprehensive coverage of exergy and its applications, along with the most up-to-date information in the area with recent developments Connects exergy with three essential areas in terms of energy, environment and sustainable development Provides a number of illustrative examples, practical applications, and case studies Written in an easy-to-follow style, starting from the basics to advanced systems

Details energy and exergy efficiencies of all major aspects of bioenergy systems Covers all major bioenergy processes starting from photosynthesis and cultivation of biomass feedstocks and ending with final bioenergy products, like power, biofuels, and chemicals Each chapter includes historical developments, chemistry, major technologies, applications as well as energy, environmental and economic aspects in order to serve as an introduction to biomass and bioenergy A separate chapter introduces a beginner in easy accessible way to exergy analysis and the similarities and differences between energy and exergy efficiencies are underlined Includes case studies and illustrative examples of 1st, 2nd, and 3rd generation biofuels production, power and heat generation (thermal plants, fuel cells, boilers), and biorefineries Traditional fossil fuels-based technologies are also described in order to compare with the corresponding bioenergy systems

Bridging the gap between concepts derived from Second Law of Thermodynamics and their application to Engineering practice, the property exergy and the exergy balance can be a tool for analyzing and improving the performance of energy conversion processes. With the exergy analysis it is possible to evaluate the performance of energy conversion processes not only on a thermodynamics basis but also by including production costs and environmental aspects and impacts of the studied processes. This comprehensive approach of the use of energy has, as one of the most important feature, the identification of sustainable ways of energy resources utilization. Based on the fundamentals of the exergy concept, its calculation, graphical representations and exergy balances evaluation, Exergy: Production Cost And Renewability describes the application of detailed exergy and thermoeconomic analysis to power plants and polygeneration systems, petroleum production and refining plants (including hydrogen production), chemical plants, biofuel production routes, combined production of ethanol and electricity, aircraft systems design, environmental impact mitigation processes and human body behavior. The presented case studies aim at providing students, researchers and engineers with guidelines to the utilization of the exergy and thermoeconomic analysis to model, simulate and optimize real processes and industrial plants.

Discover a straightforward and holistic look at energy conversion and conservation processes using the exergy concept with this thorough text. Explains the fundamental energy conversion processes in numerous diverse systems, ranging from jet engines and nuclear reactors to human bodies. Provides examples for applications to practical energy conversion processes and systems that use our naturally occurring energy resources, such as fossil fuels, solar energy, wind, geothermal, and nuclear fuels. With more than one-hundred diverse cases and solved examples, readers will be able to perform optimizations for a cleaner environment, a sustainable energy future, and affordable energy generation. An essential tool for practicing scientists and engineers who work or do research in the area of energy and exergy, as well as graduate students and faculty in chemical engineering, mechanical engineering and physics.