Chemical Properties Of Material Surfaces

A discussion of the adsorption of inorganics from aqueous solution on inorganic adsorbents. It emphasizes the relationship between adsorption and surface charging, highlighting simple and complex adsorption systems sorted by the adsorbent as well as the adsorbate. The author includes a comprehensive collection of pristine PZC of different materials - covering crystallographic structure, methods of preparation, impurities in the solid, temperature and ionic composition of the solution, experimental methods to determine PZC, and the correlation between zero points and other physical quantities.

Scientific reference covers all surface coatings, paint types, components and formulationsSolvent-, water-based, polymeric, metallic, anti-corrosion, powder and advanced active coatingsChemical equations, molecular configurations and polymer chains linked to key structure/property relationsTechnical details on specialized coatings for marine, automotive and aerospace This professional reference is a unified account of the chemistry and materials science of virtually all major resins, paints, polymeric and inorganic coatings. It offers uniform analyses of the chemical formulations and molecular structures of widely used solvent- and water-based paints and coatings, including discussions of binders, pigments and fillers. In the context of a scientific analysis of structure-property relations the book addresses adhesion, shelf-life, durability, volatility, hardness, mechanical, optical and other engineered qualities. Emerging active coatings such as conductive, self-cleaning, self-healing paints/coatings, plus eco-friendly powder coatings, are included.

DescriptionSurface Alloys and Alloy Surfaces is concerned with the structural, compositional, electronic and chemical properties of the surfaces of solids in which the surface layers, at least are alloyed. Two different categories of system are covered - the surfaces of bulk alloys (alloy surfaces) and surface phases in which one or more outermost atomic layers are alloyed, while the underlying bulk involves no such intermixing (surface alloys).Importance of TopicThe surfaces of bulk alloys have long been known to be of practical interest for their chemical properties. It has also long been known that the surface composition of such alloys commonly differs from that of the underlying bulk. However, our understanding of these chemical and physical phenomena is far from complete and the application of surface science methods to investigate these phenomena is a manifestation of a general trend to study the surfaces of increasing complexity. Surface alloy formation, as a much more recently recognized phenomenon deserves more attention.Why This TitleThis title is important as it provides new insights into a mixture of new and old problems. It is the first to cover the important mixture of material on surface alloys and alloy surfaces. Each chapter is written by experts in different areas of these two interrelated topics, covering theory and experiment, physics and chemistry, geometrical and electronic structure. The coverage of the surface alloy topic is especially novel as it is relatively newly-recognised as quite a common phenomenon.

Chemical Modification of Solid Surfaces by the Use of Additives brings ten comprehensive chapters covering different types of solid surface modifications by using surfactants or other chemicals. Each chapter explains different types of chemical surface modifications that are important for a large variety of applications. The uses of each type of modification is summarized to give the reader an overview of recent developments in this field of materials science. The book also highlights the importance of surface modification for the biomedical application of polysaccharides, sensing application of carbon electrode, metal coating substrate surfaces, microelectronic, microwave applications of perovskite material and the role of nanotechnology. This book is a useful reference for chemical engineering and civil engineering students who wish to understand the surface chemistry of additive materials. Scholars undertaking courses in nanotechnology and environmental science will also benefit from the information presented by the book.

Valuable text focuses on physical and chemical properties of the surface in a reacting system. Topics include crystallite morphology, interface equilibria, adsorption and desorption kinetics, binding states and adsorbate structures, electronic properties of nonmetal catalysts, and more. For research scientists and students of materials science, solid-state chemistry, and catalysis.

In this book, the author determines that a surface is itself a new material for chemical reaction, and the reaction of the surface provides additional new materials on that surface. The revelation of that peculiarity is what makes this book different from an ordinary textbook, and this new point of view will help to provide a new impetus when graduate students and researchers consider their results. The reaction of surface atoms provides additional new compounds, but these compounds cannot be detached from the surface. Some compounds are passive, but others work as catalysts. One superior feature of the surface is the dynamic cooperation of two or more different functional materials or sites on the same surface. This fact has been well established in the preferential oxidation of CO on platinum supported on a carbon nanotube with Ni-MgO at its terminal end. The Pt and Ni-MgO are perfectly separated, but these two are indispensable for the selective oxidation of CO in H2, where the H2O molecule plays a key role. The reader will understand that the complexity of catalysis is due to the complexity of the dynamic processes on the surface.

Throughout human history, we have long encountered the combination of promise, risk, and uncertainty that accompanies emerging technologies. Nanotechnology is a recent example of an emerging technology that promises to drastically improve existing products as well as allow for creative development of new goods and services. This new technology also has its potential downsides. Industry, academia, and regulatory agencies are all working overtime to assess risks accurately while keeping up with the pace of development. Subtle changes in the physicochemical properties of engineered nanomaterials (ENMs) can influence their toxicity and behavior in the environment and so can be used to help control potential ENM risks. This book attempts to encompass the state of the science regarding physicochemical characterization of ENMs. It illuminates the effort to understand these properties and how they may be used to ensure safe ENM deployment in existing or future materials and products.

Materials processing with lasers is a rapidly expanding field which is increasingly captivating the attention of scientists, engineers and manufacturers alike. The aspect of most interest to scientists is provided by the basic interaction mechanisms between the intense light of a laser and materials exposed to a chemically reactive or nonreactive surrounding medium. Engineers and manufacturers see in the laser a new tool which will not only make manufacturing cheaper, faster, cleaner and more accurate but which also opens up entirely new technologies and manufacturing methods that are simply not available using existing techniques. Actual and potential applications range from laser machining to laser-induced materials transformation, coating, patterning, etc. , opening up the prospect of exciting new processing methods for micromechanics, metallurgy, integrated optics, semiconductor manufacture and chemical engineering. This book concentrates on the new and interdisciplinary field of 1 aser-i nduced chemicaZ process i ng of materi als. The techni que permits maskless single-step deposition of thin films of metals, semiconductors or insulators with lateral dimensions ranging from a few tenths of a micrometer up to several centimeters. Moreover, materials removal or synthesis, or surface modifications, such as oxidation, nitridation, reduction, metallization and doping, are also possible within similar dimensions. This book is meant as an introduction. It attempts to cater for the very broad range of specific interests which different groups of readers will have, and this thinking underlies the way in which the material has been arranged.