Dielectric Ceramics

Proceedings of the Symposium on Dielectric Materials and Multilayer Electronic Devices and the Symposium on Morphotropic Phase Boundary Phenomena and Perovskite Materials, held April 28 - May 1, 2002, in St. Louis, Missouri, during the 104th Annual Meeting of the American Ceramic Society, and the Focused Session on High Strain Piezoelectrics, held April 22-25, 2001, in Indianapolis, Indiana, during the 103rd Annual Meeting of the American Ceramic Society.

Detailed study of the composition, physical properties, and manufacturing methods of ceramic dielectrics and capacitors in light of recent commercial developments and influences. Covers the essential theory and applications for electrical engineers wanting informed insight into the characteristics, advantages, and limitations of this class of capacitors, and for ceramicists seeking to improve their electrical expertise.

This comprehensive book covers recent developments in advanced dielectric, piezoelectric and ferroelectric materials. Dielectric materials such as ceramics are used to manufacture microelectronic devices. Piezoelectric components have been used for many years in radioelectrics, time-keeping and, more recently, in microprocessor-based devices. Ferroelectric materials are widely used in various devices such as piezoelectric/electrostrictive transducers and actuators, pyroelectric infrared detectors, optical integrated circuits, optical data storage and display devices.The book is divided into eight parts under the general headings: High strain high performance piezo- and ferroelectric single crystals; Electric field-induced effects and domain engineering; Morphotropic phase boundary related phenomena; High power piezoelectric and microwave dielectric materials; Nanoscale piezo- and ferroelectrics; Piezo- and ferroelectric films; Novel processing and new materials; Novel properties of ferroelectrics and related materials. Each chapter looks at key recent research on these materials, their properties and potential applications.Advanced dielectric, piezoelectric and ferroelectric materials is an important reference tool for all those working in the area of electrical and electronic materials in general and dielectrics, piezoelectrics and ferroelectrics in particular. Covers the latest developments in advanced dielectric, piezoelectric and ferroelectric materials Includes topics such as high strain high performance piezo and ferroelectric single crystals Discusses novel processing and new materials, and novel properties of ferroelectrics and related materials

Barium titanate is one of the most important electronic materials; due to its high permittivity, low dielectric loss and high tunability. The environment friendly material is suitable for microphones and microwave device applications such as tunable capacitors, delay lines, filters, resonators and phase shifters. Doped titanates are extensively used for various electronic devices, such as transducers, piezoelectric actuators, passive memory storage devices, dynamic random access memory (DRAM), multilayer ceramic capacitors (MLCCs), positive temperature coefficient resistors (PTCR), optoelectronic devices and infrared sensors. The book presents research results concerning the electron density distribution in a number of doped barium titanate ceramic materials using experimental X-ray diffraction data, UV-visible spectrophotometry (UV-vis), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The analysis of interatomic bonding and electron density distribution is important for predicting the properties of potentially important materials and has previously been lacking for the materials studied. Barium Titanate, Barium Titanate Doping, Dielectric Ceramics, Permittivity, Tunability, Transducers, Piezoelectric Actuators, Memory Storage Devices, Multilayer Ceramic Capacitors, Optoelectronic Devices, X-Ray Diffraction Data, UV-Visible Spectrophotometry, Energy Dispersive X-Ray Spectroscopy, Interatomic Bonding, Electron Density Distribution, Ceramic Property Predictions.

This book provides fundamental knowledge of ceramics science and technology in a compact volume. Based on inorganic chemistry, it is intended as a reader for graduate students and young researchers beginning work in ceramics. The importance of the book is that it provides a scientific understanding of structure, properties, and processing from the chemical aspect, leading to creation of future ceramics. Ceramics have high hardness, strength, thermal and chemical stability, as well as various electromagnetic functions. To take full advantage of ceramics, their use has been advanced to engineering and electronic ceramics. Most ceramics have been fabricated by powder processing, and new technologies have also evolved such as CVD and sol-gel methods: new ceramics aimed at new functions of highly pure oxides and artificial nitrides, carbides, and borides; fine ceramics focused on precise control of composition and microstructure; and design of unique morphology, such as nanoparticles, nanofibers, nanosheets, mesoporous materials, and hybrids. Materials are composed of atoms and molecules. They are assembled into crystals and are amorphous, leading to 3-D micro/nano structures. In addition to the topics described above, this book shows the importance of chemistry for materials design at the nanometer scale, and that chemistry develops new fields of environment, energy, informatics, biomaterials, and other areas.

Microwave dielectric materials play a key role in our global society with a wide range of applications, from terrestrial and satellite communication including software radio, GPS, and DBS TV to environmental monitoring via satellite. A small ceramic component made from a dielectric material is fundamental to the operation of filters and oscillators in several microwave systems. In microwave communications, dielectric resonator filters are used to discriminate between wanted and unwanted signal frequencies in the transmitted and received signal. When the wanted frequency is extracted and detected, it is necessary to maintain a strong signal. For clarity it is also critical that the wanted signal frequencies are not affected by seasonal temperature changes. In order to meet the specifications of current and future systems, improved or new microwave components based on dedicated dielectric materials and new designs are required. The recent progress in microwave telecommunication, satellite broadcasting and intelligent transport systems (ITS) has resulted in an increased demand for Dielectric Resonators (DRs). With the recent revolution in mobile phone and satellite communication systems using microwaves as the propagation media, the research and development in the field of device miniaturization has been a major challenge in contemporary Materials Science. In a mobile phone communication, the message is sent from a phone to the nearest base station, and then on via a series of base stations to the other phone. At the heart of each base station is the combiner/filter unit which has the job of receiving the messages, keeping them separate, amplifying the signals and sending then onto the next base station. For such a microwave circuit to work, part of it needs to resonate at the specific working frequency. The frequency determining component (resonator) used in such a high frequency device must satisfy certain criteria. The three important characteristics required for a dielectric resonator are (a) a high dielectric constant which facilitates miniaturization (b) a high quality factor (Qxf) which improves the signal-to-noise ratio, (c) a low temperature coefficient of the resonant frequency which determines the stability of the transmitted frequency. During the past 25 years scientists the world over have developed a large number of new materials (about 3000) or improved the properties of known materials. About 5000 papers have been published and more than 1000 patents filed in the area of dielectric resonators and related technologies. This book brings the data and science of these several useful materials together, which will be of immense benefit to researchers and engineers the world over. The topics covered in the book includes factors affecting the dielectric properties, measurement of dielectric properties, important low loss dielectric material systems such as perovskites, tungsten bronze type materials, materials in BaO-TiO2 system, (Zr,Sn)TiO4, alumina, rutile, AnBn-1O3n type materials, LTCC, ceramic-polymer composites etc. The book also has a data table listing all reported low loss dielectric materials with properties and references arranged in the order of increasing dielectric constant. Collects together in one source data on all new materials used in wireless communication Includes tabulated properties of all reported low loss dielectric materials In-depth treatment of dielectric resonator materials

Dielectric Spectroscopy of Electronic Materials: Applied Physics of Dielectrics incorporates the results of four decades of research and applications of dielectric spectroscopy for solids, mostly for the investigation of materials used in electronics. The book differs from others by more detailed analysis of the features of dielectric spectra conditioned by specific mechanisms of electrical polarization and conductivity. Some original methods are presented in the simulation of frequency distributions (relaxers and oscillators), with methods proposed for various ferroelectrics frequency-temperature dielectric spectra. Also described are original methods for ferroelectrics on microwaves investigation, including the features of thin films study. The book is not burdened by complex mathematical proofs and should help readers quickly understand how to apply dielectric spectroscopy methods to their own research problems. More advanced readers may also find this book valuable as a review of the key concepts and latest advances on the topics presented. Introduces critical material characterization techniques by an expert with more than 40 years of experience in dielectric spectroscopy Reviews advances in dielectric spectroscopy methods to enable advances such as the miniaturization of electronics at the nanoscale Provides an overview of polarization mechanisms utilizing different models (i.e., oscillator and relaxation)