Chemically Deposited Nanocrystalline Metal Oxide Thin Films

This book guides beginners in the areas of thin film preparation, characterization, and device making, while providing insight into these areas for experts. As chemically deposited metal oxides are currently gaining attention in development of devices such as solar cells, supercapacitors, batteries, sensors, etc., the book illustrates how the chemical deposition route is emerging as a relatively inexpensive, simple, and convenient solution for large area deposition. The advancement in the nanostructured materials for the development of devices is fully discussed.

METAL OXIDE NANOCOMPOSITE THIN FILMS FOR OPTOELECTRONIC DEVICE APPLICATIONS The book provides insight into the fundamental aspects, latest research, synthesis route development, preparation, and future applications of metal oxide nanocomposite thin films. The fabrication of thin film-based materials is important to the future production of safe, efficient, and affordable energy as the devices convert sunlight into electricity. Thin film devices allow excellent interface engineering for high-performance printable solar cells as their structures are highly reliable and stand-alone systems can provide the required megawatts. They have been used as power sources in solar home systems, remote buildings, water pumping, megawatt-scale power plants, satellites, communications, and space vehicles. Metal Oxide Nanocomposite Thin Films for Optoelectronic Device Applications covers the basics of advanced nanometal oxide-based materials, their synthesis, characterization, and applications, and all the updated information on optoelectronics. Topics discussed include the implications of metal oxide thin films, which are critical for device fabrications. It provides updated information on the economic aspect and toxicity, with great focus paid to display applications, and covers some core areas of nanotechnology, which are particularly concerned with optoelectronics and the available technologies. The book concludes with insights into the role of nanotechnology and the physics behind photovoltaics. Audience The book will be an important volume for electronics and electrical engineers, nanotechnologists, materials scientists, inorganic chemists in academic research, and those in industries, exploring the applications of nanoparticles in semiconductors, power electronics, and more.

This book satisfies the interest and curiosity of beginners in thin film electrode preparations, characterizations, and device making, while providing insight into the area for experts. The considerable literature on ‘metal chalcogenides based carbon composites and their versatile applications’ reflect its importance for research and demonstrate how it’s now reached a level where the timely review is necessary to understand the current progress and recent trends and future opportunities. In the book, the authors examine recent advances in the state-of-the-art fabrication techniques of metal sulfide based carbon composites along with their working mechanisms, associated issues/solutions, and possible future are discussed. In addition, detailed insight into the properties and various applications including principles, design, fabrication, and engineering aspects are further discussed.

Thin Film Metal-Oxides provides a representative account of the fundamental structure-property relations in oxide thin films. Functional properties of thin film oxides are discussed in the context of applications in emerging electronics and renewable energy technologies. Readers will find a detailed description of deposition and characterization of metal oxide thin films, theoretical treatment of select properties and their functional performance in solid state devices, from leading researchers. Scientists and engineers involved with oxide semiconductors, electronic materials and alternative energy will find Thin Film Metal-Oxides a useful reference.

This book explores chemical methods for thin film deposition with diverse nanostructured morphology and their applications. Unlike top-down techniques, chemical methods offer low cost, simplicity, and growth of nanostructured surface architecture with ease of small to large-scale area deposition. The book primarily focuses on innovative twelve chemical methods for thin-film deposition on one platform. Since each method has its own advantages and disadvantages, it is crucial to select the specific method for specific material to be deposited depending upon what type of application is targeted. Due to inclusive of diverse chemical deposition methods, researcher will have knowledge about best choice of the deposition method to be adopted. Inclusive methods discussed in the book are chemical bath deposition, successive ionic layer adsorption and reaction, ion exchange, electroless deposition, electrodeposition, hydrothermal, spray pyrolysis, spin coating, dip coating, doctor blade, screen printing, and sol-gel. The selection of the correct procedure for material to be deposited in thin film form depends on its unique process parameters based on the kind of application and its requirement. The role of preparative factors necessary for thin film alters properties related to structure and surface morphology, electrical conductivity and optical band gap which have been extensively discussed along with the underlying science of film synthesis. The book provides a comprehensive overview of the field of chemical methods for thin film synthesis to applications. In addition to synthesis, the book covers characterization, instrumentation, and industrial application of thin films. As a result, concentrated techniques will be of great interest to university/college professors, students and new engineers as well as postdocs and scientists in the area.

Solution Methods for Metal Oxide Nanostructures reviews solution processes that are used for synthesizing 1D, 2D and 3D metal oxide nanostructures in either thin film or in powder form for various applications. Wet-chemical synthesis methods deal with chemical reactions in the solution phase using precursors at proper experimental conditions. Wet-chemical synthesis routes offer a high degree of controllability and reproducibility for 2D nanomaterial fabrication. Solvothermal synthesis, template synthesis, self-assembly, oriented attachment, hot-injection, and interface-mediated synthesis are the main wet-chemical synthesis routes for 2D nanomaterials. Solution Methods for Metal Oxide Nanostructures also addresses the thin film deposition metal oxides nanostructures, which plays a very important role in many areas of chemistry, physics and materials science.Each chapter includes information on a key solution method and their application in the design of metal oxide nanostructured materials with optimized properties for important applications. The pros and cons of the solution method and their significance and future scope is also discussed in each chapter. Readers are provided with the fundamental understanding of the key concepts of solution synthesis methods for fabricating materials and the information needed to help them select the appropriate method for the desired application. Reviews the most relevant wet chemical solution methods for metal oxide nanostructures, including sol-gel, solvothermal, hydrothermal, co-precipitation methods, and more Addresses thin film deposition techniques for metal oxide nanostructures, such as spray-pyrolysis, electrodeposition, spin coating and self-assembly Discusses the pros and cons of each solution method and its significance and future opportunities

The focus of the book is to explore metal oxides exhibiting a high optical transmittance as applicable in the field of light-emitting diodes (LEDs), photo-catalysts, and so forth. It provides exposure to structural and chemical parameters of optically active metal oxides as a phosphor, innovative and currently demanded synthesis methods, and their proper characterization. It further covers applications such as optical thermometry, scintillation, anti-counterfeit, solid-state lighting and spectral modifier for solar cells, VUV application, and long persistent light emission phenomenon. Features: Reviews selection of structurally and functionally active materials for effective synthesis of metal oxides Exclusively covers large number of areas of applications of the luminescent metal oxides Cover various aspects of metal oxide research including synthesis and applications Includes chapters on synthesis-related predictions using machine learning Discusses radiation dosimetry and bio-imaging aspects This book is aimed at researchers and graduate students in materials science and phosphor technology.

This is the first text to cover all aspects of solution processed functional oxide thin-films. Chemical Solution Deposition (CSD) comprises all solution based thin- film deposition techniques, which involve chemical reactions of precursors during the formation of the oxide films, i. e. sol-gel type routes, metallo-organic decomposition routes, hybrid routes, etc. While the development of sol-gel type processes for optical coatings on glass by silicon dioxide and titanium dioxide dates from the mid-20th century, the first CSD derived electronic oxide thin films, such as lead zirconate titanate, were prepared in the 1980’s. Since then CSD has emerged as a highly flexible and cost-effective technique for the fabrication of a very wide variety of functional oxide thin films. Application areas include, for example, integrated dielectric capacitors, ferroelectric random access memories, pyroelectric infrared detectors, piezoelectric micro-electromechanical systems, antireflective coatings, optical filters, conducting-, transparent conducting-, and superconducting layers, luminescent coatings, gas sensors, thin film solid-oxide fuel cells, and photoelectrocatalytic solar cells. In the appendix detailed “cooking recipes” for selected material systems are offered.