Electrochemical Science And Technology

Electrochemistry is a discipline of wide scientific and technological interest. Scientifically, it explores the electrical properties of materials and especially the interfaces between different kinds of matter. Technologically, electrochemistry touches our lives in many ways that few fully appreciate; for example, materials as diverse as aluminum, nylon, and bleach are manufactured electrochemically, while the batteries that power all manner of appliances, vehicles, and devices are the products of electrochemical research. Other realms in which electrochemical science plays a crucial role include corrosion, the disinfection of water, neurophysiology, sensors, energy storage, semiconductors, the physics of thunderstorms, biomedical analysis, and so on. This book treats electrochemistry as a science in its own right, albeit resting firmly on foundations provided by chemistry, physics, and mathematics. Early chapters discuss the electrical and chemical properties of materials from which electrochemical cells are constructed. The behavior of such cells is addressed in later chapters, with emphasis on the electrodes and the reactions that occur on their surfaces. The role of transport to and from electrodes is a topic that commands attention, because it crucially determines cell efficiency. Final chapters deal with voltammetry, the methodology used to investigate electrode behavior. Interspersed among the more fundamental chapters are chapters devoted to applications of electrochemistry: electrosynthesis, power sources, “green electrochemistry”, and corrosion. Electrochemical Science and Technology is addressed to all who have a need to come to grips with the fundamentals of electrochemistry and to learn about some of its applications. It will constitute a text for a senior undergraduate or graduate course in electrochemistry. It also serves as a source of material of interest to scientists and technologists in various fields throughout academia, industry, and government – chemists, physicists, engineers, environmentalists, materials scientists, biologists, and those in related endeavors. This book: Provides a background to electrochemistry, as well as treating the topic itself. Is accessible to all with a foundation in physical science, not solely to chemists. Is addressed both to students and those later in their careers. Features web links (through www.wiley.com/go/EST) to extensive material that is of a more tangential, specialized, or mathematical nature. Includes questions as footnotes to support the reader’s evolving comprehension of the material, with fully worked answers provided on the web. Provides web access to Excel® spreadsheets which allow the reader to model electrochemical events. Has a copious Appendix of relevant data.

Sustainable and Green Electrochemical Science and Technology brings together the basic concepts of electrochemical science and engineering and shows how these are applied in an industrial context, emphasising the major role that electrochemistry plays within society and industry in providing cleaner, greener and more sustainable technologies. Electrochemistry has many applications for sustainability; it can be used to store energy, synthesise materials and chemicals, to generate power and to recycle valuable resources. Coverage includes Electrochemistry, Electrocatalysis and Thermodynamics Electrochemical Cells, Materials and Reactors Carbon Dioxide Reduction and Electro-Organic Synthesis Hydrogen production and Water Electrolysis Inorganic Synthesis Electrochemical Energy Storage and Power Sources Electrochemical processes for recycling and resource recovery Fuel Cell Technologies This book is targeted at both industrial and academic readers, providing a good technological reference base for electrochemistry. It will enable the reader to build on basic principles of electrochemistry, and takes these through to cell design for various and diverse applications.

"Fundamentals of Electrochemical Science is a valuable contribution and I support the publication....I am looking forward to seeing this book on the shelves, and once published, I will not hesitate to recommend itto my students." --ANDRZEJ WIECKOWSKI, University of Illinois at Urbana-Champaign Deals comprehensively with the basic science of electrochemistry Treats electrochemistry as a discipline in its own right and not as a branch of physical or analytical chemistry Provides a thorough and quantitative description of electrochemical fundamentals

The Second Edition of Introduction to Electrochemical Science and Engineering outlines the basic principles and techniques used in the development of electrochemical engineering related technologies, such as fuel cells, electrolyzers, and flow-batteries. Covering topics from electrolyte solutions to electrochemical energy conversion systems and corrosion, this revised and expanded edition provides new educational material to help readers familiarize themselves with some of today’s most useful electrochemical concepts. The Second Edition includes a new Appendix C with a detailed description of how the most common electrochemical laboratories can be organized, what data should be collected, and how the data should be treated and presented in a report. Video demonstrations for these laboratories are available on YouTube. In addition, the author has added conceptual and numerical exercises to all of the chapters to help with the understanding of the book material and to extend the important aspects of the electrochemical science and engineering. Finally, electrochemical impedance spectroscopy is now used in most electrochemical laboratories, and so a new section briefly describes this technique in Chapter 7. This new edition Ensures readers have a fundamental knowledge of the core concepts of electrochemical science and engineering, such as electrochemical cells, electrolytic conductivity, electrode potential, and current–potential relations related to a variety of electrochemical systems Develops the initial skills needed to understand an electrochemical experiment and successfully evaluate experimental data without visiting a laboratory Promotes an appreciation of the capabilities and applications of key electrochemical techniques Features eight lab descriptions and instructions that can be used to develop the labs by instructors for a university electrochemical engineering class Integrates eight online videos with lab demonstrations to advise instructors and students on how the labs can be carried out Features a solutions manual for adopting instructors The Second Edition is an ideal and unique text for undergraduate engineering and science students and readers in need of introductory-level content. Graduate students and engineers looking for a quick introduction to the subject will benefit from the simple structure of this book. Instructors interested in teaching the subject to undergraduate students can immediately use this book without reservation.

Polymers are normally thought of as insulators. In the last few years, however, a rapidly advancing and changing field has developed which exploits the ability of certain polymers to conduct charge, in some cases electronically and in others by means of ions. Certain electrochemical processes of major present-day industrial importance depend on the presence of polymeric materials for their efficient operation. The chlor-alkali industry is a prime example. Exciting new power sources, in which polymers replace conventional electrodes and/or electrolytes, are being intensively developed. Re markable advances in the understanding of electrochemical processes and the development of a range of sophisticated sensors and other devices have been made possible by the use of polymer-coated electrodes. The impact of polymers on the electrochemical field is still in its initial growth phase. The results of a rapidly escalating volume of industrial and academic research are being applied in many contexts, especially in the information technology field. In certain areas, the use of polymers is only just beginning to show its impact. In the next year or so, the use of polymerised Langmuir-Blodgett films as a substitute for conventional E-beam resists in electronics can be anticipated. By the end of the decade, polymerised mono- and multi-layers may be incorporated in very large-scale integrated circuits.

Closing the gap between electrochemical engineering science and electrochemical technology, this volume is for all electrochemists and electrochemical engineers, metallurgists, engineers in chemical process, galvanic, metallurgical and electric power industries.

This book titled "Recent Trend in Electrochemical Science and Technology" contains a selection of chapters focused on advanced methods used in the research area of electrochemical science and technologies; descriptions of electrochemical systems; processing of novel materials and mechanisms relevant for their operation. This book provides an overview on some of the recent development in electrochemical science and technology. Particular emphasis is given both to the theoretical and the experimental aspect of modern electrochemistry. Since it was impossible to cover the rich diversity of electrochemical techniques and applications in a single issue, the focus is on the recent trends and achievements related to electrochemical science and technology.