Epoxy Resin Technology

Epoxy resins have been commercially available for about 45 years and now have many major industrial applications, especially where technical advantages warrant their somewhat higher costs. The chemistry of these resins is fascinating and has attracted study by many very able scientists. The technological applications of the epoxy resins are very demanding and there are many new developments each year. The aims of the present book are to present in a compact form both theoretical and practical information that will assist in the study, research and innovations in the field of epoxy resin science and technology. The literature on epoxy resins is so vast that it is not possible to be encyclopaedic and that is not the function of the present text. It is the editor's hope that the selection of topics discussed will provide an up-to-date survey. There is some overlap in the chapters but this is minimal and so each chapter is essentially self contained. As with all chemicals there are toxicological and other hazards. These are not dealt with in this text since a little knowledge can be dangerous, but material supplied can provide information regarding any safety precautions that may be necessary. However, often these precautions are not onerous and epoxy resins, or more specifically the hardeners, can be handled readily. It is hoped that this text will provide an up-to-date outline of the science and technology of epoxy resins and stimulate further research into unsolved problems and assist further technological developments.

Epoxy is a term used to denote both the basic components and the cured end products of epoxy resins, as well as a colloquial name for the epoxide functional group. Epoxy resin are a class of thermoset materials used extensively in structural and specialty composite applications because they offer a unique combination of properties that are unattainable with other thermoset resins. Epoxies are monomers or prepolymers that further reacts with curing agents to yield high performance thermosetting plastics. They have gained wide acceptance in protecting coatings, electrical and structural applications because of their exceptional combination of properties such as toughness, adhesion, chemical resistance and superior electrical properties. Epoxy resins are characterized by the presence of a three membered cycle ether group commonly referred to as an epoxy group 1,2-epoxide, or oxirane. The most widely used epoxy resins are diglycidyl ethers of bisphenol-A derived from bisphenol-A and epichlorohydrin. The market of epoxy resins are growing day by day. Today the total business of this product is more than 100 crores. Epoxy resins are used for about 75% of wind blades currently produced worldwide, while polyester resins account for the remaining 25%. A standard 1.5-MW (megawatt) wind turbine has approximately 10 tonnes of epoxy in its blades. Traditionally, the markets for epoxy resins have been driven by demand generated primarily in areas of adhesives, building and civil construction, electrical insulation, printed circuit boards, and protective coatings for consumer durables, amongst others. The major contents of the book are synthesis and characteristics of epoxy resin, manufacture of epoxy resins, epoxide curing reactions, the dynamic mechanical properties of epoxy resins, physical and chemical properties of epoxy resins, epoxy resin adhesives, epoxy resin coatings, epoxy coating give into water, electrical and electronic applications, analysis of epoxides and epoxy resins and the toxicology of epoxy resins. It will be a standard reference book for professionals and entrepreneurs. Those who are interested in this field can find the complete information from manufacture to final uses of epoxy resin. This presentation will be very helpful to new entrepreneurs, technocrats, research scholars, libraries and existing units.

Featuring new techniques of physicochemical analysis and broader coverage of textile applications,the thoroughly rewritten and enlarged Second Edition provides hands-on assistance inthe use, formulation, synthesis, processing, and handling of epoxy resins.Epoxy Resins, Second Edition, Revised and Expanded documents available commercialproducts, including rarer species of epoxides ... shows how to achieve qualityassurance through analytical methods ... discusses toxicity, hazards, and safe handling ...looks closely at elastomer modification of resins as well as adhesives, coatings, electrical andelectronic applications, fiber-reinforced composites, and the use of epoxy resins in thestabilization of polymers, plasticizers, and textiles ... and assists in the more efficientselection and application of epoxy resins.Complete with nearly 300 pages of tables for quick references, plus over 300 diagrams andphotographs, and more than 4,400 bibliographic references, this volume will proveindispensable to polymer, physical, and organic chemists, rheologists, materials scientists andengineers, and chemical, plastics, aerospace, automotive, and electrical and electronicsengineers.

Synthetic resin is typically manufactured using a chemical polymerization process. This process then results in the creation of polymers that are more stable and homogeneous than naturally occurring resin. Since they are more stable and are cheaper, various forms of synthetic resin are used in a variety of products such as plastics, paints, varnishes, and textiles. There are various kinds of synthetic resins; acetal resins, amino resins, casein resins, epoxy resins, hydrocarbon resins, polyamide resins, etc. The classic variety is epoxy resin, manufactured through polymerization, used as a thermoset polymer for adhesives and composites. Epoxy resin is two times stronger than concrete, seamless and waterproof. Polyamide resin is another example of synthetic resins. Polyamide resins are products of polymerization of an amino acid or the condensation of a diamine with a dicarboxylic acid. They are used for fibers, bristles, bearings, gears, molded objects, coatings, and adhesives. The term nylon formerly referred specifically to synthetic polyamides as a class. Because of many applications in mechanical engineering, nylons are considered engineering plastics. Resins are valued for their chemical properties and associated uses, such as the production of varnishes, adhesives, lacquers, paints, rubber and pharmaceutical uses. The applications of synthetic resins are seen in some important industries like paint industry, adhesive industry, the printing ink industry, the textile industry, the leather industry, the floor polish, paper, agricultural industry etc. As it can be seen that there is an enormous scope of application of resins hence it is one of the major field to venture. Synthetic Resins are materials with properties similar to natural plant resins. They are viscous liquids capable of hardening permanently. Chemically they are very different from resinous compounds secreted by plants. Synthetic resins are of several classes. The growth of the synthetic resins market can be attributed to the high demand from the packaging sector due to favorable properties, including lightweight and ability to act as an excellent barrier, which allows for their usage in applications such as barrier packaging, shrink wraps, and pharmaceutical packaging. The major contents of the book are properties, manufacturing process, formulae of synthetic resins and applications of synthetic resins, derivatives of resins, use of resins in polymer field, alkyd resin technology, epoxy resins, manufacture of polystyrene based ion-exchange, phenol formaldehyde reactions, polycarbonates resins, polyester coating compositions, synthetic rubbers, modification with synthetic resins, water-soluble polymers, cross-linking of water-soluble coatings etc. This book also contains the list of manufacturers and dealers of raw materials, list of Chemical Plant, Photographs of Machinery with Suppliers Contact Details, Sample Plant Layout and Process Flow Chart. The book will be very useful for new entrepreneurs, manufacturers of synthetic resins who can easily extract the relevant formulation and manufacturing process from the book. 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The author reviews the synthesis, manufacture and characterisation of epoxy monomers, cure reactions of epoxy resins, spectroscopic and analytical methods of studying cure, techniques for the modelling of cure, the use of additives and modifiers, and technologically driven advances in applications. An additional indexed section containing several hundred abstracts from the Rapra Polymer Library database provides useful references for further reading.