Direct Liquid Fuel Cells

Direct Liquid Fuel Cells is a comprehensive overview of the fundamentals and specificities of the use of methanol, ethanol, glycerol, formic acid and formate, dimethyl ether, borohydride, hydrazine and other promising liquid fuels in fuel cells. Each chapter covers a different liquid fuel-based fuel cell such as: Anode catalysts of direct methanol fuel cells (DMFCs), future system designs and future trends for direct ethanol fuel cells (DEFCs), development of catalysts for direct glycerol fuel cells (DGFCs), the mechanisms of the reactions taking place at the anode and cathode electrodes, and the reported anode catalysts for direct formic acid fuel cell (DFAFC) and direct formate fuel cell (DFFC), characteristics of direct dimethyl ether fuel cell (DDMEFC), including its electrochemical and operating systems and design, the developments in direct borohydride fuel cells, the development of catalysts for direct hydrazine fuel cells (DHFCs), and also the uncommonly used liquids that have a potential for fuel cell applications including 2-propanol, ethylene glycol, ascorbic acid and ascorbate studied in the literature as well as utilization of some blended fuels. In each part, the most recent literature is reviewed and the state of the art is presented. It also includes examples of practical problems with solutions and a summarized comparison of performance, advantages, and limitations of each type of fuel cell discussed. Direct Liquid Fuel Cells is not a typical textbook but rather designed as a reference book of which any level of students (undergraduate or graduate), instructors, field specialists, industry and general audience, who benefit from current and complete understanding of the many aspects involved in the development and operation of these types of fuel cells, could make use of any chapter when necessary. Presents information on different types of direct liquid fuel cells. Explores information under each section, for specific fuel-based fuel cells in more detail in terms of the materials used. Covers three main sections: direct alcohol, organic fuel-based and inorganic fuel-based fuel cells

Direct Liquid Fuel Cells is a comprehensive overview of the fundamentals and specificities of the use of methanol, ethanol, glycerol, formic acid and formate, dimethyl ether, borohydride, hydrazine and other promising liquid fuels in fuel cells. Each chapter covers a different liquid fuel-based fuel cell such as: Anode catalysts of direct methanol fuel cells (DMFCs), future system designs and future trends for direct ethanol fuel cells (DEFCs), development of catalysts for direct glycerol fuel cells (DGFCs), the mechanisms of the reactions taking place at the anode and cathode electrodes, and the reported anode catalysts for direct formic acid fuel cell (DFAFC) and direct formate fuel cell (DFFC), characteristics of direct dimethyl ether fuel cell (DDMEFC), including its electrochemical and operating systems and design, the developments in direct borohydride fuel cells, the development of catalysts for direct hydrazine fuel cells (DHFCs), and also the uncommonly used liquids that have a potential for fuel cell applications including 2-propanol, ethylene glycol, ascorbic acid and ascorbate studied in the literature as well as utilization of some blended fuels. In each part, the most recent literature is reviewed and the state of the art is presented. It also includes examples of practical problems with solutions and a summarized comparison of performance, advantages, and limitations of each type of fuel cell discussed. Direct Liquid Fuel Cells is not a typical textbook but rather designed as a reference book of which any level of students (undergraduate or graduate), instructors, field specialists, industry and general audience, who benefit from current and complete understanding of the many aspects involved in the development and operation of these types of fuel cells, could make use of any chapter when necessary. Presents information on different types of direct liquid fuel cells. Explores information under each section, for specific fuel-based fuel cells in more detail in terms of the materials used. Covers three main sections: direct alcohol, organic fuel-based and inorganic fuel-based fuel cells

The comprehensive, accessible introduction to fuel cells, their applications, and the challenges they pose Fuel cells electrochemical energy devices that produce electricity and heat present a significant opportunity for cleaner, easier, and more practical energy. However, the excitement over fuel cells within the research community has led to such rapid innovation and development that it can be difficult for those not intimately familiar with the science involved to figure out exactly how this new technology can be used. Fuel Cells: Problems and Solutions, Second Edition addresses this issue head on, presenting the most important information about these remarkable power sources in an easy-to-understand way. Comprising four important sections, the book explores: The fundamentals of fuel cells, how they work, their history, and much more The major types of fuel cells, including proton exchange membrane fuel cells (PEMFC), direct liquid fuel cells (DLFC), and many others The scientific and engineering problems related to fuel cell technology The commercialization of fuel cells, including a look at their uses around the world Now in its second edition, this book features fully revised coverage of the modeling of fuel cells and small fuel cells for portable devices, and all-new chapters on the structural and wetting properties of fuel cell components, experimental methods for fuel cell stacks, and nonconventional design principles for fuel cells, bringing the content fully up to date. Designed for advanced undergraduate and graduate students in engineering and chemistry programs, as well as professionals working in related fields, Fuel Cells is a compact and accessible introduction to the exciting world of fuel cells and why they matter.

This first book to focus on a comprehensive description on DMFC electrocatalysis draws a clear picture of the current status of DMFC technology, especially the advances, challenges and perspectives in the field. Leading researchers from universities, government laboratories and fuel cell industries in North America, Europe and Asia share their knowledge and information on recent advances in the fundamental theories, experimental methodologies and research achievements. In order to help readers better understand the science and technology of the subject, some important and representative figures, tables, photos, and comprehensive lists of reference papers are also included, such that all the information needed on this topic may be easily located. An indispensable source for physical, catalytic, electro- and solid state chemists, as well as materials scientists and chemists in industry.

Direct Methanol Fuel Cell Technology presents the overall progress witnessed in the field of DMFC over the past decade, highlighting the components, materials, functions, properties and features, designs and configurations, operations, modelling, applications, pros and cons, social, political and market penetration, economics and future directions. The book discusses every single aspect of DMFC device technology, the associated advantages and drawbacks of state-of-the-art materials and design, market opportunities and commercialization aspects, and possible future directions of research and development. This book, containing critical analyses and opinions from experts around the world, will garner considerable interest among actual users/scientists/experts. Analyzes developments of membrane electrolytes, electrodes, catalysts, catalyst supports, bipolar plates, gas diffusion layers and flow channels as critical components of direct methanol fuel cells Includes modeling of direct methanol fuel cells to understand their scaling up potentials Discusses commercial aspects of direct methanol fuel cells in terms of market penetration, end application, cost, viability, reliability, social and commercial perception, drawbacks and prospects

Since publication of the first edition of Fuel Cell Systems Explained, three compelling drivers have supported the continuing development of fuel cell technology. These are: the need to maintain energy security in an energy-hungry world, the desire to move towards zero-emission vehicles and power plants, and the mitigation of climate change by lowering of CO2 emissions. New fuel cell materials, enhanced stack performance and increased lifetimes are leading to the emergence of the first truly commercial systems in applications that range from fork-lift trucks to power sources for mobile phone towers. Leading vehicle manufacturers have embraced the use of electric drive-trains and now see hydrogen fuel cells complementing advanced battery technology in zero-emission vehicles. After many decades of laboratory development, a global but fragile fuel cell industry is bringing the first commercial products to market. This thoroughly revised edition includes several new sections devoted to, for example, fuel cell characterisation, improved materials for low-temperature hydrogen and liquid-fuelled systems, and real-world technology implementation. Assuming no prior knowledge of fuel cell technology, the third edition comprehensively brings together all of the key topics encompassed in this diverse field. Practitioners, researchers and students in electrical, power, chemical and automotive engineering will continue to benefit from this essential guide to the principles, design and implementation of fuel cell systems.

Direct Alcohol Fuel Cells: Materials, Performance, Durability and Applications begins with an introductory overview of direct alcohol fuel cells (DAFC); it focuses on the main goals and challenges in the areas of materials development, performance, and commercialization. The preparation and the properties of the anodic catalysts used for the oxidation of methanol, higher alcohols, and alcohol tolerant cathodes are then described. The membranes used as proton conductors in DAFC are examined, as well as alkaline membranes, focusing on the electrical conductivity and alcohol permeability. The use of different kinds of carbon materials as catalyst supports, gas diffusion layers, and current collectors in DAFC is also discussed. State of the art of the modeling is used to estimate performance and durability. The closing chapter reviews the use of DAFC in portable equipment and mobile devices and features a detailed discussion on the mechanisms of component degradation which limits their durability. This book is written to facilitate the understanding of DAFC technology, applications, and future challenges. It is an excellent introduction for electrochemical and material engineers interested in small fuel cells as portable energy sources, scientists focused on materials science for energy production and storage, as well as policy-makers in the area of renewable energies.

In the course of his distinguished career spanning about half a century, George A Olah, winner of the 1994 Nobel Prize for Chemistry, has been exceedingly prolific and has published more than 1000 scientific papers and 15 books and holds more than 100 patents. This invaluable volume contains about 250 papers selected for their breadth and current importance. Contents: Volume 1: Early StudiesElectrophilic Aromatic SubstitutionFriedel-Crafts ChemistryStable (Persistent), Long Lived Carbocations: General AspectsTrivalent Alkyl (Cycloalkyl) Cations (Carbenium Ions)π- and πσ-Delocalized CarbocationsHeteroatom and Metal Substituted CarbocationsCarbodicationsAromatic and Homoaromatic Cations and DicationsFive and Higher Coordinate (Nonclassical) Carbonium Ions: Controversy and SignificanceMagic Acid and Superacid ChemistrySolid Superacid CatalysisFrom Kekulé's Four-Valent Carbon to Higher Coordinate HypercarbonElectrophilic Chemistry of Saturated HydrocarbonsOnium Ions: General Aspects Volume 2: Oxonium, Sulfonium, Selenonium and Telluronium IonsAzonium IonsHalonium IonsMiscellaneous Onium IonsGitonic Onium Di(Poly)cations and Superelectrophilic ActivationSynthetic Reagents, Methods and ReactionsOxygenation and SulfurationNitration and Nitrosation ChemistryOrganofluorine ChemistryOrganometallic ChemistryPolymer ChemistryNew Approaches to Future of Hydrocarbon NeedsMiscellaneous Studies keywords: