Electronic Excitations In Organic Based Nanostructures

The first book devoted to a systematic consideration of electronic excitations and electronic energy transfer in organic crystalline multilayers and organics based nanostructures(quantum wells, quantum wires, quantum dots, microcavities). The ingenious combination of organic with inorganic materials in one and the same hybrid structure is shown to give qualitatively new opto-electronic phenomena, potentially important for applications in nonlinear optics, light emitting devices, photovoltaic cells, lasers and so on. The book will be useful not only for physicists but also for chemists and biologists.To help the nonspecialist reader, three Chapters which contain a tutorial and updated introduction to the physics of electronic excitations in organic and inorganic solids have been included. * hybrid Frenkel-Wannier-Mott excitons * microcavities with crystalline and disordered organics * electronic excitation at donor-acceptor interfaces * cold photoconductivity at donor-acceptor interface * cummulative photovoltage * Feorster transfer energy in microcavity * New concepts for LEDs

During the last decade our expertise in nanotechnology has advanced considerably. The possibility of incorporating in the same nanostructure different organic and inorganic materials has opened up a promising field of research, and has greatly increased the interest in the study of properties of excitations in organic materials. In this book not only the fundamentals of Frenkel exciton and polariton theory are described, but also the electronic excitations and electronic energy transfers in quantum wells, quantum wires and quantum dots, at surfaces, at interfaces, in thin films, in multilayers, and in microcavities. Among the new topics in the book are those devoted to the optics of hybrid Frenkel-Wannier-Mott excitons in nanostructures, polaritons in organic microcavities including hybrid organic-inorganic microcavities, new concepts for organic light emitting devices, the mixing of Frenkel and charge-transfer excitons in organic quasi one-dimensional crystals, excitons and polaritons in one and two-dimensional crystals, surface electronic excitations, optical biphonons, and Fermi resonances by polaritons. All new phenomena described in the book are illustrated by available experimental observations. The book will be useful for scientists working in the field of photophysics and photochemistry of organic solids (for example, organic light-emitting devices and solar cells), and for students who are entering this field. It is partly based on a book by the author written in 1968 - "Theory of Excitons" - in Russian. However the new book includes only 5 chapters from this version, all of which have been updated. The 10 new chapters contain discussions of new phenomena, their theory and their experimental observations.

The book provides a detailed and uniform treatment of the science and technology of light absorbing organic materials (used in nano-scale optical devices, LEDs, solar cells, flat screens, cell phones etc), which are increasingly investigated for use in mass market products.

The book provides a review of some of the most important and 'hot' topics in condensed matter physics today. It includes contributions by internationally leading experts such as V M Agranovich, B L Altshuler, E Burstein, V L Ginzburg, K Von Klitzing, P B Littlewood, M Pepper etc, and can serve as a guide-book to modern condensed matter physics.

The remarkable development of organic thin film transistors (OTFTs) has led to their emerging use in active matrix flat-panel displays, radio frequency identification cards, and sensors. Exploring one class of OTFTs, Organic Field-Effect Transistors provides a comprehensive, multidisciplinary survey of the present theory, charge transport studies, synthetic methodology, materials characterization, and current applications of organic field-effect transistors (OFETs). Covering various aspects of OFETs, the book begins with a theoretical description of charge transport in organic semiconductors at the molecular level. It then discusses the current understanding of charge transport in single-crystal devices, small molecules and oligomers, conjugated polymer devices, and charge injection issues in organic transistors. After describing the design rationales and synthetic methodologies used for organic semiconductors and dielectric materials, the book provides an overview of a variety of characterization techniques used to probe interfacial ordering, microstructure, molecular packing, and orientation crucial to device performance. It also describes the different processing techniques for molecules deposited by vacuum and solution, followed by current technological examples that employ OTFTs in their operation. Featuring respected contributors from around the world, this thorough, up-to-date volume presents both the theory behind OFETs and the latest applications of this promising technology.

This comprehensive text collects the progress made in recent years in the fabrication, processing, and performance of organic nanophotonic materials and devices. The first part of the book addresses photonic nanofabrications in a chapter on multiphoton processes in nanofabrication and microscopy imaging. The second part of the book is focused on nanoscale light sources for integrated nanophotonic circuits, and is composed of three chapters on organic nano/microcavities, organic laser materials, and polymer light-emitting electrochemical cells (LECs). The third part is focused on the interactions between light and matter and consists in three chapters, including the propagation of light in organic nanostructures and photoswitches based on nonlinear optical polymer photonic crystals and photoresponsive molecules, respectively. The final chapter of this book introduces the integration of miniaturized photonic devices and circuits with various organic nanophotonic elements. The practical case studies demonstrate how the latest applications actually work, while tables throughout the book summarize key information and diagrams and figures help readers to grasp complex concepts and designs. The references at the end of each chapter can be used as the gateway to the relevant literature in the field. Moreover, this book helps researchers to advance their own investigations to develop the next generation of miniaturized devices for information processing, efficient energy conversion, and highly accurate sensing. Yong Sheng Zhao, PhD, is a Professor at the Institute of Chemistry, Chinese Academy of Sciences (ICCAS), China.

Cu(In1-xGax)Se2 Based Thin Film Solar Cells provides valuable contents about the fabrication and characterization of chalcopyrite Cu(In1-xGax)Se2 based thin film solar cells and modules. The growth of chalcopyrite Cu(In1-xGax)(S1-ySey)2 absorbers, buffers, window layers, antireflection coatings, and finally metallic grids, which are the sole components of solar cells, is clearly illustrated. The absorber, which contains multiple elements, segregates secondary phases if the growth conditions are not well optimized i.e., the main drawback in the fabrication of solar cells. More importantly the solutions for the growth of thin films are given in detail. The properties of all the individual layers and single crystals including solar cells analyzed by different characterization techniques such as SEM, AFM, XPS, AES, TEM, XRD, optical, photoluminescence, and Raman spectroscopy are explicitly demonstrated. The electrical analyses such as conductivities, Hall mobilities, deep level transient spectroscopy measurements etc., provide a broad picture to understand thin films or single crystals and their solar cells. The book clearly explains the working principle of energy conversion from solar to electrical with basic sciences for the chalcopyrite based thin film solar cells. Also, it demonstrates important criteria on how to enhance efficiency of the solar cells and modules. The effect of environmental factors such as temperature, humidity, aging etc., on the devices is mentioned by citing several examples. Illustrates a number of growth techniques to prepare thin film layers for solar cells Discusses characterization techniques such as XRD, TEM, XPS, AFM, SEM, PL, CL, Optical measurements, and Electrical measurements Includes I-V, C-V measurements illustrations Provides analysis of solar cell efficiency Presents current trends in thin film solar cells research and marketing

This volume explores high-pressure phenomena, the third fundamental variable altering materials (after the variables of temperature and chemical composition). Pressure is in many ways the most remarkable as it spans some 60 orders of magnitude in the universe.